Soil batch leaching tests are conducted worldwide to quantify the leaching of hazardous substances from contaminated soil. In the extracts of soil batch leaching tests, some inorganic substances such as arsenic and lead are released both in colloidal and dissolved form. Recent studies have found that soil colloidal particles with small diameters persist in the filtrate even after the extracts are filtered through a membrane filter (MF) with a pore size of 0.45 μm, and they might affect the concentration of arsenic or lead. This study evaluated the effects of 0.45- or 0.4-μm MF materials on filtrate turbidity and leaching concentrations of inorganic hazardous elements during batch leaching tests. Turbidity and arsenic and lead concentrations in the filtrates of the tested soil samples varied greatly depending on the MF material. These findings indicate that the MF material affects the removal rate of colloidal arsenic or lead and therefore affects the results of leaching tests.
The construction industry is one of the key industries with high potential for the circular economy; the promotion of reuse and recycling of construction and demolition waste (CDW) is essential for sustainable urban development. In this study, a series of compaction, California bearing ratio, saturated hydraulic conductivity, and particle breakage tests of well– and poor–graded mixtures of recycled clay brick aggregates (RCBs) and recycled concrete aggregates (RCAs) with maximum aggregate diameters of 19, 25, and 37.5 mm were carried out to examine the practical application of those mixtures to unbound roadbed materials in Vietnam. The experimental results suggest that the maximum amount of RCBs added to RCAs should be less than 30% when applied to unbound roadbed materials. In addition, it was found that the mixing proportions of RCBs and RCAs and the maximum aggregate diameter, gradation of aggregates, and initial moisture condition control the saturated hydraulic conductivity. Further, the particle breakage characteristics under compaction were carefully examined, and it was found that the percentage increment/decrement, as well as a newly introduced method of estimating the mixing proportions of RCAs and RCBs in the fine fraction (<2.36 mm), is effective in understanding the mechanism of particle breakage of RCA and RCB mixtures.
Adsorption parameters such as the distribution coefficient are required to predict the release behavior of contaminants using advection-dispersion models. However, for potentially contaminant-releasing materials (PCMs) such as dredged sludge and coal ash, these parameters cannot be obtained by conventional adsorption tests. This study developed a method to determine adsorption parameters for PCMs from a set of batch tests conducted in parallel as a function of the liquid-solid ratio (LS-parallel test). This LS-parallel test was performed on sandy soil derived from marine sediment using liquid-solid ratios from 1 to 300 L/kg. The water-contact time was also changed from 10 min to 28 d to elucidate the kinetics or equilibrium of contaminants released from the sample. Adsorption parameters were successfully obtained if the substance was under adsorption control. A column percolation test was performed to confirm the effectiveness of the obtained parameters. Good agreements were observed for SO42− and B, but discrepancies remained for other substances such as F− and As suggesting that improvements are necessary in both the LS-parallel test procedure and the advection-dispersion model.