The discovery of an innovative category of inorganic geopolymer composites has generated extensive scientific attention and the kaleidoscopic development of their applications. The escalating concerns over global warming owing to emissions of carbon dioxide (CO₂), a primary greenhouse gas, from the ordinary Portland cement industry, may hopefully be mitigated by the development of geopolymer construction composites with a lower carbon footprint. The current manuscript comprehensively reviews the rheological, strength and durability properties of geopolymer composites, along with shedding light on their recent key advancements viz., micro-structures, state-of-the-art applications such as the immobilization of toxic or radioactive wastes, digital geopolymer concrete, 3D-printed fly ash-based geopolymers, hot-pressed and foam geopolymers, etc. They have a crystal-clear role to play in offering a sustainable prospect to the construction industry, as part of the accessible toolkit of building materials—binders, cements, mortars, concretes, etc. Consequently, the present scientometric review manuscript is grist for the mill and aims to contribute as a single key note document assessing exhaustive research findings for establishing the viability of fly ash-based geopolymer composites as the most promising, durable, sustainable, affordable, user and eco-benevolent building materials for the future.

Even though, an innovative inorganic family of geopolymer concretes are eye-catching potential building materials, it is quite essential to comprehend the fire and thermal resistance of these structural materials at a very high temperature and also when experiencing fire with a view to make certain not only the safety and security of lives and properties but also to establish them as more sustainable edifice materials for future. The experimental and field observations of degree of cracking, spalling and loss of strength within the geopolymer concretes subsequent to exposure at elevated temperature and incidences of occurrences of disastrous fires extend an indication of their resistance against such severely catastrophic conditions. The impact of heat and fire on mechanical attributes viz., mechanical-compressive strength, flexural behavior, elastic modulus; durability—thermal shrinkage; chemical stability; the impact of thermal creep on compressive strength; and microstructure properties—XRD, FTIR, NMR, SEM as well as physico-chemical modifications of geopolymer composites subsequent to their exposures at elevated temperatures is reviewed in depth. The present scientific state-of-the-art review manuscript aimed to assess the fire and thermal resistance of geopolymer concrete along with its thermo-chemistry at a towering temperature in order to introduce this novel, most modern, user and eco-benign construction materials as potentially promising, sustainable, durable, thermal and fire-resistant building materials promoting their optimal and apposite applications for construction and infrastructure industries.

There is nothing more fundamental than clean potable water for living beings next to air. On the other hand, wastewater management is cropping up as a challenging task day-by-day due to lots of new additions of novel pollutants as well as the development of infrastructures and regulations that could not maintain its pace with the burgeoning escalation of populace and urbanizations. Therefore, momentous approaches must be sought-after to reclaim fresh water from wastewaters in order to address this great societal challenge. One of the routes is to clean wastewater through treatment processes using diverse adsorbents. However, most of them are unsustainable and quite costly e.g. activated carbon adsorbents, etc. Quite recently, innovative, sustainable, durable, affordable, user and eco-benevolent Geopolymer composites have been brought into play to serve the purpose as a pretty novel subject matter since they can be manufactured by a simple process of Geopolymerization at low temperature, lower energy with mitigated carbon footprints and marvellously, exhibit outstanding properties of physical and chemical stability, ion-exchange, dielectric characteristics, etc., with a porous structure and of course lucrative too because of the incorporation of wastes with them, which is in harmony with the goal to transit from linear to circular economy, i.e., “one’s waste is the treasure for another”. For these reasons, nowadays, this ground-breaking inorganic class of amorphous alumina-silicate materials are drawing the attention of the world researchers for designing them as adsorbents for water and wastewater treatment where the chemical nature and structure of the materials have a great impact on their adsorption competence. The aim of the current most recent state-of-the-art and scientometric review is to comprehend and assess thoroughly the advancements in geo-synthesis, properties and applications of geopolymer composites designed for the elimination of hazardous contaminants viz., heavy metal ions, dyes, etc. The adsorption mechanisms and effects of various environmental conditions on adsorption efficiency are also taken into account for review of the importance of Geopolymers as most recent adsorbents to get rid of the death-defying and toxic pollutants from wastewater with a view to obtaining reclaimed potable and sparkling water for reuse offering to trim down the massive crisis of scarcity of water promoting sustainable water and wastewater treatment for greener environments. The appraisal is made on the performance estimation of Geopolymers for water and wastewater treatment along with the three-dimensional printed components are characterized for mechanical, physical and chemical attributes, permeability and Ammonium (NH₄⁺) ion removal competence of Geopolymer composites as alternative adsorbents for sequestration of an assortment of contaminants during wastewater treatment.

The concept of sustainability and the utilization of renewable bio-based sources have gained prominent attention in the construction industry. Material selection in construction plays a significant role in design and manufacturing process of sustainable building construction. Several studies are being carried out worldwide to investigate the potential use of natural fibres as reinforcement in concrete with its noticeable environmental benefits and mechanical properties. 3D printed concrete (3DPC) is another emerging technology, which has been under-developed for the past decade. The integration of reinforcement is one of the major challenges in the application of this new technology in real-life scenario. Presently, artificial fibres have been used as a reinforcement material for this special printable concrete mixture. However, natural fibre composites have received significant attention by many 3DPC constructions due to their lightweight energy conservation and environmentally friendly nature. These benchmarking characteristics unlock the wider area of natural fibres into the composite sector and challenge the substitution of artificial fibres. Hence, this paper presents a comprehensive review on the current practice and advantages of natural fibres in conventional concrete construction. Subsequently, with a view to the future efficient 3DPC construction, the potentials of natural fibres such as eco-friendly, higher impact, thermal, structural, and fire performance over the artificial fibres were highlighted, and their applicability in 3DPC as composites was recommended.

The development of cracks, owing to a relatively lower tensile strength of concrete, diverse loading, and environmental factors driving the deterioration of structures, is an inescapable key concern for engineers. Reparation and maintenance operations are thus extremely important to prevent cracks from spreading and mitigating the lifetime of structures. However, ease of access to the cracked zone may be challenging, and it also needs funds and manual power. Hence, autonomous sealing of cracks employing microorganisms into the concrete sans manual intervention is a promising solution to the dilemma of the sustainable improvement of concrete. ‘Ureolytic bacteria’, key organism species in rumen-producing ‘urease’ enzymes such as Bacillus pasteurii or subtilis—when induced—are capable of producing calcium carbonate precipitations into the concrete. As their cell wall is anionic, CaCO₃ accumulation on their surface is extensive, and the whole cell, therefore, becomes crystalline and ultimately plugs pores and cracks. This natural induction technique is an environmentally friendly method that researchers are studying intensively. This manuscript reviews the application process of bacterial healing to manufacture autonomous self-healing bacterial concrete. Additionally, it provides a brief review of diverse attributes of this novel concrete which demonstrate the variations with the auto-addition of different bacteria, along with an evaluation of crack healing as a result of the addition of these bacteria directly into concrete or after encapsulation in a protective shell. Comparative assessment techniques for autonomous, bio-based self-healing are also discussed, accompanied by progress, potential, modes of application of this technique, and its resultant benefits in the context of strength and durability. Imperatives for quantitative sustainability assessment and industrial adoption are identified, along with the sealing of artificially cracked cement mortar with sand as a filling material in given spaces, as well as urea and CaCl₂ medium treatment with Bacillus pasteurii and Sporosarcina bacteria. The assessment of the impact on the compressive strength and rigidity of cement mortar cubes after the addition of bacteria into the mix is also considered. Scanning electron microscope (SEM) images on the function of bacteria in mineral precipitation that is microbiologically induced are also reviewed. Lastly, future research scope and present gaps are recognised and discussed.

Currently, novel inorganic alumino-silicate materials, known as geopolymer composites, have emerged swiftly as an ecobenevolent alternative to contemporary ordinary Portland cement (OPC) building materials since they display superior physical and chemical attributes with a diverse range of possible potential applications. The said innovative geopolymer technology necessitates less energy and low carbon footprints as compared to OPC-based materials because of the incorporation of wastes and/or industrial byproducts as binders replacing OPC. The key constituents of ceramic are silica and alumina and, hence, have the potential to be employed as an aggregate to manufacture ceramic geopolymer concrete. The present manuscript presents a review of the performance of geopolymer composites incorporated with ceramic waste, concerning workability, strength, durability, and elevated resistance evaluation.