Waste-derived materials obtained from the recovery and recycling of electronic waste (e-waste) such as batteries and printed circuit boards have attracted enormous attention from academia and industry in recent years, especially due to their eco-friendly nature and the massive increment in e-waste due to technological development. Several investigations in the literature have covered the advances achieved so far. Meanwhile, photocatalytic applications are especially of interest since they maintain mutual benefits and can be used for H2 production from solar water splitting based on semiconductor processing as a proper environmentally friendly technique for solar energy conversion. In addition, they can be utilized to degrade a variety of organic and non-organic contaminations. Nonetheless, to the best of the authors’ knowledge, there has not been any comprehensive review that has specifically been focused on e-waste-derived photocatalytic materials. In this regard, the present work is dedicated to thoroughly discussing the related mechanisms, strategies, and methods, as well as the various possible photocatalysts synthesized from e-wastes with some critiques in this field. This brief overview can introduce modern technologies and promising possibilities for e-waste valorization, photocatalytic processes, and new photocatalytic degradation methods of eco-friendly nature. This paper discusses various e-waste-obtained photocatalytic materials, synthesis procedures, and applications, as well as several types of e-waste, derived materials such as TiO2, ZnO, indium tin oxide, and a variety of sulfide- and ferrite-based photocatalytic materials.
The thermo-mechanical behavior of nanosized Al2O3 particles reinforcing aluminum was analyzed in the present paper. The material was prepared by spark plasma sintering and friction stir welding. The thermal stresses affecting the composite behavior during welding were modeled through COMSOL MultiPhysics, and the results were validated by the analyses of the composites’ mechanical properties. The spark-plasma-sintered materials presented limited porosity, which was taken into account during the modeling phase. Both model and experiments revealed that higher heat input is related to better material mixing during welding and sound mechanical properties. Thermal stresses lead to residual stresses close to 300 MPa in the thermo-mechanically affected zone for processing conditions of 1900 RPM and 37 mm/min. This leads to an increase in hardness up to 72 HV.
Among different promising solutions, coupling closed-cell aluminium foam composite panels prepared by a powder metallurgical method with pore walls interconnected by microcracks, with low thermal conductivity phase change materials (PCMs), is one of the effective ways of increasing thermal conductivity for better performance of thermal storage systems in buildings. The internal structure of the foam formation, related to the porosity which decides the heat transfer rate, plays a significant role in the thermal energy storage performance. The dependence of the heat transfer characteristics on the internal foam structure is studied numerically in this work. The foamable precursor of 99.7% pure aluminium powder mixed with 0.15 wt.% of foaming agent, TiH2 powder, was prepared by compacting, and extruded to a volume of 20 × 40 × 5 mm. Two aluminium foam samples of 40 × 40 × 5 mm were examined with apparent densities of 0.7415 g/cm3 and 1.62375 g/cm3. The internal porous structure of the aluminium foam samples was modelled using X-ray tomography slices through image processing techniques for finite element analysis. The obtained numerical results for the heat transfer rate and effective thermal conductivity of the developed surrogate models revealed the influence of porosity, struts, and the presence of pore walls in determining the heat flow in the internal structure of the foam. Additionally, it was found that the pore size and its distribution determine the uniform heat flow rate in the entire foamed structure. The numerical data were then validated against the analytical predictions of thermal conductivity based on various correlations. It has been found that the simplified models of Bruggemann and Russell and the parallel–series model can predict the excellent effective thermal conductivity results of the foam throughout the porosity range. The optimal internal foam structure was studied to explore the possibilities of using aluminium foam for PCM-based thermal storage applications.
The internal pore wall structure formation and density play an important role in improving the mechanical and thermal properties of the closed-cell aluminium foams. The present research work aims to investigate the internal structure formation of the aluminium foam prepared by powder metallurgy and the uniformity of the distribution of the pores when the minimum amount of TiH2 is added. The foamable precursor of two different aluminium alloys (Al-1050 and A5083) is produced with a TiH2 gaseous agent of 0.05 wt.%. The parameters analysed include the density, pore wall formations, pore, and metal density distribution inside the structure with the help of X-ray tomography. Furthermore, the image-processing technique has been adopted to produce the 3D surrogate model of the foam for visual inspection and analysis. The obtained results show the importance of the amount of TiH2 addition and of the foaming furnace temperature in deciding the internal porous structure formation. Further, the pore morphology of lower porosity foams (in the range of 30-40 % porosity) of the two alloys produced at 690 °C furnace temperature is investigated with the help of developed surrogate models. The presence of micropores and uniformity of the distribution of pores found brings the idea of choosing the optimized structure of foam for thermal energy storage systems associated with PCM.