Carbonation lime mud is a by-product formed during the production of sugar in the process of raw beetroot juice purification. On average, during one campaign, over 12,000 tons of carbonation lime mud is obtained in the operation of one sugar production plant. It is stored in prisms, which negatively affects the environment. The chemical properties of carbonation lime mud allow using it as a soil improver. This article presents the results of research into the development of carbonation lime mud disposal technology and its management. The chemical composition and physical properties of waste were determined. It has been proposed to use carbonation lime mud as the basic raw material in the production of mineral–organic fertilizers. Tests were conducted in a disc granulator. The granulated material was wetted with water and aqueous solution of molasses. Carbonation lime mud is a material that is easily subjected to the granulation process, using any wetting liquid. The beds wetted with 33% and 66% solutions of molasses are characterized by a greater homogeneity and smaller size of the obtained product. During experiments in which wetting with water was applied, the product obtained after drying demonstrated low resistance to compression; granules wetted with 33% aqueous solution of molasses demonstrated resistance to compression below 10 N; and granules wetted with 66% aqueous solution of molasses demonstrated resistance to compression above 10 N.
The policy of sustainable development, the need to save natural environmental resources, and the use of waste as raw materials in new production processes allow the use of enzymes in many industries. Enzymatic tanning and chrome tanning are two different methods used in the leather industry to transform raw hides into a durable and usable material. Enzymatic tanning uses natural enzymes that are biodegradable and environmentally friendly. Additionally, enzymatic tanning requires less water and generates less waste than chrome tanning. Moreover, enzymatic tanning can result in softer and more flexible leather with better uniformity. Enzymes selectively break down collagen fibers, resulting in a more even tanning and a consistent leather product. The use of combined enzymatic technologies with non-obvious leather finishing methodologies in tanning is forced by European Union regulations limiting the use of hazardous substances and generating significant amounts of corrosive wastewater for the environment. However, tanning with enzymes is not a perfect process; therefore, this work presents the advantages and disadvantages of tanning with enzymes and describes new technological trends in the tanning industry.
This review presents the latest research works detailing granulation processes and granulates, including and based on waste (bio and industrial) as a biofuel/energy source and the possible usage of granulates from and/or based on biochar. The innovative aspect is that the article focuses on the broadest possible environmental aspect understood in minimizing the burden related to the amount and composition of waste generated by various industries. The aim of the study is to demonstrate the processes as an effective method of waste management and also as energy sources. Based on various sources, a brief summary of why granulation is an important area of both scientific research and industrial applications is provided. The review also presents a summary of basic concepts and definitions in the topic of granulation—types of processes, apparatuses used, and examples of research results in the literature. The main part of the review is the analysis of the literature providing numerous examples on the usage of granules based on bio and industrial waste and various biochar granulates. The conclusions present the aspect of economical sustainability of granulation processes and the use of granulates as effective solutions for energy sources (fuel, biofuel), waste management, and applications in agriculture (soil additives, fertilizers).
This paper presents methods for managing waste produced by the leather industry, including tanning shavings derived from chrome tanning technologies and collagen preparations. Shavings were classified according to their shape (in accordance with Zingg’s shape classification). The content of individual elements was determined, together with the content of volatile organic compounds. Two new products were developed as part of the completed works: agglomerates (methods of non-pressure granulation) and composite materials were produced on the basis of tanning shavings and mineral fillers. Young’s modulus values classify these composite materials in the group of polymers and certain materials from the group of elastomers. A method for seed coating (on the example of legumes and rape) was also developed using a disc granulator, including collagen preparations in one of the layers as a solution for preventing the effects of droughts (biostimulant). The analyses of selected properties of the new products confirm the wide possible application of waste shavings and collagen preparations in a circular economy, especially in the construction, packaging, and agricultural sectors.
This work concerns non-pressure granulation of mineral materials used for the production of agricultural fertilizers for soil deacidification. In order to expand the product range of Nordkalk Poland sp. z o. o. located in Poland, the granulation conditions of the gypsum–lime mix were examined with the use of various granulation methods. The processed mixture was Jurassic lime flour mined in the Sławno mine (Poland) and waste gypsum (sulfogypsum) obtained from the largest coal-fired power plant in the EU, Bełchatów Power Plant (Poland). This paper presents the results of the optimization of the gypsum–lime fertilizer granulation process. The results of the study of granulation of gypsum–lime mixture realized in one-stage technology in a disc granulator were compared with the effects of two-stage agglomeration. During the research, a mixture (in a 1:1 ratio) of waste sulfogypsum and lime flour was used. Such a weight ratio provides maximum use of the sulfogypsum waste while maintaining good mechanical properties of the granulate. The granulated bed was moistened with a lignosulfonate solution. The process was carried out periodically. After the experiment, the grain composition of the granulate obtained was determined and tests were performed to determine the strength of the product. The test results were compared with analogous ones obtained during granulation with the use of molasses (waste from sugar production). The results obtained were verified during a trial carried out on an industrial scale.