The seasonal changes in ambient mass concentrations and chemical composition of fine particulate matter (PM_2.5) were investigated in three locations in Poland. The analyses included PM_2.5-bound hazardous benzo(a)pyrene (BaP), As, Ni, Cd, and Pb. The samples of PM_2.5 were collected daily in Katowice (southern Poland, urban background site), Gdańsk, and Diabla Góra (northern Poland, urban and regional background sites, respectively) during 1-year-long campaign in 2010. Based on monthly ambient concentrations of PM_2.5-bound carbon (organic and elemental), water-soluble ions (Na⁺, NH₄ ⁺, K⁺, Mg²⁺, Ca²⁺, Cl⁻, NO₃ ⁻, SO₄ ²⁻), and elements As, Ni, Cd, Pb, Ti, Al, Fe, the chemical mass closure of PM_2.5 was checked for each of the four seasons of the year and for the heating and non-heating periods at each site. Also, the annual concentrations of PM_2.5 were determined and the annual PM_2.5 mass closure checked. At each measuring point, the PM_2.5 concentrations were high compared to its Polish yearly permissible value, 25 μg/m³, and its concentrations elsewhere in Europe. The highest annual PM_2.5 concentration, 43 μg/m³, occurred in Katowice; it was twice the annual PM_2.5 concentration in Gdańsk, and thrice the one in Diabla Góra. The high annual averages were due to very high monthly concentrations in the heating period, which were highest in the winter. PM_2.5 consisted mainly of carbonaceous matter (elemental carbon (EC) + organic matter (OM), the sum of elemental carbon, EC, and organic matter, OM; its annual mass contributions to PM_2.5 were 43, 31, and 33 % in Katowice, Gdansk, and Diabla Góra, respectively), secondary inorganic aerosol (SIA), the Na_Cl group, and crustal matter (CM)—in the decreasing order of their yearly mass contributions to PM_2.5. OM, EC, SIA, Na_Cl, and CM accounted for almost 81 % of the PM_2.5 mass in Katowice, 74 % in Gdańsk, and 90 % in Diabla Góra. The annual average toxic metal contribution to the PM_2.5 mass was not greater than 0.2 % at each site. In Katowice and Gdańsk, the yearly ambient BaP concentrations were high (15.4 and 3.2 ng/m³, respectively); in rural Diabla Góra, the concentrations of BaP were almost equal to 1 ng/m³, the Polish BaP annual limit. The great seasonal fluctuations of the shares of the component groups in PM_2.5 and of the concentrations of PM_2.5 and its components are due to the seasonal fluctuations of the emissions of PM and its precursors from hard and brown coal combustion for energy production, growing in a heating season, reaching maximum in winter, and decreasing in a non-heating period. In Gdańsk, northern Poland, especially in the spring and autumn, sea spray might have affected the chemical composition of PM_2.5. The greatest hazard from PM_2.5 occurs in Katowice, southern Poland, in winter, when very high concentrations of PM_2.5 and PM_2.5-related carbonaceous matter, including BaP, are maintained by poor natural ventilation in cities, weather conditions, and the highest level of industrialization in Poland. In less industrialized northern Poland, where the aeration in cities is better and rather gaseous than solid fuels are used, the health hazard from ambient PM_2.5 is much lower.

Assessment of exposure to polycyclic aromatic hydrocarbons (PAHs) is important due to the widespread presence of PAHs in the environment and their toxicological relevance, especially to susceptible populations such as children and their health. The aim of this study is to compare indoor and outdoor concentrations of particulate matter with a diameter of 2.5 μm or less (PM2.5) and 15 individual PAHs, as well as contribution of the analyzed PAHs to mutagenic and carcinogenic activity. Samples were collected during spring season in two sites in southern Poland (Silesia) representing urban and rural areas. Indoor samples of PM2.5 were sampled in kindergartens. At the same time, in the vicinity of the kindergarten buildings, the collection of the outdoor PM2.5 samples was carried out. Mutagenic (MEQ) and carcinogenic (TEQ) equivalents related to BaP and the percentage share expressed as mutagenic (MP) and carcinogenic (CP) potential of each individual compound to the total mutagenic/carcinogenic potential of the PAH mixture were calculated. The obtained results show that high concentrations of PM2.5 (above 25 μg/m³) and 15 PM2.5-bound PAHs in outdoor and indoor air were similar in the two studied areas. In overall PAHs mutagenic and carcinogenic potential, the percentage share of benzo(a)pyrene (BaP) was dominant and varied from 49.0–54.5% to 62.5–70.0%, respectively. The carried out study indicates the necessity of reducing PAH emission from solid fuel combustion, which is reflected in PM2.5-bound PAHs concentrations and their diagnostic ratios. In the recent years, health effects on children resulting from their activity pattern and air quality in the public places have been a serious problem.

Along with house heating and industry, emissions from road traffic (exhaust and tire, brake, car body or road surface abrasions) are one of the primary sources of particulate matter (PM) in the atmosphere in urban areas. Though numerous regulations and vehicle-control mechanisms have led to a significant decline of PM emissions from vehicle exhaust gases, other sources of PM remain related to road and car abrasion are responsible for non-exhaust emissions. Quantifying these emissions is a hard problem in both laboratory and field conditions. First, we must recognize the physicochemical properties of the PM that is emitted by various non-exhaust sources. In this paper, we underline the problem of information accessibility with regards to the properties and qualities of PM from non-exhaust sources. We also indicate why scarce information is available in order to find the possible solution to this ongoing issue.

Forty-nine components of ambient particulate matter (PM) in size-fractionated PM were investigated at an urban background site in Katowice (Silesian Agglomeration in Southern Poland) in the non-heating season of 2012. PM was analyzed for two groups of carbon compounds (organic (OC) and elemental (EC) carbon, Lab OC-EC Aerosol Analyzer), five major water-soluble ions (NH₄ ⁺, Cl⁻, SO₄ ²⁻, NO₃ ⁻, and Na⁺ contents in PM water extracts, ion chromatography), 26 elements (X-ray fluorescence spectrometry), and 16 polycyclic aromatic hydrocarbons (PAHs, gas chromatography). The distributions of the masses of these components among 13 basic PM fractions were determined, and chemical mass closure was checked for each of these fractions separately. The particles having their aerodynamic diameters in the interval 0.03–0.26 μm, the fraction PM_0.03–0.26, contributed about 13 % to the total PM mass. This PM fraction consisted of primary particles predominantly composed of various inorganic compounds, primary organic compounds, and, in lesser amounts, of elemental carbon, secondary ions, and secondary organic compounds. The second particle fraction, PM_0.26–1.6, consisted mainly of secondary matter, and its mass contribution to the total PM mass was about 59 %. The third fraction, PM_1.6–40, was a fraction of coarse particles composed of mineral/soil and organic matter and elemental carbon. It contributed to the PM mass about 28 %. For each of PM_0.03–0.26, PM_0.26–1.6, and PM_1.6–40, the health hazard from its 16 PAH contents was determined by computing toxicity factors. PM_0.26–1.6 posed the greatest health hazard from the mixture of the 16 PAHs that it contained, PM_1.6–40 was the next, and the hazard from the PM_0.03–0.26-bound 16 PAHs was the smallest. The molecular diagnostic ratios computed for these three fractions were specific for coal and wood combustion; some indicated the road traffic effects.