We theoretically investigate high-pressure effects on the atomic dynamics of metallic glasses. The theory predicts compression-induced rejuvenation and the resulting strain hardening that have been recently observed in metallic glasses. Structural relaxation under pressure is mainly governed by local cage dynamics. The external pressure restricts the dynamical constraints and slows down the atomic mobility. In addition, the compression induces a rejuvenated metastable state (local minimum) at a higher energy in the free-energy landscape. Thus, compressed metallic glasses can rejuvenate and the corresponding relaxation is reversible. This behavior leads to strain hardening in mechanical deformation experiments. Theoretical predictions agree well with experiments.
In this work, photocatalytic performance is divulged in the ternary CuO-Ag-ZnO nanowire synthesized via a two-step approach. The decoration of Ag and CuO nanostructures onto the surface of ZnO nanowires was simply carried out by using the plasma electrolytic oxidation method in a short time. The structure, size, morphology, and optical properties of as-prepared samples were characterized by X-ray diffraction, field-emission scanning electron microscopy, and spectrophotometry measurements. The diameters of Ag nanoparticles and ZnO nanoflowers are in the range of 5–20 nm and 20–60 nm, respectively. Within the first 15 min, methyl orange was decolorized 96.3 and 82.8% in the CuO-Ag-ZnO and Ag-ZnO, respectively, and there is only about 46.7% of that decomposed in pure ZnO. The CuO-Ag-ZnO shows a higher rate constant k = 0.2007 min−1 and a lower half-life time t = 6.1 min compared to Ag-ZnO and bare ZnO nanowires. The photo-reusability of the ternary nanostructures was estimated to be much outweighed compared to ZnO nanowires. Interestingly, the synergic incorporation between noble metal–semiconductor or semiconductor–semiconductor in the interfaces of Ag-CuO, Ag-ZnO, and CuO-ZnO expands the visible light absorption range and eliminates the photogenerated electron–hole recombination, resulting in a superior visible-light-driven photocatalyst.
Nano/micro polystyrene (PS) beads have found many applications in different fields spanning from drug delivery, bio-diagnostics, and hybrid plasmonics to advanced photonics. The sizes of the PS beads are an important parameter, especially in plasmonic and photonic experiments. In this work, we demonstrate a quick and straightforward method to estimate the diameters of sub-microspheres (0.2 μm to 0.8 μm) using the transmission spectra of a close-packed monolayer of polystyrene beads on glass or quartz substrates. Experimental transmission spectra of the PS monolayers were verified against finite-difference time-domain (FDTD) simulation and showed good agreement. The effects of the substrates on the transmission spectra and, hence, the accuracy of the method were also studied by simulation, which showed that common transparent substrates only cause minor deviation of the PS bead sizes calculated by the proposed method.
We propose a design rule for broadband metamaterial absorbers and investigate their plasmonic properties under solar irradiation. The metamaterials consist of periodic arrays of titanium nitride (TiN) rings placed on an antireflective MgF2 dielectric film on a TiN bottom layer. We simulate the absorption of our metamaterials and find the dependence of the optical spectrum on structural parameters. From this, we propose a simple rule to design the nanostructures with an average spectral absorptivity greater than 95% over the solar spectrum from 200 to 3000 nm. Particularly, we introduce, for the first time, metamaterial perfect absorbers that can be designed using two-layer structures instead of higher-layer structures as conventional and sandwich designs. Our study would pave the way for great potential applications in the fields of solar energy harvesters and photo-to-thermal converters.
A reconfigurable metamaterial absorber (MA) in the microwave region is numerically and experimentally demonstrated based on a multi-layered metamaterial. The proposed structure can be mechanically switched between two different configurations to obtain designated absorption behaviors. By rotating the upper ring layer by multiples of 90 deg, two separated absorption modes of the MA are created. The first configuration acts as a single-band absorber, while the second configuration performs multi-band perfect absorption. In addition, the proposed structure can be easily switched into two different configurations to obtain a designated absorption feature. Our work is expected to provide an effective approach to obtaining reconfigurable MAs, which are useful for various applications.
A metamaterial (MM), mimicking electromagnetically-induced transparency (EIT) in the GHz regime, was demonstrated numerically and experimentally by exploiting the near-field coupling of asymmetric split-ring and cut-wire resonators. By moving the resonators towards each other, the original resonance dip was transformed to a multi-band EIT. The phenomenon was explained clearly through the excitation of bright and dark modes. The dispersion characteristic of the proposed MM was also investigated, which showed a strongly-dispersive behavior, leading to a high group index and a time delay of the MM. Our work is expected to contribute a simple way to develop the potential devices based on the multi-band EIT effect.