According to the European Research and Innovation Policy Agenda, nature-based solutions (NBSs) are key technologies to improve the sustainability of urban areas. Among NBSs, green walls have been recently studied for several applications, among the others the treatment of lowly polluted wastewater flows as greywater (GW, e.g. domestic wastewater excluding toilet flushes). This work is aimed at the evaluation of the influence of four additives (compost, biochar, granular activated carbon, polyacrylate) mixed with a base filter medium made of coconut fibre and perlite, on the performances of a green wall fed in batch mode with synthetic GW. The green wall was operated with a high hydraulic loading rate of GW (740.8 L/m²/day) in open-air winter conditions (3.5-15 °C measured for GW) between January and April. The performances of the green wall have been assessed though the monitoring every 1-2 weeks of physicochemical and biological parameters (pH, electric conductivity, total suspended solids, dissolved oxygen, BOD₅ and COD, nitrogen and phosporus compounds, chlorides and sulphates, anionic surfactants and E. coli). Removal performances were excellent for BOD₅ (>95%) and E.coli (>98%) for all additives; compared to the base medium, biochar was the best performing additive over the highest number of parameters, achieving removals equal to 51% for COD, 47% for TKN and nitric nitrogen and 71% for anionic surfactants. Compost also achieved high removal performances, but the frequent clogging events occurred during the monitoring period do not make its use recommendable. Granular activated carbon and the combination of biochar and polyacrylate performed better than the base medium, but only about the removal of nitric nitrogen. These results demonstrated that, in the considered experimental boundaries, biochar could improve the overall treatment performances of a green wall fed by GW and operated in challenging conditions.

Wine lees have a great potential to obtain clean energy in the form of biogas through anaerobic digestion due to their high organic load. However, wine lees are a complex substrate and may likely give rise to instabilities leading to failure of the biological process. This work analysed the digestion of wine lees using two different approaches. First, electro-oxidation was applied as pre-treatment using boron-doped diamond-based electrodes. The voltage was 25 V and different treatment times were tested (ranging from 0.08 to 1.5 h) at 25 °C. Anaerobic digestion of wine lees was evaluated in batch tests to investigate the effect of electro-oxidation on biogas yield. Electro-oxidation exhibited a significant positive effect on biogas production increasing its value up to 330 L kg⁻¹ of volatile solids after 1.5 h of treatment, compared to 180 L kg⁻¹ of volatile solids measured from raw wine lees. As a second approach, the addition of biochar to the anaerobic digestion of wine lees was investigated; in the experimental conditions considered in the present study, the addition of biochar did not show any positive effect on anaerobic digestion performance.

Biochar (BC) recently gained attention as an additive for anaerobic digestion (AD). This work aims at a critical analysis of the effect of six BCs, with different physical and chemical properties, on the AD of mixed wastewater sludge at 37 °C, comparing their influence on methane production and AD kinetics. AD batch tests were performed at the laboratory scale operating 48 reactors (0.25 L working volume) for 28 days with the addition of 10 g L⁻¹ of BC. Most reactors supplemented with BCs exhibited higher (up to 22%) methane yields than the control reactors (0.15 Nm³ kg_VS⁻¹). The modified Gompertz model provided maximum methane production rate values, and in all reactors the lag-phase was equal to zero days, indicating a good adaptation of the inoculum to the substrate. The potential correlations between BCs’ properties and AD performance were assessed using principal component analysis (PCA). The PCA results showed a reasonable correlation between methane production and the BCs’ O–C and H–C molar ratios, and volatile matter, and between biogas production and BCs’ pore volume, specific surface area, and fixed and total carbon. In conclusion, the physic-chemical properties of BC (specifically, hydrophobicity and morphology) showed a key role in improving the AD of mixed wastewater sludge.