Major efforts are currently being made in the research community to address the challenges of greenhouse gas emissions from fossil fuel combustion by using lignocellulosic biomass, agricultural waste, and forest residues as cleaner energy sources. However, its poor qualities, such as low energy density, high moisture content, irregular shape and size, and heterogeneity, make it impossible to utilize in its natural state. Torrefaction, a simple heat treatment method, is used frequently with natural bioresources to improve their thermal characteristics so that they may be used as energy sources in domestic power plants. The quality of the resulting torrefied solids (biochar) is determined by the heat condition settings in the absence of oxygen, and it may be enhanced by carefully selecting and altering the processing parameters. The comprehensive overview presented here should serve as a useful toolkit for farmers, combined heat and power plants, pulp and paper installations, and other industrial plants that use biomass as a substrate for biofuel production. This research focuses on torrefaction product properties, reaction mechanisms, a variety of technologies, and torrefaction reactors. It is impossible to determine which torrefaction technology is superior as each reactor has unique properties. However, some suggestions and recommendations regarding the use of torrefaction reactors are given.

This work presents the results of research on the thermo-chemical conversion of woody biomass–pine wood coming from lodzkie voivodship forests and sewage sludge from the Group Sewage Treatment Plant of the Łódź Urban Agglomeration. Laboratory scale analyses of the carbonization process were carried out, initially using the TGA technique (to assess activation energy (EA)), followed by a flow reactor operating at temperature levels of 280–525 °C. Both the parameters of carbonized solid biofuel and biochar as a carrier for fertilizer (proximate and ultimate analysis) and the quality of the torgas (VOC) were analyzed. Analysis of the pine wood and sewage sludge torrefaction process shows clearly that the optimum process temperature would be around 325–350 °C from a mass loss ratio and economical perspective. This paper shows clearly that woody biomass, such as pine wood and sewage sludge, is a very interesting material both for biofuel production and in further processing for biochar production, used not only as an energy carrier but also as a new type of carbon source in fertilizer mixtures.

One of the solid waste produced during the combustion of coal are fly ashes. Disposal challenges and environmental consequences are the results of significant process yield and atmospheric emission of fly ashes. The exact chemical composition of FA depends mainly on the type of utilised fuel and combustion conditions. It consists mainly of chemically stable metal oxides, such as Al₂O₃, Fe₂O₃, SiO₂, CaO, MgO, K₂O, Na₂O and TiO₂, but its toxicity is related to the possible presence of some trace elements, such as As, Hg, Cd, Se and Cr. The chemical and physical properties of fly ash (e.g., particle size distribution, porosity, and surface area) make it suitable as an adsorbent to remove various impurities from process flows such as flue gas stream. Its suitability for capturing mercury from flue gas was experimentally confirmed due to its abundant supply, particle size, bulk density, porosity, chemical composition and low cost. Hence, the use of fly ash as adsorbents and precursors for the production of heavy metal adsorbents is of great practical importance, as it reduces the cost of mercury capture and alleviates the problems associated with the disposal of solid waste. Studies showed that the chemical components present in fly ash additives could stimulate catalytic oxidative capacity, which increases the adsorption of Hg⁰ oxidation and adsorption of both Hg and CO₂. The presented study analysed fly ashes from different zones of the electrostatic precipitator and verified their suitability for removing impurities from flue gases, i.e., mercury and carbon dioxide. The results outlined modified fly ash as having good Hg and CO₂ removal capabilities. The adsorption efficiency of Hg reached 92% for Hg and 66% for CO₂, while untreated fly ash reached 67% for Hg and 59% for CO₂.

This paper offers an algorithm to account for potential actions on the efficient production of renewable energy. The algorithm consists of a substantiated choice of a certain type of renewable energy, the evaluation of its potential, and the regulation of the processes of obtaining that renewable energy. Also, potential resources for agricultural biofuel production have been analyzed and it has been determined that there is real biomass potential in Lithuania. It will thus be beneficial to make appropriate managerial decisions on the methods of biofuel processing and consumption, as well as on means of receiving the economic, energy and environmental effects. The total potential of by-product biomass of crop production was determined, and the thermal and electric potential of the crop by-products were calculated. Additionally, the potential for production of gas-like types of fuel (biomethane, biohydrogen, and syngas) from crop by-products was determined. The potential for the production of diesel biofuel from oil crop waste (bran) was also found, and the potential for livestock by-products for receiving gas-like types of fuel (biomethane, biohydrogen) was established. The corresponding thermal and electric equivalents of the potential were found and the potential volumes of the biomethane and biohydrogen production were calculated. The total energy equivalent equals, on average, 30.017 × 10⁶ GJ of the thermal energy and 9.224 × 10⁶ GJ of the electric energy in Lithuania. The total potential of biomethane production (taking into account crop production and animal husbandry wastes) on average equals 285.6 × 10⁶ m³. The total potential of biohydrogen production on average equals 251.9 × 10⁶ m³. The cost equivalents of the energy potential of agrarian biomass have been calculated. The average cost equivalent of the thermal energy could equal EUR 8.9 billion, electric energy—EUR 15.9 billion, biomethane—EUR 3.3 billion and biohydrogen—EUR 14.1 billion. The evaluation of the agricultural biomass potential as a source of renewable energy confirmed that Lithuania has a large biomass potential and satisfies the needs for the production of renewable energy. Thus, it is possible to move to the second step, that of making a decision concerning biomass conversion.

The torrefaction process represents a thermal conversion technique conducted at relatively low temperatures ranging between 200 to 300 °C. Its objective is to produce fuel with a higher energy density by decomposing the reactive portion of hemicellulose. In this study, the kinetics of mass loss during torrefaction were investigated for willow. The experiments were carried out under isothermal conditions using thermogravimetric analysis. Batch torrefaction reactor designs were conducted and explained in detail. Co-combustion of willow with hard coal (origin: Katowice mine) in different mass ratios (25% biomass + 75% coal, 50% biomass + 50% coal, and 75% biomass + 25% coal) was conducted in addition to raw biomass torrefaction. TG/MS analysis (a combination of thermogravimetric analysis with mass spectrometry analysis) was performed in the research. The optimal torrefaction conditions for willow were identified as an average temperature of 245 °C and a residence time of 14 min, resulting in the lowest mass loss (30.15%). However, it was noted that the composition of torgas, a by-product of torrefaction, presents challenges in providing a combustible gas with sufficient heat flux to meet the energy needs of the process. Prolonged residence times over 15 min and higher average temperatures above 250 °C lead to excessive energy losses from volatile torrefaction products, making them suboptimal for willow. On the other hand, the co-combustion of torrefied biomass with hard coal offers advantages in reduced sulfur emissions but can lead to increased NOx emissions when biomass with a higher nitrogen content is co-combusted in proportions exceeding 50% biomass. This paper summarizes findings related to optimizing torrefaction conditions, challenges in torgas composition, and the emissions implications of co-combustion.

This paper presents an analysis of methods to increase the efficiency of heat transfer in heat exchangers. The scope of the research included analysis of efficiency optimization using the example of two tubular heat exchanger structures most often used in industry. The obtained efficiency of heat recovery from the ground of the examined exchangers was over 90%, enabling the reduction of emissions of the heating systems of buildings. The paper presents the results of tests of two types of heat pipes using R134A, R404A, and R407C working agents. The paper also presents the results of experimental tests using the R410A working medium. The results included in the study will also enable the effective use of land as a heat store.