The aim of this paper is to evaluate the influence of small variations in chemical composition on the corrosion resistance and mechanical properties of low-manganese and medium manganese high strength steels. Six different steels with manganese content varying from 1.5 to 4.0 wt.% and aluminium from 0.008 to 6.5 wt.% were subjected to the analysis. The other subjects for evaluation included the effect of aluminium as a replacement for silicon, niobium microalloying and the effect of heat treatment. The effect of non-metallic inclusions on localized corrosion initiation and propagation was also documented. Using potentiodynamic testing, exposure testing, tensile and impact testing, it was found that the improvement in corrosion resistance associated with increasing aluminium content is accompanied by a significant deterioration of the mechanical properties. Niobium microalloying and heat treatment was found to have no quantifiable impact on the anti-corrosion properties. The effect of aluminium content proved to be superior to the effect of nonmetallic inclusions in terms of determining the overall corrosion resistance of the experimental steels.

The microstructure, mechanical, tribological, and corrosion properties of Fe–Cr–Al–Y-based oxide-precipitation-hardened (OPH) alloy at room temperature are presented. Two OPH alloys with a composition of 0.72Fe–0.15Cr–0.06Al–0.03Mo–0.01Ta–0.02Y₂O₃ and 0.03Y₂O₃ (wt.%) were prepared by mechanical alloying with different milling times. After consolidation by hot rolling, the alloys presented a very fine microstructure with a grain size of approximately 180 nm. Such a structure is relatively brittle, and its mechanical properties are enhanced by heat treatment. Annealing was performed at three temperatures (1000 °C, 1100 °C, and 1200 °C), with a holding time from 1 to 20 h. Tensile testing, wear testing, and corrosion testing were performed to evaluate the effect of heat treatment on the behavior and microstructural properties. The grain size increased almost 10 times by heat treatment, which influenced the mechanical properties. The ultimate tensile strength increased up to 300% more compared to the initial state. On the other hand, heat treatment has a negative effect on corrosion and wear resistance.

This paper introduces a new alloying concept for low-density steels. Based on model calculations, samples—or “heats”—with 0.7 wt% C, 1.45 wt% Si, 2 wt% Cr, 0.5 wt% Ni, and an aluminium content varying from 5 to 7 wt% are prepared. The alloys are designed to obtain steel with reduced density and increased corrosion resistance suitable for products subjected to high dynamic stress during operation. Their density is in the range from 7.2 g cm⁻³ to 6.96 g cm⁻³. Basic thermophysical measurements are carried out on all the heats to determine the critical points of each phase transformation in the solid state, supported by metallographic analysis on SEM and LM or the EDS analysis of each phase. It is observed that even at very high austenitisation temperatures of 1100 °C, it is not possible to change the two-phase structure of ferrite and austenite. A substantial part of the austenite is transformed into martensite during cooling at 50 °C s⁻¹. The carbide kappa phase is segregated at lower cooling rates (around 2.5 °C s⁻¹).