Sewage sludge management is a key concern in today’s world. Improper disposal can lead to various environmental issues including air, water and soil pollution. Among the available technologies, thermal treatments, particularly pyrolysis, are gaining interest for their ability to reduce sewage sludge volume and to recover materials and energy from it. This study explored the influence of some relevant parameters in the thermal pyrolysis process. The design of experiment, named central composite design, was accounted to optimize temperature, heating rate and residence time in order to maximize the biochar yield and its CO₂ adsorption capacity. A two-factor interaction model provided a satisfactory interpretation of the results. Within the studied ranges, maximum values of 47.8 wt% and 0.514 mol CO₂/kg were obtained for the yield and CO₂ adsorption capacity, respectively. Two significant experiments were repeated in a different pyrolysis system highlighting how other factors (e.g., reactor geometry, granulometry, etc.) can influence the quantity and the quality of produced biochar. The biochar obtained under the best pyrolysis conditions was characterized by a surface area of 124 m²/g and an ash content of 61 wt%. Lastly, the theoretical energy balance showed that the drying process is the main energy-intensive step in the pyrolysis of sewage sludge.

Mature landfill leachates are characterized by high levels of ammoniacal nitrogen which must be reduced for discharge in the sewer system and further treatment in municipal wastewater treatment plants. The use of anammox-based processes can allow for an efficient treatment of ammonium-rich leachates. In this work, two real scale sequencing batch reactors (SBRs), designed to initially perform partial nitritation/anammox (PN/A) and simultaneous partial nitrification and denitrification (SPND) for the treatment of ammonium-rich urban landfill leachate, were modelled using BioWin 6.0 in order to enable plant-wide modelling and optimizing. The constructed models were calibrated and validated using data from long- and short-term (one cycle) SBR operation and fit well to the main physical-chemical parameters (i.e., ammonium, nitrite and nitrate concentrations) measured during short-term (one cycle) operations. Despite the different strategies in terms of dissolved oxygen (DO) concentrations and aeration and mixing patterns applied for SBR operation, the models allowed for understanding that in both reactors the PN/A process was shown as the main contributor to nitrogen removal when the availability of organic carbon was low. Indeed, in both SBRs, the activity of nitrite oxidizing bacteria was inhibited due to high levels of free ammonia, whereas anammox bacteria were active due to the simultaneous presence of ammonium and nitrite and their ability to recover from DO inhibition. Increasing the external carbon addition, a prompt decrease of the anammox biomass was observed, with SPND becoming the main nitrogen removal mechanism. Models were also applied to estimate the production rates of nitrous oxide by aerobic ammonia oxidizing bacteria and heterotrophic denitrifiers. The models were found to be a robust tool for understanding the effects of different operating conditions (i.e, temperature, cycle phases, DO concentration, external carbon addition) on the nitrogen removal performances of the two reactors, assessing the contribution of the different bacterial groups involved.

In recent years, sewage sludge (SS) and bio-waste management have attracted increasing environmental attention. In this study, hydrothermal carbonization (HTC) technology is investigated in the framework of a co-treatment of sewage sludge digestate (SSD) and an organic fraction of municipal solid waste (OW). The proposed configuration integrates HTC with anaerobic digestion (AD) in an inter-stage configuration (AD1 + HTC + AD2). The effects of different percentages of OW added to SSD in the HTC treatment are evaluated in terms of characteristics and methane yield of the produced HTC liquor (HTCL) and HTC slurry (i.e., the mixture hydrochar-HTCL), as well as dewaterability of the HTC slurry. Results show that, with the increase in the percentage of OW in the OW-SSD mixture fed to the HTC process, production of biogas and biomethane of both HTC slurry and HTCL increases. The highest biogas production is achieved when a mixture consisting of half SSD and half OW is used, reaching 160 ± 10 and 240 ± 15 mL biogas g⁻¹ COD_added, respectively, for HTCL and HTC slurry. Furthermore, sludge dewaterability is significantly improved by the combined AD1-HTC-AD2 process. Finally, an energy assessment allows estimating that the co-treatment of OW with SSD in HTC can cover up to 100% of the energy consumption of the system.

A global shift towards renewable energy production, driven primarily by the challenges posed by climate change, is currently underway. In this context, the utilization of heat recovery from municipal wastewater emerges as a promising green technology. Notably, the advantage of implementing energy recovery in sewers, as opposed to wastewater treatment plants (WWTPs), lies in the higher temperature of the wastewater and its proximity to potential heat users. Despite these benefits, concerns arise regarding the potential adverse effects on biological wastewater treatment processes downstream of the heat recovery section, particularly during colder seasons. This paper seeks to assess the impact of a heat recovery system along the sewer network on the efficiency of biological wastewater treatment processes. The methodology involves a modeling analysis of a real sewage network in Italy. Under typical northern Italy climate conditions, the results demonstrate the feasibility of heat recovery in sewers for WWTPs designed with a sludge residence time under aerobic conditions (SRT_aer) greater than 13 days. In such cases, the nitrification process remains relatively unaffected. However, for lower SRT_aer values, a case-specific feasibility assessment is recommended to evaluate the overall process efficiency comprehensively.

Aerobic granular sludge is an interesting alternative to the conventional activated sludge (CAS) system and modified-Ludzack–Ettinger (MLE) process for biological wastewater treatment, as it allows a more cost-effective and simultaneous removal of carbon (C) and nitrogen (N) compounds in a single stage. In this study, (micro)aerobic C and N removal from synthetic urban wastewater was investigated in a continuous-double-column-upflow aerobic granular sludge blanket (UAGSB) system. The UAGSB reactor was operated under different dissolved oxygen (DO) ranges (0.01–6.00 mg∙L⁻¹), feed C/N ratios (4.7–13.6), and hydraulic retention times (HRTs) (6–24 h). At a DO range of 0.01–0.30 mg∙L⁻¹, feed C/N ratio of 13.6, and HRT of 24 h, the UAGSB achieved the highest chemical oxygen demand (COD), N-NH₄⁺, and total inorganic nitrogen (TIN) removal efficiencies of 86, 99, and 84%, respectively. A preliminary assessment of the energy and economic savings associated with the process investigated was also carried out. The impact of capital and operating costs mainly related to the energy consumption of the aeration was taken into account. The assessment reveals that the capital and energy expenses of the UAGSB reactor would result in cost savings of around 14 and 7%, respectively, compared with a MLE system.

The sustainability of industrial production, especially for highly water-demanding processes, is strictly related to water resource availability and to the dynamic interactions between natural and anthropogenic requirements over the spatial and temporal scales. The increase in industrial water demand raises the need to assess the related environmental sustainability, facing the occurrence of global and local water stress issues. The identification of reliable methodologies, based on simple indices and able to consider the impact on local water basins, may play a basilar role in water sustainability diagnosis and decision-making processes for water management and land use planning. The present work focalized on the definition of a methodology based on the calculation of indicators and indices in the view of providing a synthetic, simple, and site-specific assessment tool for industrial water cycle sustainability. The methodology was built starting from geo-referenced data on water availability and sectorial uses derived for Italian sub-basins. According to the data monthly time scale, the proposed indices allowed for an industrial water-related impacts assessment, able to take into account the seasonal variability of local resources. Three industrial factories, located in northern (SB1, SB2) and central (SB3) Italian sub-basins, were selected as case studies (CS1, CS2, CS3) to validate the methodology. The companies were directly involved and asked to provide some input data. The methodology is based on the calculation of three synthetic indexes: the Withdrawal and Consumption water Stress Index (WCSI) allowed for deriving a synthetic water stress level assessment at the sub-basin scale, also considering the spatial and temporal variations; the industrial water use sustainability assessment was achieved by calculating the Overall Factory-to-Basin Impact (OFBI) and the Internal Water Reuse (IWR) indices, which allowed a preliminary evaluation of the factories' impacts on the sub-basin water status, considering the related water uses and the overall pressures on the reference territorial context. The WCSI values highlighted significant differences between the northern sub-basins, characterised by limited water stress (WCSI_SB1 = 0.221; WCSI_SB2 = 0.047), and the central ones, more subjected to high stress (WCSI_SB3 = 0.413). The case studies CS1 and CS3 showed to exert a more significant impact on the local water resource (OFBI_CS1 = 0.18%; OFBI_CS2 = 0.192%) with respect to CS2 (OFBI = 0.002%), whereas the IWR index revealed the different company's attitude in implementing water reuse practices (IWR_CS1 = 40%; IWR_CS1 = 27%; IWR_CS1 = 99%). The proposed methodology and the indices may also contribute to assessing the effectiveness of river basin management actions to pursue sustainable development goals.