María Dolores Marrero Alemán

Prof. Dr. María Dolores Marrero Alemán

orcid

Research Focus & Metrics

Academic Career Length

10Years (2017-Present)

(Calculated once Scilit publication data is synced: current year − year of first publication + 1)

Representative Publications

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15 October 2022 in Journal of Natural Fibers
Verified
Journal Article
Open access
LSLuis Suárez
Luis Suárez
Mateusz BarczewskiMateusz Barczewski
Mateusz Barczewski
Paulina KosmelaPaulina Kosmela
Paulina Kosmela
MAMaría Dolores Marrero Alemán
María Dolores Marrero Alemán
Zaida OrtegaZaida Ortega
Zaida Ortega
This work describes an extraction method for giant reed fibers from stems and leaves based on chemical soaking and crushing through a rolling mill. Obtained fibers, together with the shredded plant (stems + leaves), are characterized in terms of chemical composition, thermal stability, morphology, and crystallinity. Mechanical properties of fibers have also been assessed (single fiber tensile tests). The results show that the proposed method allows obtaining fibers with higher cellulose content (near 70%), good thermal stability (10% weight loss over 270°C), higher density, and better mechanical properties than other Arundo fibers previously reported in the literature. Fibers from leaves are thinner and show higher crystallinity than those from stems (72 μm vs. 157 μm, 73% vs. 67% crystallinity, respectively), although mechanical properties are similar for both (around 900 MPa for tensile strength and over 45 GPa for elastic modulus). Analysis of the microstructure shows that fibers consist of microfiber bundles, and the removal of a thin layer of non-cellulosic nature is clear; fibers provide a rougher, cleaner surface than shredded raw material.

5 July 2021 in Polymers
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Journal Article
Open access
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Zaida OrtegaZaida Ortega
Zaida Ortega
FRFrancisco Romero Francisco Romero
Francisco Romero Francisco Romero
Rubén PazRubén Paz
Rubén Paz
LSLuis Suárez
Luis Suárez
AVAntonio Nizardo Benítez Vega
Antonio Nizardo Benítez Vega
MAMaría Dolores Marrero Alemán
María Dolores Marrero Alemán
This paper compares the mechanical properties of different natural fiber composites produced by rotational molding as a way of waste valorization from campaigns to control invasive plant species in Macaronesia. Rotomolded parts produced with polymeric matrices (polyethylene) and filled with up to 20% by weight of cellulosic fibers obtained from Arundo donax L., Pennisetum setaceum, and Ricinus communis plants were characterized in terms of tensile, flexural, and impact strength. It was found that the sieving of natural fibers allowed for their introduction in higher loadings, from 10 (for un-sieved material) to 20%; fiber size greatly affected the mechanical properties of the final parts, although some combinations were proven not to reduce the mechanical properties of the neat resin. This study is a first approach to the valorization of residues obtained from periodic campaigns of the control of invasive species performed by public authorities, usually at the local level. It is important to highlight that the main objective of this research did not focus on economically profitable activity; instead, it was focused on the reduction of wastes to be disposed from ecosystem maintenance actions and the investment of potential income into preservation policies.

25 June 2021 in Polymers
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Journal Article
Open access
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LSLuis Suárez
Luis Suárez
JCJessica Castellano
Jessica Castellano
FRFrancisco Romero Francisco Romero
Francisco Romero Francisco Romero
MAMaría Dolores Marrero Alemán
María Dolores Marrero Alemán
AVAntonio Nizardo Benítez Vega
Antonio Nizardo Benítez Vega
Zaida OrtegaZaida Ortega
Zaida Ortega
This paper summarises the results obtained from the characterisation of giant reed (Arundo donax L.) plant and fibres. The research is part of a project developed in the Macaronesia region, of which the aim is to demonstrate the feasibility of using biomass from invasive plant species in the composites sector as a way of financing control campaigns and habitats conservation labours. An experimental procedure for the extraction of fibre bundles from this plant was developed, and the material obtained was characterised in terms of chemical composition, thermogravimetry and infrared spectra to evaluate its potential application in the production of polymeric composite materials as a strategy for the valorisation of residual biomass from this invasive species in Macaronesia. Thermoplastic matrix composites with fibre content up to 40 wt.% were produced and their mechanical properties under tensile, flexural and impact loading were determined. No references on the preparation of composite materials with polyolefin matrices and giant reed fibres have been found. Results obtained from mechanical tests show a good performance of the manufactured composites, with a significant increase in both flexural and tensile stiffness; the flexural modulus is almost tripled for PE-based composites and rises to 88% with respect to PP matrix. The ultimate flexural strength and the tensile and flexural yield strength are kept at acceptable values compared to neat polymer materials, although ultimate tensile strength and impact resistance are significantly affected when natural fibres are added.

24 June 2021 in Polymers
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Journal Article
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JCJessica Castellano
Jessica Castellano
MAMaría Dolores Marrero Alemán
María Dolores Marrero Alemán
Zaida OrtegaZaida Ortega
Zaida Ortega
FRFrancisco Romero Francisco Romero
Francisco Romero Francisco Romero
AVAntonio Nizardo Benítez Vega
Antonio Nizardo Benítez Vega
MVM.R. Myriam Ventura
M.R. Myriam Ventura
Some studies have evaluated the use of Opuntia as reinforcement for polymeric matrices, obtaining good results in energy absorption tests and increasing the tensile elastic modulus. However, no studies focusing on the previous characterisation of the fibres and their treatment to improve compatibility with polymeric matrices have been found. This work analyses the chemical composition of Opuntia maxima (OM) and Opuntia dillenii (OD) cladodes and fibre, studying how different treatments influence it. AOAC 2000 methods were used to determine non-structural components and the Van Soest method was used to estimate structural components. Surface characteristics of the samples were also evaluated by Fourier Transform Infrared Spectroscopy (FTIR). Opuntia fibre presented higher cellulose (50–66%) and lignin (6–14%) content and lower hemicellulose (8–13%) content than Opuntia cladodes (9–14% cellulose, 20–50% hemicellulose, 1–4% lignin). Despite the variability of lignocellulosic materials, OD cladodes treated with water and acetic acid achieved an increase in the structural components. Alkaline fibre treatment removed pectin and hemicellulose from the fibre surface, slightly increasing the cellulose content. Future research should evaluate whether the treated Opuntia fibre can improve the mechanical properties of reinforced polymer.

1 September 2022 in Journal of Polymers and the Environment
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Journal Article
Open access
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LSLuis Suárez
Luis Suárez
Zaida OrtegaZaida Ortega
Zaida Ortega
FRFrancisco Romero Francisco Romero
Francisco Romero Francisco Romero
Rubén PazRubén Paz
Rubén Paz
MAMaría Dolores Marrero Alemán
María Dolores Marrero Alemán
This paper assesses the modifications in the properties of rotomolded polyethylene (PE) and polylactic acid (PLA) composites obtained with 5 and 10% giant reed fibers, mainly focusing on the alterations due to a bio-disintegration process. Thermal properties (melting temperature and crystallinity degree), morphology (via optical and scanning electron microscopy), and chemical changes (by Fourier Transformed Infrared spectroscopy) were studied. Composites with untreated and NaOH-treated fibers were obtained, finding that this treatment does not improve the mechanical performance of composites due to increased porosity. The introduction of natural fibers into a PE matrix does not significantly modify the thermal and bio-disintegration properties of the rotomolded material. Regarding mechanical properties, PE-composites show increased tensile modulus and reduced impact and tensile strength than the matrix. On the other hand, PLA composites show lower impact and flexural strength than neat PLA, remaining the rest of the mechanical properties unchanged regardless of the fibers' addition. The incorporation of Arundo fibers modifies to a great extent the thermal and degradation behavior of the PLA matrix.

1 December 2021 in Marine Pollution Bulletin
Verified
Journal Article
Open access
SRStefanie Reinold
Stefanie Reinold
AHAlicia Herrera
Alicia Herrera
NSNicolò Stile
Nicolò Stile
Francesco SaliuFrancesco Saliu
Francesco Saliu
CHCarlos Hernández-González
Carlos Hernández-González
MGMay Gómez
May Gómez
Sediment core samples from high tide lines and in submerged zones as well as surface water samples from eight beaches of Tenerife were analysed. Sampling was conducted over a period of one year in intervals of 5 weeks. The majority of particles were found in the high tide sediment (66%), followed by water samples (23%) and finally in sediment from submerged zones (11%). Regarding the particle amount per volume (items/L), accumulation in sediment samples was statistically higher compared to water samples. Mean values of items/L were higher in high tide sediments. In high tide and water samples, mostly white and transparent particles 1 mm were found. More than 70% were represented by fragments. In sediments from submerged zones, yellow and blue microparticles (<1 mm) were predominant and 61.9% consisted of fibres. Larger particles were mainly identified as PP, PE, PS, PTFE and PVC, while polymer types of smaller particles were more variable.