Embedded copper mesh coatings with low sheet resistance and high transparency were formed using a low-cost Cu seed mesh obtained with a magnetron sputtering on a cracked template, and subsequent operations electroplating and embedding in a photocurable resin layer. The influence of the mesh size on the optoelectric characteristics and the electromagnetic shielding efficiency in a wide frequency range is considered. In optimizing the coating properties, a shielding efficiency of 49.38 dB at a frequency of 1 GHz, with integral optical transparency in the visible range of 84.3%, was obtained. Embedded Cu meshes have been shown to be highly bending stable and have excellent adhesion strength. The combination of properties and economic costs for the formation of coatings indicates their high prospects for practical use in shielding transparent objects, such as windows and computer monitors.

The study was devoted to the creation of transparent electrodes based on highly conductive mesh structures. The analysis and reasonable choice of technological approaches to the production of such materials with a high Q factor (the ratio of transparency and electrical conductivity) were carried out. The developed manufacturing technology consists of the formation of grooves in a transparent substrate by photolithography methods, followed by reactive ion plasma etching and their metallization by chemical deposition using the silver mirror reaction. Experimental samples of a transparent electrode fabricated using this technology have a sheet resistance of about 0.1 Ω/sq with a light transmittance in the visible wavelength range of more than 60%.

A complex of models for optimizing the design and operation modes of an automotive thermoelectric generator is developed within the proposed approach taking into account the influence of hydraulic resistance of the generator on the internal combustion engine. Several designs of generators for converting the thermal energy of exhaust gases (EGs) of internal combustion engines into electricity due to the Seebeck effect in semiconductor elements, which have different geometries of the continuous-flow part of the generator with different hydraulic resistances, are considered. Models for calculating the thermoelectric elements, gas heat exchanger, and automotive engine are considered jointly. Simulation is performed using the example of a VAZ-21126 engine, which demonstrated that up to 500 W of electric power can be obtained using semiconductor thermoelectric elements based on germanium and lead tellurides.

This paper is devoted to the study of the structure and thermomechanical properties of PVDF-based ferroelectric polymer film. Transparent electrically conductive ITO coatings are applied to both sides of such a film. In this case, such material acquires additional functional properties due to piezoelectric and pyroelectric effects, forming, in fact, a full-fledged flexible transparent device, which, for example, will emit a sound when an acoustic signal is applied, and under various external influences can generate an electrical signal. The use of such structures is associated with the influence of various external influences on them: thermomechanical loads associated with mechanical deformations and temperature effects during operation, or when applying conductive layers to the film. The article presents structure investigation and its change during high-temperature annealing using IR spectroscopy and comparative results of testing a PVDF film before and after deposition of ITO layers for uniaxial stretching, its dynamic mechanical analysis, DSC, as well as measurements of the transparency and piezoelectric properties of such structure. It is shown that the temperature-time mode of deposition of ITO layers has little effect on the thermal and mechanical properties of PVDF films, taking into account their work in the elastic region, slightly reducing the piezoelectric properties. At the same time, the possibility of chemical interactions at the polymer–ITO interface is shown.

The approaches to creation of the materials providing simultaneously high indicators of transparency in the visible spectrum and shielding in a wide radio frequency band are considered in this paper. The analysis and comparison of the main designs of such materials, as well as approaches to their creation, including multilayer and conductive mesh structures, is carried out. The results of our own theoretical studies of the disordered mesh structure are presented, which allow one to obtain a light transmission coefficient from 90 to 98 % in combination with an electromagnetic interference shielding efficiency from 50 to 65 dB. The best results practically achieved to date (shielding efficiency equal 45 dB in the range from 10 kHz to 20 GHz with a light transparency of more than 80 %) were obtained on mesh structures by photolithography, which is a significant limiting factor of this approach. The created multilayer structures show, in general, lower characteristics. However, the technology for their production is better scaled, and the optimization of the thicknesses and chemical composition of multilayer structures can significantly increase them. In this regard, technological aspects may come to the fore when taking into account the possibility of subsequent scaling of the technology and economic indicators when choosing an approach for the implementation of the materials with the required characteristics.

This paper presents data on the macroscopic polarization of copolymer films of vinylidene fluoride with tetrafluoroethylene obtained with a modified apparatus assembled according to the Sawyer–Tower Circuit. The kinetics of the polarization process were analyzed taking into consideration the contributions of both bound and quasi-free (impurity) charges. It was shown that an “abnormal” decrease in conductivity was observed in fields near the coercive fields. This could be associated with the appearance of deep traps of the impurity charge carriers formed by the polar planes of β-phase crystals. The conductivity data obtained from the charge and current responses differed. It was concluded that chain segments contributing to polarization with sufficiently low fields were present in the amorphous phase. A comparison showed that the average size of β-phase crystals (crystals of X-ray diffraction reflection width) was almost one order of magnitude lower than the domain size obtained using piezoresponse force microscopy (PFM). The analysis of the fast-stage dielectric response before and after polarization indicated that as the external polarizing field increased in the ferroelectric polymer chains, conformational transitions occurred according to the T₃GT₃G⁻ → (-TT-)_n и TGTG → (-TT-)_n types. This was accompanied by an increase in the effective dipole moment in the amorphous phase chains. The analysis of the IR spectroscopy data obtained in transmission and ATR modes revealed a difference in the conformational states of the chains in the core and surface parts of the film.