The interaction of terahertz electromagnetic radiation with dilute graphene-epoxy composites was studied experimentally at frequencies from 0.25 to 4 THz. Composites with low graphene loading (≤1.2 wt. %) below the electrical percolation threshold revealed the total shielding effectiveness above ∼70 dB (1 mm thickness) at 1.6 THz frequency. The unexpected high shielding effectiveness of dilute graphene composites in blocking terahertz radiation was mostly achieved by absorption rather than reflection. The shielding effectiveness increases with increasing frequency. Our results suggest that even the thin-film or spray coatings of the lightweight, electrically insulating graphene composites with thicknesses in the few-hundred-micrometer range can be sufficient for blocking terahertz radiation in many practical applications.
In this article, we present the possibility of using terahertz time-domain spectroscopy to detect trace, ppm-level (%wt.) concentrations of admixtures in 95-octane lead-free gasoline in straightforward time-of-flight (pulse-delay) measurements performed directly in the liquid. The method was tested on samples containing 75–0.0125% of isopropanol and 0.3–0.0250% of water. The detection limits for isopropanol and water content were determined to be 125 ppm and 250 ppm, respectively, approaching the limits of much more complicated and time-consuming methods (like spectroscopy of the vapor phase). The measured pulse delays were compared with theoretical calculations using the modified Gladstone-Dale mixing rule for the solutions. The comparison demonstrated good agreement for gasoline-alcohol mixtures and large discrepancies for gasoline-water mixtures, suggesting that gasoline-water mixtures cannot be considered idealized binary mixtures. Our results clearly show that the pulse time delay measurement by THz-TDS is a fast and sensitive method of gasoline contamination detection and, as such, can be easily integrated with industrial online real-time quality control applications.
Thin layers of silver nanowires are commonly studied for transparent electronics. However, reports of their terahertz (THz) properties are scarce. Here, we present the electrical and optical properties of thin silver nanowire layers with increasing densities at THz frequencies. We demonstrate that the absorbance, transmittance and reflectance of the metal nanowire layers in the frequency range of 0.2 THz to 1.3 THz is non-monotonic and depends on the nanowire dimensions and filling factor. We also present and validate a theoretical approach describing well the experimental results and allowing the fitting of the THz response of the nanowire layers by a Drude–Smith model of conductivity. Our results pave the way toward the application of silver nanowires as a prospective material for transparent and conductive coatings, and printable antennas operating in the terahertz range—significant for future wireless communication devices.
The interaction between condensed matter excitations and electromagnetic cavity fields serves as a rich playground for fundamental research and lies at the core of photonic and quantum technologies. Herein, the intriguing concept of composite states formed by distinct quasiparticles strongly coupled to the same optical cavity modes is experimentally and theoretically demonstrated. Specifically, magnons excited in a slab of an antiferromagnetic crystal and phonons excited in a distinct specimen of an insulating material are explored. The crystal slabs form an optical cavity with Fabry–Pérot oscillations in the terahertz range. Hybridized phonon–magnon polariton modes and their tunability by adjusting the distance between the slabs, showing that hybridization persists even at separations of up to several millimeters is demonstrated. The experimental results are interpreted using both classical and quantum electrodynamical models. The quantum description allows us to quantify the degree of hybridization linked to a topological behavior of the electric field phasor, in agreement with the classical electrodynamics expectations. The presented results are obtained at room temperature and cavities of millimeter size, paving the way for the engineering of realistic, frequency‐tunable THz devices through the hybridization of electric (phononics) and magnetic (spintronics) elementary excitations of matter.