The modernization, efficiency, and decarbonization of the energy supply systems are among the new challenges to be faced in the coming decades to achieve the targets and objectives dictated by European strategic policies. Despite the countless benefits related to renewable energy sources (RES) integration, this brings key challenges to the power system, such as the risk of imbalance between energy generation and demand, sudden changes in flows in transmission lines with a need for expensive and time-consuming upgrades, and the withdrawal of conventional generation systems with consequent demands for new solutions and innovation to support grid services. A potential solution to limit the huge intermittence and fluctuation in power generation from RES is Concentrated Solar Power (CSP) technology integrated with thermal energy storage. The aim of this paper is to discuss the potential benefits related to the use of CSP technology by presenting innovative industrial solutions developed in the Italian SOLARGRID Project, namely the hybridization of CSP–PV systems and the solar thermo-electric system developed by MAGALDI, the parabolic trough collector of Eni, and the new linear Fresnel reflector configuration of IDEA S.r.l. These plant and component solutions are developed for improving the technical performance of CSP technology and reducing the levelized cost of electricity, thereby fostering an effective and massive deployment and encouraging the creation of new business models.

In the context of Concentrated Solar Power (CSP) technology, this paper presents a comparison between the Parabolic Trough Collector (PTC) and the Linear Fresnel Collector (LFC), considering both evacuated and non-evacuated receiver tubes. The comparison was carried out in terms of the Levelized Cost of Electricity (LCOE) considering a reference year and four locations in the world, characterized by different levels of direct normal irradiation (DNI) from 2183 kWh/m²/year to 3409 kWh/m²/year. The LCOE depends on economic parameters and on the net energy generated by a plant on an annual basis. The latter was determined by a steady-state 1D model that solved the energy balance along the receiver axis. This model required computing the incident solar power and heat losses. While the solar power was calculated by an optical ray-tracing model, heat losses were computed by a lumped-parameter model developed along the radial direction of the tube. Since the LFC adopted a secondary concentrator, no conventional correlation was applicable for the convective heat transfer from the glass cover to the environment. Therefore, a 2D steady-state CFD model was also developed to investigate this phenomenon. The results showed that the PTC could generate a higher net annual energy compared to the LFC due to a better optical performance ensured by the parabolic solar collector. Nevertheless, the difference between the PTC and the LFC was lower in the non-evacuated tubes because of lower heat losses from the LFC receiver tube. The economic analysis revealed that the PTC with the evacuated tube also achieved the lowest LCOE, since the higher cost with respect to both the LFC system and the non-evacuated PTC was compensated by the higher net energy yield. However, the non-evacuated LFC demonstrated a slightly lower LCOE compared to the non-evacuated PTC since the lower capital cost of the non-evacuated LFC outweighed its lower net annual energy yield. Finally, a sensitivity analysis was conducted to assess the impact on the LCOE of the annual optical efficiency and of the economic parameters. This study introduces key technical parameters in LFC technology requiring improvement to achieve the level of productivity of the PTC from a techno-economic viewpoint, and consequently, to fill the gap between the two technologies.

A radiative cooling device, based on a metamaterial able to mirror solar radiation and emit heat toward the universe by the transparency window of the atmosphere (8–13 µm), reaching and maintaining temperatures below ambient air, without any electricity input (passive), could have a significant impact on energy consumption of buildings and positive effects on the global warming prevention. A similar device is expected to properly work if exposed to the nocturnal sky, but during the daytime, its efficacy could be affected by its own heating under direct sunlight. In scientific literature, there are only few evidences of lab scale devices, acting as passive radiative cooling at daytime, and remaining few degrees below ambient air. This work describes the proof of concept of a daytime passive radiative cooler, entirely developed in ENEA labs, capable to reach well 12 °C under ambient temperature. In particular, the prototypal device is an acrylic box case, filled with noble gas, whose top face is a metamaterial deposited on a metal substrate covered with a transparent polymeric film. The metamaterial here tested, obtained by means of a semi-empirical approach, is a spectrally selective coating based on low cost materials, deposited as thin films by sputtering on the metallic substrate, that emits selectively in the 8–13 µm region, reflecting elsewhere UV_VIS_NIR_IR electromagnetic radiation. The prototype during the daytime sky could reach temperatures well beyond ambient temperature. However, the proof of concept experiment performed in a bright clear June day has evidenced some limitations. A critical analysis of the obtained experimental results has done, in order to individuate design revisions for the device and to identify future metamaterial improvements.

In the framework of the European Optimised Microturbine Solar Power system (OMSoP) project, a novel energy system for solar electricity production was developed, based on the integration of the solar dish technology with Micro Gas Turbines (MGT). A pilot plant with a capacity of 5–7 kW_e was realized and installed at the ENEA Casaccia site (Rome) and went under testing to validate the feasibility of the technology and improve the current design. The present work deals with the development of a quasi-state system model, built in the Engineering Equation Solver environment, composed of different modules that correspond to the main system components. The system model was used to define the optimal system parameters, to help the elaboration on an operational strategy to maximize the overall plant efficiency, and to guide the improvement of the single components in view of their optimised design. From the analysis it emerged that the system in design conditions is able to generate, in nominal conditions, 4.5 kW_e instead of the expected 5 kW_e due to the limitation of the stator current to 13 A, while maximum levels of 5.6 kW could be achieved by “overcharging” the high-speed generator up to 15 A and operating the MGT at the very high speed of 150 krpm. From the transient simulation of the demo system on an annual basis, the maximum average output power is 3.58 kW_e. Regarding the cycle efficiency, the annual averaged value is about 17%, whereas the target value is 21%. The improvement of the generator only does not seem to significantly increase the power output on the annual basis (3.75 kW_e vs. 3.58 kW_e). Differently, the improvement of the solar dish, with the upgrade of the other system components, would significantly increase the system power output to around ~10 kW_e.

One of the most interesting perspectives for the development of concentrated solar power (CSP) is the storage of solar energy on a seasonal basis, intending to exploit the summer solar radiation in excess and use it in the winter months, thus stabilizing the yearly production and increasing the capacity factor of the plant. By using materials subject to reversible chemical reactions, and thus storing the thermal energy in the form of chemical energy, thermochemical storage systems can potentially serve to this purpose. The present work focuses on the identification of possible integration solutions between CSP plants and thermochemical systems for long-term energy storage, particularly for high-temperature systems such as central receiver plants. The analysis is restricted to storage systems potentially compatible with temperatures ranging from 700 to 1000 °C and using gases as heat transfer fluids. On the basis of the solar plant specifications, suitable reactive systems are identified and the process interfaces for the integration of solar plant/storage system/power block are discussed. The main operating conditions of the storage unit are defined for each considered case through process simulation.

This study provides a comprehensive review of molten salt technology, as well as electrochemical and thermochemical processes aimed at hydrogen and syngas production. First, this research illustrates the current types of molten salt mixtures, detailing their main applications and thermophysical properties. Then, the analysis delves into existing thermo-electrochemical cycles and their specific operating conditions for producing hydrogen and syngas. Moreover, this study assesses the compatibility of these processes with molten salt integration. This investigation involved a comprehensive review of the existing technical and scientific literature, blending insights and practical experiences to offer detailed data on the topics explored. The findings suggest that molten salts, with their medium–high operating temperatures, can markedly improve the efficiency and sustainability of hydrogen and syngas production. Furthermore, this study outlines the pivotal role these technologies can play in achieving the European Union’s ambitious goals by enhancing the use of renewable energy sources and advancing the shift to carbon-free solutions.