This work presents the results of research on the thermo-chemical conversion of woody biomass–pine wood coming from lodzkie voivodship forests and sewage sludge from the Group Sewage Treatment Plant of the Łódź Urban Agglomeration. Laboratory scale analyses of the carbonization process were carried out, initially using the TGA technique (to assess activation energy (EA)), followed by a flow reactor operating at temperature levels of 280–525 °C. Both the parameters of carbonized solid biofuel and biochar as a carrier for fertilizer (proximate and ultimate analysis) and the quality of the torgas (VOC) were analyzed. Analysis of the pine wood and sewage sludge torrefaction process shows clearly that the optimum process temperature would be around 325–350 °C from a mass loss ratio and economical perspective. This paper shows clearly that woody biomass, such as pine wood and sewage sludge, is a very interesting material both for biofuel production and in further processing for biochar production, used not only as an energy carrier but also as a new type of carbon source in fertilizer mixtures.
Carbonation lime mud is a by-product formed during the production of sugar in the process of raw beetroot juice purification. On average, during one campaign, over 12,000 tons of carbonation lime mud is obtained in the operation of one sugar production plant. It is stored in prisms, which negatively affects the environment. The chemical properties of carbonation lime mud allow using it as a soil improver. This article presents the results of research into the development of carbonation lime mud disposal technology and its management. The chemical composition and physical properties of waste were determined. It has been proposed to use carbonation lime mud as the basic raw material in the production of mineral–organic fertilizers. Tests were conducted in a disc granulator. The granulated material was wetted with water and aqueous solution of molasses. Carbonation lime mud is a material that is easily subjected to the granulation process, using any wetting liquid. The beds wetted with 33% and 66% solutions of molasses are characterized by a greater homogeneity and smaller size of the obtained product. During experiments in which wetting with water was applied, the product obtained after drying demonstrated low resistance to compression; granules wetted with 33% aqueous solution of molasses demonstrated resistance to compression below 10 N; and granules wetted with 66% aqueous solution of molasses demonstrated resistance to compression above 10 N.
The application of the Discrete Element Method (DEM) allows simulating the movement of a particle of any shape in a conveyor. The DEM method uses the assumptions of the Lagrange calculation model, in which each particle in the domain is tracked individually. It makes it possible to conduct a thorough examination of the behavior of the entire bulk material bed consisting of a set of elements with characteristic physicochemical properties. Therefore, the deposit is not considered according to averages and constants, e.g., strength values, but as a set of elements that can be described individually. The article presents the results of a simulation, with the use of the Discrete Elements Method (DEM), of the process of soft fruit transport in the food industry. The results of the research and exemplary simulations of blueberry fruit transport are presented. The influence of the type of a transport device on the values of normal and tangential forces occurring between the blueberry fruit and structural elements of the transport device, as well as the interaction between the fruits, were modeled. In addition, based on the amount of energy absorbed by each fruit due to collisions, the analysis of the energy spectrum of collisions of particles was carried out to determine the likelihood of damage to the fruit in transport and to identify the phenomena that favor it.
The goal of this paper is the research and analysis of municipal waste stream management in rural areas, potentially designed for energy purposes in thermal treatment systems. The research section includes granulometric, morphological, and physicochemical analyses to determine waste parameters. Studies have indicated that the calorific value for mixed municipal waste ranged between 6.5 and 9.5 MJ∙kg, while following mechanical treatment for the oversize fraction over 80 mm ranged between 11.6 and 12.7 MJ∙kg. The biodegradable fraction content analysis of waste—granulation 10 to 20 mm—demonstrated its presence at the level of 80%, which may be used to produce biogas. Studies have shown that the humidity level of waste generated in rural areas is in the range of 32.9 to 40.9%, which does not disqualify it from energy use in the production of refuse-derived fuel. Implementing a circular economy in the municipal waste sector aims at minimizing the use of raw materials, limiting municipal waste generation and greenhouse gases emissions, and increasing the level of energy use. Implementing new municipal waste management models is crucial to achieve a balanced, low-emission, waste-free, and competitive economy. The results are a significant research input for a group of municipal wastes generated in rural areas, such as refuse-derived fuel.
Water pollution is an immense environmental problem, and plant protection products are part of it. The organophosphorus insecticides, chlorpyrifos as an example, were used for years, and their high concentration could negatively influence ecosystems. Some of the plants, such as macrophytes, were exposed to a variety of stress factors. To live on, the macrophytes developed an efficient antioxidative system consisting of enzymatic and non-enzymatic antioxidants. The remediation process of polluted water ecosystems caused by plant protection products in our climate zone can be intensified if it is provided by autochthonic macrophytes. The results of our studies are part of the research that allows optimizing the phytoremediation process without irreversible effect on investigated species. The influence of various concentrations of chlorpyrifos on the enzymatic system in Canadian waterweed (Elodea canadensis Michx.), needle spikerush (Eleocharis acicularis L.), and water mint (Mentha aquatica L.) were studied. The differences in values of guaiacol peroxidase (GPX) and glutathione S-transferase (GST) activities were determined in leaves and roots. Research indicated an increase in both enzyme activities in plants exposed to toxic compounds. The highest concentration of chlorpyrifos affected the highest activities of enzymes. The water mint roots responded with the highest value of glutathione S-transferase activity during cultivation in polluted environment. It was therefore concluded that an aqueous plant exposed to the toxic insecticide created a defensive mechanism by enzymatic antioxidant systems that correlated to the pollutant concentration and plant species.
This work concerns non-pressure granulation of mineral materials used for the production of agricultural fertilizers for soil deacidification. In order to expand the product range of Nordkalk Poland sp. z o. o. located in Poland, the granulation conditions of the gypsum–lime mix were examined with the use of various granulation methods. The processed mixture was Jurassic lime flour mined in the Sławno mine (Poland) and waste gypsum (sulfogypsum) obtained from the largest coal-fired power plant in the EU, Bełchatów Power Plant (Poland). This paper presents the results of the optimization of the gypsum–lime fertilizer granulation process. The results of the study of granulation of gypsum–lime mixture realized in one-stage technology in a disc granulator were compared with the effects of two-stage agglomeration. During the research, a mixture (in a 1:1 ratio) of waste sulfogypsum and lime flour was used. Such a weight ratio provides maximum use of the sulfogypsum waste while maintaining good mechanical properties of the granulate. The granulated bed was moistened with a lignosulfonate solution. The process was carried out periodically. After the experiment, the grain composition of the granulate obtained was determined and tests were performed to determine the strength of the product. The test results were compared with analogous ones obtained during granulation with the use of molasses (waste from sugar production). The results obtained were verified during a trial carried out on an industrial scale.