This paper investigates the influence of iron oxide (Fe2O3) nanoparticles on the physical properties of medium density fiberboard (MDF). In this study, three different nano iron oxide loadings, i.e., 0.5, 1.5 and 2.5 wt %, and untreated poplar fibers were used. The iron oxide (Fe2O3) nanoparticles were initially dispersed into urea formaldehyde resin using a high-vacuum mechanical stirrer before being incorporated into natural fibers. The untreated poplar fibers were wound onto metal frames to produce dry mat layers. Twenty different composite samples were made. All composite samples were tested for physical properties, i.e., thickness swelling, water absorption, moisture content and density in accordance with standards EN-317, ASTM D570, EN-322 and EN-323 respectively. Based on the results, it was found that the incorporation of homogeneously dispersed iron oxide nanoparticles significantly improved thickness swelling (Ts). Moreover, water absorption (WA) improved by up to 49.18 and 34.54%, respectively, at the highest loading of 2.5 wt %. Microstructure was investigated and characterized with scanning electron microscopy (SEM), x-ray diffraction (XRD) and energy dispersive spectroscopy (EDS) and we examined whether iron oxide nanoparticles exhibit good interactions with urea formaldehyde and poplar wood fibers. Heat and mass transfer investigation in the form of differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA) was carried out due to the impact of Fe2O3 nanoparticles. The curing temperature and thermal stability of the resin were enhanced due to the addition of Fe2O3 nanoparticles. A one-way ANOVA statistical analysis was established to effectively control the use of Fe2O3 nanoparticles. Therefore, the presence of iron oxide nanoparticles in an epoxy polymer contributes to a stiffer matrix that, effectively, enhances the capability of improving the physical properties of nano MDF.
Polytetrafluoroethylene (PTFE) was coated on 316L stainless steel (SS) substrate through a spin coating technique to enhance its corrosion resistance properties in hydrochloric acid (HCl) and nitric acid (HNO3) medium. Scanning electron microscopy (SEM) revealed the morphology of the coated and uncoated substrates and showed a uniform and crack-free PTFE coating on 316L SS substrate, while a damaged surface with thick corrosive layers was observed after the electrochemical test on the uncoated sample. However, an increased concentration of HCl and HNO3 slightly affected the surface morphology by covering the corrosive pits. An atomic force microscope (AFM) showed that the average surface roughness on 316L SS and PTFE coating was 26.3 nm and 24.1 nm, respectively. Energy dispersive X-ray spectroscopy (EDS) was used for the compositional analysis, which confirmed the presence of PTFE coating. The micro Vickers hardness test was used to estimate the hardness of 316L SS and PTFE-coated substrate, while the scratch test was used to study the adhesion properties of PTFE coating on 316L SS. The anticorrosion measurements of 316L SS and PTFE-coated substrates were made in various HCl and HNO3 solutions by using the electrochemical corrosion test. A comparison of the corrosion performance of PTFE-coated substrate with that of bare 316L SS substrate in HCl medium showed a protection efficiency (PE) of 96.7%, and in the case of HNO3 medium, the PE was 99.02%, by slightly shifting the corrosion potential of the coated sample towards the anodic direction.
This research aims to explore the effects of nanoparticles such as alumina (Al2O3) on the physical and mechanical properties of medium density fiberboards (MDF). The nanoparticles are added in urea-formaldehyde (UF) resin with different concentration levels e.g., 1.5%, 3%, and 4.5% by weight. A combination of forest fibers such as Populus Deltuidess (Poplar) and Euamericana (Ghaz) are used as a composite reinforcement due to their exceptional abrasion confrontation as well as their affordability and economic value with Al2O3-UF as a matrix or nanofillers for making the desired nanocomposite specimens. Thermo-gravimetric analysis (TGA) and thermal analytical analysis (TAA) in the form of differential scanning calorimetry (DSC) are carried out and it has been found that increasing the percentage of alumina nanoparticles leads to an increase in the total heat content. The mechanical properties such as internal bonding (IB), modulus of elasticity (MOE) and modulus of rupture (MOR), and physical properties such as density, water absorption (WA), and thickness swelling (TS) of the specimens have been investigated. The experimental results showed that properties of the new Nano-MDF are higher when compared to the normal samples. The results also showed that increasing the concentration of alumina nanoparticles in the urea-formaldehyde resin effects the mechanical properties of panels considerably.
The main purpose of this research work is to characterize zinc oxide-urea formaldehyde nano resin and identify the physical performance of medium-density fiberboard (MDF). Considering the dry weight of natural fibers, the ZnO nanoparticles were added to urea formaldehyde (UF) glue at four levels—0.0%, 1.0%, 2.0% and 3.0%—and their effects were investigated in terms of the physical properties of MDF. The surface morphology and crystalline structure of ZnO, UF and UF-ZnO nanofillers were characterized using Scanning Electron Microscopy (SEM) and X-ray diffraction (XRD) analysis and significant improvements were achieved as a result of the addition of nanoparticles. Thermal properties were analyzed by means of differential scanning calorimetry (DSC) and thermogravemetric analysis (TGA) and it was observed that increasing the concentration of ZnO nanoparticles ultimately enhanced the curing of UF-ZnO nanofillers. Finally, density, thickness swelling and water absorption properties were investigated and it was observed that thickness swelling and water absorption properties were improved by 38% and 12%, respectively, when compared to control MDF.
In this research work effect of embedment of multiwall carbon nanotubes (MWCNTs) on the physical and mechanical properties of medium density fiberboard (MDF) have been investigated. The MWCNTs were embedded in urea formaldehyde resin (UF) at 0, 1.5%, 3% and 5% concentrations by weight for the manufacturing of nano-MDF. The addition of these nanoparticles enhanced thermal conductivity by 24.2% reduced curing time by 20% and controlled formaldehyde emission by 59.4%. The internal bonding (I.B), modulus elasticity (MOE), modulus of rupture (MOR), thickness swelling (Ts) and water absorption (WA) properties were improved significantly by 21.15%, 30.2%, 28.3%, 44.8% and 29% respectively as compared to controlled MDF.
22 March 2024 in Journal of Coatings Technology and Research