Without fillers, rubber types such as silicone rubber exhibit poor mechanical, thermal, and electrical properties. Carbon black (CB) is traditionally used as a filler in the rubber matrix to improve its properties, but a high content (nearly 60 per hundred parts of rubber (phr)) is required. However, this high content of CB often alters the viscoelastic properties of the rubber composite. Thus, nowadays, nanofillers such as graphene (GE) and carbon nanotubes (CNTs) are used, which provide significant improvements to the properties of composites at as low as 2–3 phr. Nanofillers are classified as those fillers consisting of at least one dimension below 100 nanometers (nm). In the present review paper, nanofillers based on carbon nanomaterials such as GE, CNT, and CB are explored in terms of how they improve the properties of rubber composites. These nanofillers can significantly improve the properties of silicone rubber (SR) nanocomposites and have been useful for a wide range of applications, such as strain sensing. Therefore, carbon-nanofiller-reinforced SRs are reviewed here, along with advancements in this research area. The microstructures, defect densities, and crystal structures of different carbon nanofillers for SR nanocomposites are characterized, and their processing and dispersion are described. The dispersion of the rubber composites was reported through atomic force microscopy (AFM), transmission electron microscopy (TEM), and scanning electron microscopy (SEM). The effect of these nanofillers on the mechanical (compressive modulus, tensile strength, fracture strain, Young’s modulus, glass transition), thermal (thermal conductivity), and electrical properties (electrical conductivity) of SR nanocomposites is also discussed. Finally, the application of the improved SR nanocomposites as strain sensors according to their filler structure and concentration is discussed. This detailed review clearly shows the dependency of SR nanocomposite properties on the characteristics of the carbon nanofillers.

Zinc oxide performs as the best cure activator in sulfur-based vulcanization of rubber, but it is regarded as a highly toxic material for aquatic organisms. Hence, the toxic cure activator should be replaced by a non-toxic one. Still, there is no suitable alternative industrially. However, binary activators combining ZnO and another metal oxide such as MgO can largely reduce the level of ZnO with some improved benefits in the vulcanization of rubber as investigated in this research. Curing, mechanical, and thermal characteristics were investigated to find out the suitability of MgO in the vulcanization of rubber. Curing studies reveal that significant reductions in the optimum curing times are found by using MgO as a co-cure activator. Especially, the rate of vulcanization with conventional 5 phr (per hundred grams) ZnO can be enhanced by more than double, going from 0.3 Nm/min to 0.85 Nm/min by the use of a 3:2 ratio of MgO to ZnO cure activator system that should have high industrial importance. Mechanical and thermal properties investigations suggest that MgO as a co-cure activator used at 60% can provide 7.5% higher M100 (modulus at 100% strain) (0.58 MPa from 0.54 MPa), 20% higher tensile strength (23.7 MPa from 19.5 MPa), 15% higher elongation at break (1455% from 1270%), 68% higher fracture toughness (126 MJ/m³ from 75 MJ/m³), and comparable thermal stability than conventionally using 100 % ZnO. Especially, MgO as a co-cure activator could be very useful for improving the fracture toughness in rubber compounds compared to ZnO as a single-site curing activator. The significant improvements in the curing and mechanical properties suggest that MgO and ZnO undergo chemical interactions during vulcanization. Such rubber compounds can be useful in advanced tough and stretchable applications.

The integration of smart nanomaterials into pharmaceutics has transformed approaches to disease diagnosis, targeted therapy, and tissue regeneration. These nanoscale materials exhibit unique features such as controlled responsiveness, biocompatibility, and precise site-specific action, offering new possibilities for personalized healthcare. This review provides a comprehensive overview of recent advances in the design and application of functional nanomaterials, including nanoparticle-based drug carriers, responsive hydrogels, and nanostructured scaffolds. Special focus is placed on stimuli-triggered systems that achieve controlled drug release and localized therapeutic effects. In addition, the review explores how these materials enhance diagnostic imaging and support tissue regeneration through adaptive and multifunctional designs. Importantly, this work uniquely integrates stimuli-responsive nanomaterials across therapeutic, imaging, and regenerative domains, providing a unified view of their biomedical potential. The challenges of clinical translation, large-scale synthesis, and regulatory approval are critically analyzed to outline future directions for research and real-world implementation. Overall, this review highlights the pivotal role of smart nanomaterials in advancing modern pharmaceutics toward more effective and patient-centered therapies.

This review article focuses on the potential of cobalt oxide composites with conducting polymers, particularly polypyrrole (PPy) and polyaniline (PANI), as advanced electrode materials for supercapacitors, batteries, and supercapatteries. Cobalt oxide, known for its high theoretical capacitance, is limited by poor conductivity and structural degradation during cycling. However, the integration of PPy and PANI has been proven to enhance the electrochemical performance through improved conductivity, increased pseudocapacitive effects, and enhanced structural integrity. This synergistic combination facilitates efficient charge transport and ion diffusion, resulting in improved cycling stability and energy storage capacity. Despite significant progress in synthesis techniques and composite design, challenges such as maintaining structural stability during prolonged cycling and scalability for mass production remain. This review highlights the synthesis methods, latest advancements, and electrochemical performance in cobalt oxide/PPy and cobalt oxide/PANI composites, emphasizing their potential to contribute to the development of next-generation energy storage devices. Further exploration into their application, especially in battery systems, is necessary to fully harness their capabilities and meet the increasing demands of energy storage technologies.

Energy harvesting systems fabricated from rubber composite materials are promising due to their ability to produce green energy with no environmental pollution. Thus, the present work investigated energy harvesting through piezoelectricity using rubber composites. These composites were fabricated by mixing titanium carbide (TiC) and molybdenum disulfide (MoS₂) as reinforcing and electrically conductive fillers into a silicone rubber matrix. Excellent mechanical and electromechanical properties were produced by these composites. For example, the compressive modulus was 1.55 ± 0.08 MPa (control) and increased to 1.95 ± 0.07 MPa (6 phr or per hundred parts of rubber of TiC) and 2.02 ± 0.09 MPa (6 phr of MoS₂). Similarly, the stretchability was 133 ± 7% (control) and increased to 153 ± 9% (6 phr of TiC) and 165 ± 12% (6 phr of MoS₂). The reinforcing efficiency (R.E.) and reinforcing factor (R.F.) were also determined theoretically. These results agree well with those of the mechanical property tests and thus validate the experimental work. Finally, the electromechanical tests showed that at 30% strain, the output voltage was 3.5 mV (6 phr of TiC) and 6.7 mV (6 phr of MoS₂). Overall, the results show that TiC and MoS₂ added to silicone rubber lead to robust and versatile composite materials. These composite materials can be useful in achieving higher energy generation, high stretchability, and optimum stiffness and are in line with existing theoretical models.

The latest progress (the year 2021–2024) on multifunctional sensors based on silicone rubber is reported. These multifunctional sensors are useful for real-time monitoring through relative resistance, relative current change, and relative capacitance types. The present review contains a brief overview and literature survey on the sensors and their multifunctionalities. This contains an introduction to the different functionalities of these sensors. Following the introduction, the survey on the types of filler or rubber and their fabrication are briefly described. The coming section deals with the fabrication methodology of these composites where the sensors are integrated. The special focus on mechanical and electro-mechanical properties is discussed. Electro-mechanical properties with a special focus on response time, linearity, and gauge factor are reported. The next section of this review reports the filler dispersion and its role in influencing the properties and applications of these sensors. Finally, various types of sensors are briefly reported. These sensors are useful for monitoring human body motions, breathing activity, environment or breathing humidity, organic gas sensing, and, finally, smart textiles. Ultimately, the study summarizes the key takeaway from this review article. These conclusions are focused on the merits and demerits of the sensors and are followed by their future prospects.