A recent hydrocarbons discovery in 2021 in the Kawagarh Formation has brought attention to the significance of sedimentology and specifically diagenesis for understanding and characterizing the reservoir properties. The diagenetic history and multiscale processes that contributed to diagenesis were vaguely known. This study aimed to reconstruct various diagenetic phases, paragenetic sequences, and the interrelationship of these phases in the Kawagarh Formation. The diagenetic processes were identified and characterized through an integrated methodology utilizing the outcrop, petrographic, and geochemical analyses. Early calcite cementation was found to occur in the early stages of marine burial diagenesis involving pore fluid originating from the dissolution of aragonite in interlayer marl/mudstone beds and reprecipitating as microspar in adjacent limestone beds. The absence of mechanical compaction in wackstone and mudstone facies and the presence of late compaction in lithified packstones clearly imply that early calcite cementation occurred prior to compaction. Dolomitization with stylolites coupled with significant negative oxygen (δ18O) isotope values implies a fault-related hydrothermal dolomitization model. Uplift introduced the fractures and low Mg fresh fluids to the system which caused calcitisation in shallow burial settings. The depleted δ13C and negative δ18O values indicate the mixing of surface-derived waters with hot burial fluids during the calcitization. This study offers valuable insights into several aspects related to the formation and the basin itself, including burial depths, fluid influx, and geochemical gradients. It also sheds light on the evolution of reservoir properties such as porosity and permeability in dolomitization fronts. Such insights can be used to gain a deeper understanding about the burial history, basin evaluation, and reservoir characterization for hydrocarbon exploration.
We provide new kinematic data from the Potwar Plateau (Pakistan) to evaluate the tectonic evolution of the region during the Neogene. The plateau is bound by two major strike-slip faults in the west and the east, accommodating its southwards translation. We have recognized two Neogene deformation phases in the plateau, based on paleostress inversion and Anisotropy of Magnetic Susceptibility (AMS) tensors. The first phase lasted until the early Pliocene and was characterized by vertical minor stress and N-S compression, implying thrust tectonics. The second deformation phase is characterized by a near-vertical intermediate principal stress and near-horizontal major and minor stresses, interpreted to be associated with strike-slip tectonics since the late Pliocene. Kint vectors from 21 sites are relatively compatible with the major principal stress orientations (σ1) and indicate two distinct domains. This is possibly because Kmin orientations are related to compaction, whereas Kint orientations were always parallel to tectonic shortening and hence compression direction during both strike-slip (post-late Pliocene) and thrusting (pre-late Pliocene) phases. These phases are characterized by swapping of (σ2) and (σ3) orientations while (σ1) maintained its orientation. The most prominent change occurs at the western part of the Potwar Plateau, where major principal stress directions (σ1) and Kint axes fan out south-westwards. The eastern domain is dominated by NE-SW trending folds and thrust faults, which are absent in the western domain. These structural features are interpreted to be the result of the distribution of deposits of the Neoproterozoic Salt Range Formation as a substratum below the Potwar Plateau. The Salt Range Formation is very thick and widespread in the west area and almost absent in the east. This factor led to unconstrained southwards gliding of the Potwar Plateau over the salt deposits in the west as opposed to frictional sliding and substantial internal deformation in the east.
The present study was carried out to estimate the residual level of preservatives and active whitening agents from personal care products (PCPs) wastewater
Hazara Basin is a NE-SW trending fold and thrust belt, emerged as a consequence of ongoing collision between the Indian and Eurasian plates. Hazara Basin is bounded by Panjal Thrust (PT) in the North and Main Boundary Thrust (MBT) is located in the South. The present work deals with the paleostresses and outcrop fracture pattern (orientations, opening, fracture density) in different rock units exposed in Ghumanwan area located in the vicinity of Abbottabad, in Hazara Basin. PT and MBT juxtapose various lithological units along the Hazara Kashmir Syntaxes (HKS). The imbricate fault system between these two faults indicates a sinistral relative movement. We adopted circle inventory method in the field and collected data (fracture length, width, orientations and dip azimuth) from diverse rock units at 11 visited outcrop stations of the Ghumanwan Dome. These rock units include Upper Cretaceous (Kawagarh Formation) and Paleogene carbonates (Lockhart Formation and Margalla Hill Limestone). We observed highly dense, non-systematic fracture pattern in which mostly fractures are oriented in N-W direction normal to the bedding. Moreover, MOVETM 2018 (Midland Valley) Stress Analysis module (Stereonet Plot) was used for paleostresses analysis. The results show that the Slip Tendency (ratio of shear stress to normal stress) magnitude of σ2 lies closer to the σ3 (on Stereonet) and suggests compressional stresses in which NW-SE oriented fractures developed. The N-S compressive stresses which have mainly affected the concerned area are presumably linked to be late Eocene-Oligocene tectonic event.