Biodegradable magnesium alloys have emerged as promising alternatives to permanent metallic implants due to their unique combination of mechanical compatibility with bone and complete resorption, addressing the persistent issues of stress shielding and secondary removal surgeries. This review critically examines the historical development of magnesium-based biomaterials, highlighting advances in alloy design, manufacturing processes, and surface engineering that now enable tailored degradation and improved clinical performance. Drawing on recent clinical and preclinical studies, we summarize improvements in corrosion resistance, mechanical properties, and biocompatibility that have supported the clinical translation of magnesium alloys across a variety of orthopedic and emerging medical applications. However, challenges remain, including unpredictable in vivo degradation kinetics, limited long-term safety data, lack of standardized testing protocols, and ongoing regulatory uncertainties. We conclude that while magnesium-based biomaterials have advanced from experimental concepts to clinically validated solutions, further progress in personalized degradation control, real-time monitoring, and harmonized regulatory frameworks is needed to fully realize their transformative clinical potential.

Biofilters (BFs) and biotrickling filters (BTFs) are two types of bioreactors used for treatment of volatile organic compounds (VOCs). Both BFs and BTFs use packing materials in which various microorganisms are immobilised. The water phase in BFs is stationary and used to maintain the humidity of packing materials, while BTFs have a mobile liquid phase. Optimisation of irrigation of packing materials is crucial for effective performance of BFs and BTFs. A literature review is presented on the influence of water content of packing materials on the biofiltration efficiency of various pollutants. Different configurations of BFs and BTFs and their influence on moisture distribution in packing materials were discussed. The review also presents various packing materials and their irrigation control strategies applied in recent biofiltration studies. The sources of this review included recent research articles from scientific journals and several review articles discussing BFs and BTFs.

Macroalgae can be a viable alternative to replace fossil fuels that have a negative impact on the environment. By mixing macroalgae with other substrates, higher quality biogas can be obtained. Such biogas is considered one of the most promising solutions for reducing climate change. In the work, new studies were conducted, during which biogas yield was investigated in a three-stage bioreactor (TSB) during the anaerobic digestion of Cladophora glomerata macroalgae with inoculants from cattle manure and sewage sludge at different organic loading rates (OLR). By choosing the optimal OLR in this way, the goal was to increase the energy potential of biomass. The research was performed at OLRs of 2.87, 4.06, and 8.13 Kg VS/m³ d. After conducting research, the highest biogas yield was determined when OLR was 2.87 Kg VS/m³ d. With this OLR, the average biogas yield was 439.0 ± 4.0 L/Kg VS_added, and the methane yield was 306.5 ± 9.2 L CH₄/Kg VS_added. After increasing the OLR to 4.06 and 8.13 Kg VS/m³ d, the yield of biogas and methane decreased by 1.55 times. The higher yield was due to better decomposition of elements C, N, H, and S during the fermentation process when OLR was 2.87 Kg VS/m³ d. At different OLRs, the methane concentration remained high and varied from 68% to 80%. The highest biomass energy potential with a value of 3.05 kWh/Kg VS_added was determined when the OLR was 2.87 Kg VS/m³ d. This biomass energy potential was determined by the high yield of biogas and methane in TSB.

Acetone released into the atmosphere can adversely affect human health and the environment. The aim of this work was to evaluate the performance of a laboratory-scale biotrickling filter (BTF) with bioball packing material to remove acetone vapor from contaminated air. The acetone removal efficiency was investigated in two different scenarios: with and without the inoculation of microorganisms. Three strains of bacteria, Pseudomonas putida, Rhodococcus aerolatus, and Aquaspirillum annulus, were used in the BTF. In both cases, the filter units were simultaneously operated for 100 days under three different inlet acetone concentrations (0.18 ± 0.01 g/m³, 0.25 ± 0.01 g/m³, and 0.40 ± 0.02 g/m³) and two different gas flow rates (2.54 and 5.09 m³/h). The results showed that acetone removal was greater in the filter with the inoculated bacteria. In the filter operated without inoculum, the acetone removal efficiency gradually decreased with filtration time from 90.1% to 6.1%. While employing three types of bacteria in the BTF, the efficiency of acetone removal remained relatively stable and varied between 70.2% and 97.6%. The study also revealed that bioballs can be successfully used as a packing material in air biofiltration systems designed for acetone removal from the air.

Sewage sludge was treated with nanoscale zero-valent iron (nZVI) to enhance biogas and methane (CH₄) production, and the influence of key parameters on the material’s anaerobic digestion (AD) efficiency was analyzed using sigmoidal mathematical models. In this study, three dosages of nZVI (0.5%, 1.5% and 3%) were added to the anaerobic sludge digestion system to enhance and accelerate the sludge decomposition process. The results showed that cumulative biogas yield after 41 days of digestion increased by 23.9% in the reactor with a nZVI dosage of 1.5%. Correspondingly, the highest CH₄ production enhancement by 21.5% was achieved with a nZVI dosage of 1.5% compared to the control. The results indicated that this nZVI dosage was optimal for the AD system, as it governed the highest biogas and CH₄ yields and maximum removal of total and volatile solids. Additionally, to predict biogas and CH₄ yields and evaluate kinetic parameters, eight kinetic models were applied. According to the results of the modified Gompertz, Richards and logistic models, the nZVI dosage of 1.5% shortened the biogas lag phase from 11 to 5 days compared to the control. The Schnute model provided the best fit to the experimental biogas and CH₄ data due to highest coefficients of determination (R²: 0.9997–0.9999 at 1.5% and 3% nZVI dosages), as well as the lowest Akaike’s Information Criterion values and errors. This demonstrated its superior performance compared to other models.

Background: Following an extensive examination of various biofiltration packing materials within a typical bioreactor (a biofilter) is aiming to remove hydrogen sulfide (H2 S) in the raw biogas. Methods: Both biochar (pre- and post-pyrolysis at 400, 500, and 600 °C) and cellular concrete (CLC) waste, representing organic and inorganic packing materials, respectively, displayed remarkable removal efficiency (RE) performance under dynamic conditions. Nevertheless, the physical and chemical properties of these packing materials play a crucial role in absorbing and trapping H2 S for further filtration from the raw biogas. Key evaluations encompass chemical compositions, porosity, and specific surface area, aligning with contemporary research methodologies (e.g., XRF, Walkley-black, Kjeldahl, BET, T-plot), as analyzed in this study. Results: Subsequently, the modification of these physicochemical properties aimed to demonstrate continued interactions of iron (III) oxide (Fe2 O3 ) with H2 S for chemical modification of CLC waste, and enhance the specific surface area of biochar from 12, 22, and 24 m2 /g to 235, 433, 475 m2 /g, and for porosity from 0.01, 0.42, and 0.025 cm3 /g to 0.096, 4, 0.24 cm3 /g, respectively, for physical modification of biochar samples after pyrolysis at 400, 500, and 600 °C. Conclusion: In the end, improving the possibility of getting better RE from a laboratory-scale biofilter is possible by modification of the most effective physical (adding KOH to biochar and increasing porosity by 9 times, specific surface area by 19 times) and chemical (adding Fe2 O3 to CLC waste) properties of the environment-friendly packing materials.