The approach of the present work is based on the use of poly (methylmethacrylate) (PMMA) polymer, which is compatible with PVDF and TiO₂ nanoparticles in casting solutions, for the preparation of nano-composites membranes using a safer and more compatible solvent. TiO₂ embedded poly (vinylidene fluoride) (PVDF)/PMMA photocatalytic membranes were prepared by phase inversion method. A non-solvent induced phase separation (NIPS) coupled with vapor induced phase separation (VIPS) was used to fabricate flat-sheet membranes using a dope solution consisting of PMMA, PVDF, TiO₂, and triethyl phosphate (TEP) as an alternative non-toxic solvent. Membrane morphology was examined by scanning electron microscopy (SEM). Backscatter electron detector (BSD) mapping was used to monitor the inter-dispersion of TiO₂ in the membrane surface and matrix. The effects of polymer concentration, evaporation time, additives and catalyst amount on the membrane morphology and properties were investigated. Tests on photocatalytic degradation of methylene blue (MB) were also carried out using the membranes entrapped with different concentrations of TiO₂. The results of this study showed that nearly 99% MB removal can be easily achieved by photocatalysis using TiO₂ immobilized on the membrane matrix. Moreover, it was observed that the quantity of TiO₂ plays a significant role in the dye removal.

Photocatalytic TiO₂-PVDF/PMMA nano-composites flat sheet membranes were fabricated by phase inversion and then employed in a crossflow filtration pilot to remove model pollutants of various sizes and charge from aqueous solution. The dope solution contained a mixture of PVDF and PMMA as polymers, polyethylene glycol (PEG) and polyvinylpyrrolidone (PVP) as additives, triethyl phosphate (TEP) as green solvent and TiO₂ as immobilized photo catalyst. After undergoing characterization tests such as SEM morphology thickness, porosity, contact angle and water permeability, the membranes were used to eliminate the model pollutants from synthetic aqueous solution. The impact of the operating conditions (i.e., pH, pressure and initial pollutant concentration) and composition of the doping solution on the performance and photocatalytic and antifouling activity of the membranes was investigated. The results showed that Congo Red and Tartrazine despite their small size were rejected at 99% and 81%, respectively, because of their negative charge, while Ciprofloxacin, which is larger than Tartrazine but of neutral charge, crossed the membrane. The permeability did not decrease with a decline in pollutant concentration but diminished when the pressure increased and was reduced by more than half for wastewater.

The results of a feasibility study are presented on the use of a polystyrene (PS) organic membrane as a photocatalyst support in the degradation of organic pollutants in aqueous solution. Methylene blue (MB) was employed as a model dye and commercial titanium dioxide (TiO₂) was used as a photocatalyst. The MB dye which is resistant to direct photolysis especially at high concentrations was successfully eliminated by TiO₂ fixed on the PS membrane in aqueous dispersion under solar irradiation. Photodegradation results of MB showed that the film with 10 wt% TiO₂ exhibited a remarkable ultraviolet (sun light) photocatalytic activity over 5 h, with 68% of the pollutant being degraded. This is similar to a TiO₂ slurry system. The photocatalytic degradation obeyed pseudo-first-order kinetics at low initial MB concentration. The optimum pH for efficient removal of dye was found to be 11. An increase in initial dye concentration decreased the degradation rate. The applicability of Langmuir–Hinshelwood kinetic equation revealed that the degradation of MB occurred mainly on the surface of the photocatalyst. The concept and results provide a promising platform for fabricating highly efficient organic photocatalytic membranes for water treatment.

The present study aimed to investigate the adsorption capacity of two anionic dyes, namely, Congored (CR) and Coralene Dark Red2B (DR), onto prepared alginate (Alg) and chitosan(Cs) biopolymer films. The two biopolymers were combined at different mass ratios using a “solvent-cast” process to incorporate their unique properties and evaluate their effectiveness in removing the dyes. All samples were characterized by means of Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), scanning electron microscopy (SEM) and determination of point of zero charge (pH_pzc). The swelling ratios were determined by gravimetric measurements. The effects of pH, adsorption time, thickness, temperature and initial concentration of CR and DR dyes on the adsorption results were studied systematically. The dye adsorption kinetics showed that the Alg/Cs films at % proportions of 75/25, 50/50, 25/75 and 0/100 reached equilibrium from 30 min to 180 min with high removal efficiencies that varied between 222.30 mg/g and 842.36 mg/g. The adsorption mechanism of CR and DR onto the synthesized biofilms was confirmed through Langmuir isotherm and the kinetics fitted well by the pseudo-second-order model, suggesting a monolayer and chemisorption process. The thermodynamic results demonstrated the spontaneity and the feasibility of the process as well as the exothermic nature. Hence, the findings revealed that the Alg/Cs biofilms could be employed as potential natural adsorbents for the removal of anionic dye pollutants from aqueous environments.

Experiments were conducted with a commercial membrane distillation module, which has an air-gap membrane distillation (AGMD) and spiral-wound configuration. Tests were performed simulating the salinity and temperature of the water using as a case study the Albian aquifer in Algeria. Solar thermal energy from a field of stationary flat-plate solar collectors was supplied to the module. The total productivity of the AGMD system was analyzed for different operational conditions and compared with that from the RO system. The effect of brackish water temperature on the energy consumption was scrutinized, and the energy requirements assessed toward the design of a pilot unit for decentralized autonomous solar desalination. Results showed that for producing a higher volume of distillate, module with less surface area is better. Also, it was found that recovery ratio increases linearly with the temperature difference in both modules. The maximum value was 6% for the highest feed flow rate operated in module 1 with highest surface area. These values are much lower than those obtained with RO processes, which can reach 45%.

A quantitative and qualitative analysis was performed on treated wastewater to see if it can be used for irrigation, using as a case study the effluent from a wastewater treatment plant in Chlef, Algeria. The results showed that the average removal efficiencies of suspended solids (TSS), chemical oxygen demand (COD), and biochemical oxygen demand (BOD5) were 88, 94, and 98%, respectively. The average effluent concentrations ranged from 3 to 29 mg/L for TSS, 30 to 57 mg/L for COD, and 3 to 8.9 mg/L for BOD5. All were within the World Health Organization standards. Furthermore, the total coliform concentration of the treated wastewater was also within the national and international standards. There was an absence of toxic micro-pollutants such as heavy metals, which suggests that treated water can be used as an alternative water resource for irrigation. The reuse of treated wastewater is both a political and socioeconomic challenge. However, this route may help to alleviate water shortages by better conserving natural resources and also contributing to the development of integrated water management systems.