Steel slag is one of the most common waste products from the steelmaking industry. Conventional methods of slag disposal can cause negative impacts on humans and the environment. In this paper, the process of steel and steel slag production, physical and chemical properties, and potential options of slag recycling were reviewed. Since steel is mainly produced through an electric arc furnace (EAF) in Malaysia, most of the recycling options reviewed in this paper focused on EAF slag and the strengths and weaknesses of each recycle option were outlined. Based on the reports from previous studies, it was found that only a portion of EAF slag is recycled into more straightforward, but lower added value applications such as aggregates for the construction industry and filter/absorber for wastewater treatments. On the other hand, higher added value recycling options for EAF slag that are more complicated such as incorporated as raw material for Portland cement and ceramic building materials remain at the laboratory testing stage. The main hurdle preventing EAF slag from being incorporated as a raw material for higher added value industrial applications is its inconsistent chemical composition. The chemical composition of EAF slag can vary based on the scrap metal used for steel production. For this, mineral separation techniques can be introduced to classify the EAF slag base on its physical and chemical compositions. We concluded that future research on recycling EAF slag should focus on separation techniques that diversify the recycling options for EAF slag, thereby increasing the waste product’s recycling rate.
18 February 2019 in Soldering & Surface Mount Technology
Purpose: The purpose of this paper is to review and examine three of the most common corrosion characterization techniques specifically on Sn-Zn solders. The discussion will highlight the configurations and recent developments on each of the compiled characterization techniques of potentiodynamic polarization, potentiostatic polarization and electrochemical impedance spectroscopy (EIS).Design/methodology/approach: The approach will incorporate a literature review of previous works related to the experimental setups and common parameters.Findings: The potentiostatic polarization, potentiodynamic polarization and EIS were found to provide crucial and vital information on the corrosion properties of Sn-Zn solders. Accordingly, this solder relies heavily on the amount of Zn available because of the inability to produce the intermetallic compound in between the elements. Further, the excellent mechanical properties and low melting temperature of the Sn-Zn solder is undeniable, however, the limitations regarding corrosion resistance present opportunities in furthering research in this field to identify improvements. This is to ensure that the corrosion performance can be aligned with the outstanding mechanical properties. The review also identified and summarized the advantages, recent trends and important findings in this field.Originality/value: The unique challenges and future research directions regarding corrosion measurement in Sn-Zn solders were shown to highlight the rarely discussed risks and problems in the reliability of lead-free soldering. Many prior reviews have been undertaken of the Sn-Zn system, but limited studies have investigated the corrosive properties. Therefore, this review focuses on the corrosive characterizations of the Sn-Zn alloy system.
An ionic liquid (IL) 1-ethyl, 2-methyl imidazolium thiocyanate incorporated biopolymer system is reported in this communication for applications in dual energy devices, i.e., electric double-layer capacitors (EDLCs) and dye-sensitized solar cells (DSSCs). The solution caste method has been used to synthesize ionic-liquid-incorporated biopolymer electrolyte films. The IL mixed biopolymer electrolytes achieve high ionic conductivity up to the order of 10−3 S/cm with good thermal stability above 250 °C. Electrical, structural, and optical studies of these IL-doped biopolymer electrolyte films are presented in detail. The performance of EDLCs was evaluated using low-frequency electrochemical impedance spectroscopy, cyclic voltammetry, and constant current charge–discharge, while that of DSSCs was assessed using J–V characteristics. The EDLC cells exhibited a high specific capacitance of 200 F/gram, while DSSCs delivered 1.53% efficiency under sun conditions.
This study aims to optimize the composition (body formulation) and firing temperature of sustainable ceramic clay-based ceramics incorporated with electric arc furnace (EAF) steel slag waste using general full factorial design (GFFD). The optimization is necessary to minimize drawbacks of high iron oxide’s fluxing agent (originated from electric arc furnace, EAF steel slag waste), which led to severe surface defects and high closed porosity issue of the ceramics. Statistical analysis of GFFD including model adequacy checking, analysis of variance (ANOVA), interaction plots, regression model, contour plot and response optimizer were conducted in the study. The responses (final properties of ceramics) investigated were firing shrinkage, water absorption, apparent porosity, bulk density and modulus of rupture (MOR). Meanwhile, the factors employed in experimental parameters were weight percentage (wt.%) of EAF slag added and firing temperature. Upon statistical analysis, GFFD has deduced that wt.% amount of EAF slag added and firing temperatures are proven to significantly influence the final properties of the clay-based ceramic incorporated with EAF slag. The results of conducted statistical analysis were also highly significant and proven valid for the ceramics. Optimized properties (maximum MOR, minimum water absorption and apparent porosity) of the ceramic were attained at 50 wt.% of EAF slag added and firing temperature of 1180 °C.
Biobased toughened thermosetting polymer blend was prepared by incorporating epoxidized soybean oil (ESO) into a petroleum-based epoxy (DGEBA) in different composition ratios. The mechanical properties (tensile and flexural tests) of the ESO/DGEBA thermoset blends were determined. Thermal properties of the blends were characterized using thermogravimetric analysis. The result showed that, the tensile and flexural properties decreased with increasing of ESO content. However, a slight increase in the strength properties was observed at 10% of ESO content. A significant enhancement in impact strength proves the role of ESO acting as a plasticizer in the blends as well as improve the toughness properties of ESO/DGEBA thermoset blend. As the ESO content increase, the thermal stability of ESO/DGEBA thermoset blend has decreased might be due to reduced cross-linking density of the epoxy network. Further investigations on morphological properties were also done to correlate the mechanical properties of ESO/DGEBA thermoset blend.
This study was conducted to the physical and mechanical properties of particleboard sample manufactured from oil palm trunk (Elaesis quineensis) using glutardialadehyde as replacement for urea formaldehyde resin. Density that was used is 0.6 g/cm3, 0.7 g/cm3 and 0.8 g/cm3 to compare the durability of the each particleboard with the dimension of 21 cm × 21 cm × 0.5 cm. Binderless particleboards were made by using hot pressing system at temperature 150 °C for 10 minutes. The method used is based on previous studies and according to Japanese Industrial Standard, JIS A-5908 2003. The physical and mechanical properties of the study consist of density test, moisture content test, water absorption and thickness swelling test, and also bending test. From this study it was found that 0.7 g/cm3 density level particleboard was the optimum density level that gives the highest MOR. The moisture content also shows lowest reading in density level 0.7 g/cm3. The result for all the water absorption test and thickness swelling test were at density level 0.7 g/cm3 were the optimum density level.