Aluminum-based metallic matrix composites reinforced by carbon nanofibers (CNFs) are important precursors for development of new light and ultralight materials with enhanced properties and high specific characteristics. In the present work, powder metallurgy technique was applied for production of composites based on reinforcement of aluminum matrices by CNFs of different concentrations (0~2.5 wt%). CNFs were produced by chemical vapor deposition (CVD) and mechanical activation. We determined that in situ synthesis of carbon nanostructures with subsequent mechanic activation provides satisfactory distribution of nanofibers and homogeneous composite microstructure. Introduction of 1 vol% of flux (0.25 NaCl + 0.25 KCl + 0.5 CaF2) during mechanic activation helps to reduce the strength of the contacts between the particles. Additionally, better reinforcement of alumina particles and strengthening the bond between CNFs and aluminum are observed due to alumina film removal. Introduction of pure aluminum into mechanically alloyed powder provides the possibility to control composite durability, plasticity and thermal conductivity.
Copper-based composites strengthened with fullerene soot nanoparticles of 20–30 nm size in concentration up to 23 vol.% were prepared via two methods: mechanical mixing and molecular level mixing. The dependence of thermal conductivity on the carbon concentration was studied. Maxwell’s model describes well the change in the thermal conductivity of the composite obtained by molecular level mixing. However, thermal conductivity of the composite produced by mechanical mixing is significantly lower than the calculated values, due to structural inhomogeneity and residual stresses. Comparison of the thermal conductivity of Cu-fullerene soot composites with that of Cu-based composites described in the literature showed that the prepared materials are not inferior in thermal conductivity to composites containing carbon nanotubes, despite the fact that fullerene soot has a much lower thermal conductivity.
In this study, the main goal of this study was to understand the effect of carbon nanotube (CNT) additives on the elastic behaviors of textile-based composites. The materials have three phases: carbon fiber fabric, epoxy matrix, and carbon nanotubes. Different weight fractions of CNTs were used (0% as a reference, 0.3%). Mechanical tests were performed, such as tension and three-point bending beam tests. In addition, the composite material damages were examined in detail. The experimental results show that the samples with CNT carried 9% and 23% more axial tensile force and bending capacity on average than those with NEAT. Besides, it was understood that adding 0.3% by weight of MWCNT increases the tensile modulus by approximately 9%. Finally, the mechanical tensile and bending tests are supported by analytical solutions successfully applied in the literature.
Copper-based composite materials strengthened with nanosized fullerene soot particles were produced by mechanical milling and hot pressing technology with a content of carbon up to 5 wt. %. The microstructure of the composite powders and the compacts prepared using them were examined by light microscopy, SEM, EDS, XRD, and XPS; hardness, heat conductivity, and tribological characteristics were measured. The interesting feature of the observed microstructure was a “marble” pattern formed by a white boundary net. The study shows homogeneous distribution of carbon inside the copper grains and its lower concentration in the grain boundaries. The effect was caused by a reaction of carbon with oxygen adsorbed by the copper particles surface. The maximal hardness of the material is 160 HB for the sample with 0.5 wt. % of fullerene soot; this material has the minimal friction coefficient (0.12) and wear in a dry friction condition. Heat conductivity of the material (Cu-0.5 wt. % C) is 288 W/m*K.