Ultrathin NiO films in the thickness range between 1 and 27 nm have been deposited on high-quality quartz substrates by direct magnetron sputtering under a rough vacuum with a base pressure of 2 × 10⁻² mbar. The sputtering target was metallic Ni; however, due to the rough vacuum a precursor material was grown in which most of Ni was already oxidized. Subsequent short annealing at temperatures of about 600 °C in a furnace in air resulted in NiO with high crystallinity quality, as atomic force microscopy revealed. The images of surface morphology showed that the NiO films were continuous and follow a normal grain growth mode. UV-Vis light absorption spectroscopy experiments have revealed a blue shift of the direct band gap of NiO. The band gap was determined either by Tauc plots (onset) or by the derivative method (highest rate of absorbance increase just after the onset). The experimental results are interpreted as evidences of quantum confinement effects. Theoretical calculations based on Hartree Fock approximation as applied for an electron-hole system, in the framework of effective mass approximation were carried out. The agreement between theory and experiment supports the quantum confinement interpretation.

In this study, the localized surface plasmon resonances (LSPRs) of Ag nanoparticles (NPs) embedded in ZnO dielectric matrices were studied. Initially, continuous Ag thin films were deposited on Corning glass substrates via magnetron sputtering, followed by post annealing, resulting in the formation of self-assembled nanoparticles. In some cases, a heated substrate holder was employed to induce NP formation during the deposition. The morphology of nanoparticles was studied using atomic force microscopy (AFM). Ultraviolet–visible spectroscopy (UV-Vis) probed the LSPRs. Subsequently, a 70 nm thick ZnO layer was deposited on top of the Ag thin films. For the Ag films, LSPR characteristics were found to depend on the initial film thickness. The ZnO capping layer induced an intense red shift, suggesting its potential as a mechanism for tailoring LSPRs. Lastly, theoretical calculations with the rigorous coupled-wave analysis (RCWA) method were carried out for comparison with the experimental results.

The microstructure of aluminum thin films, including the grain morphology and surface roughness, are key parameters for improving the thermal or electrical properties and optical reflectance of films. The first step in optimizing these parameters is a thorough understanding of the grain growth mechanisms and film structure. To investigate these issues, thin aluminum films with thicknesses ranging from 25 to 280 nm were coated on SiO_x/Si substrates at ambient temperature under high-vacuum conditions and a low argon pressure of 3 × 10⁻³ mbar (0.3 Pa) using the radio frequency magnetron sputtering method. Quantitative analyses of the surface roughness and nanograin characteristics were conducted using atomic force microscopy (AFM), transmission electron microscopy (TEM), and X-ray diffraction. Changes in specular reflectance were measured using ultraviolet–visible and near-infrared spectroscopy. The low roughness values obtained from the AFM images resulted in high film reflectivity, even for thicker films. TEM and AFM results indicate monomodal, randomly oriented grain growth without a distinct columnar or spherical morphology. Using TEM cross-sectional images and the dependence of the grain size on the film thickness, we propose a grain growth mechanism based on the diffusion mobility of aluminum atoms through grain boundaries.

We compare the structure and growth modes of two series of nanocrystalline Ni/Pt multilayers deposited on glass, Si, and polyimide substrates by electron-beam evaporation at room temperature (40 °C) and at 200 °C. X-ray diffraction patterns are recorded in order of the quality of the layering to be examined. The morphology of the films is studied by atomic force microscopy. The roughness of the samples is found to depend on the substrate and the total thickness, following a power law. The crystal structure, the shape of the crystallites, and the layering of the samples were determined by transmission electron microscopy. Differences in the shape of the crystallites and the surface morphology between the two series of samples are observed and they are understood within the framework of structural zone models. Finally, it is demonstrated the large stability of the multilayer structure for a period of at least 12 years.

Considering that the plasmonic properties of metallic nanoparticles (NPs) are strongly influenced by their dielectric environment, comprehension and manipulation of this interplay are crucial for the design and optimization of functional plasmonic systems. In this study, the plasmonic behavior of silver nanoparticles encapsulated in diverse copolymer dielectric environments was investigated, focusing on the analysis of the emerging localized surface plasmon resonances (LSPRs) through both experimental and theoretical approaches. Specifically, two series of nanostructured silver ultrathin films were deposited via magnetron sputtering on heated Corning Glass substrates at 330 °C and 420 °C, respectively, resulting in the formation of self-assembled NPs of various sizes and distributions. Subsequently, three different polymeric layers were spin-coated on top of the silver NPs. Optical and structural characterization were carried out by means of UV–Vis spectroscopy and atomic force microscopy, respectively. Rigorous Coupled Wave Analysis (RCWA) was employed to study the LSPRs theoretically. The polymeric environment consistently induced a red shift as well as various alterations in the LSPR amplitude, suggesting the potential tunability of the system.

Plasmonic materials currently have a plethora of applications. How would a dielectric matrix, such as diblock copolymers, tune plasmonic properties? In this work, self-assembled gold nanoparticles were fabricated in medium vacuum conditions on heated Corning glass substrates (kept at 440 ^°C) under the coexistence of argon and air by means of DC magnetron sputtering. These samples were compared structurally and optically to samples deposited at room temperature and post annealed. Subsequently, the better of the two preparations, those deposited on heated glass, were covered with three different polymers, namely: Polystyrene-block-polybutadiene-block-polystyrene (PS-b-PBD-b-PS); Polystyrene-co-methyl methacrylate (PS-co-PMMA); and Polystyrene-block-polyisoprene-block-polystyrene (PS-b-PI-b-PS), by means of spin coating. Localized surface plasmon resonances were recorded and analyzed, respectively, for polymer-covered gold nanoparticles, with the width, intensity, and position of the resonances changing according to multiple factors, such as the nanoparticles size and the refractive index of each polymer. Lastly, for purposes of justification and comparison with the experimental results, rigorous theoretical calculations have been carried out.