Supercapacitor electrodes fabricated from single-walled carbon nanotubes (SWNTs) are shown to be capable of durable operation at 4 V, exceeding the operating voltage limit of activated carbon electrodes (AC, 3 V), while delivering significantly higher energy and power (see figure). Dual exploitation of SWNTs as combined electrodes and current collectors is also explored.
Increased portability, versatility and ubiquity of electronics devices are a result of their progressive miniaturization, requiring current flow through narrow channels. Present-day devices operate close to the maximum current-carrying-capacity (that is, ampacity) of conductors (such as copper and gold), leading to decreased lifetime and performance, creating demand for new conductors with higher ampacity. Ampacity represents the maximum current-carrying capacity of the object that depends both on the structure and material. Here we report a carbon nanotube-copper composite exhibiting similar conductivity (2.3-4.7 × 10(5) S cm(-1)) as copper (5.8 × 10(5) S cm(-1)), but with a 100-times higher ampacity (6 × 10(8) A cm(-2)). Vacuum experiments demonstrate that carbon nanotubes suppress the primary failure pathways in copper as observed by the increased copper diffusion activation energy (~2.0 eV) in carbon nanotube-copper composite, explaining its higher ampacity. This is the only material with both high conductivity and high ampacity, making it uniquely suited for applications in microscale electronics and inverters.
Shake It to Wake It: Viscoelastic materials combine the recoverable stretchiness found in elastic materials with the slow-flowing behavior of a thick fluid, like honey. When subjected to an oscillatory motion, the response will depend on the frequency. At low frequencies, the viscous behavior will dominate and lead to a dissipation of the applied energy as heat, while at fast frequencies the elastic behavior dominates.
Xu
et al. (p. 1364 ; see the Perspective by Gogotsi ) developed a viscoelastic material with an exceptionally broad operating temperature range, based on a network of carbon nanotubes. The responsiveness of the material was probably caused by the “zipping” and “unzipping” of the nanotubes at points of contact.