Transition metal dichalcogenide coatings have emerged as potential candidates for terrestrial and aerospace mobility applications. Among these, the alloyed MoSe2 coatings have displayed promising results while sliding in diverse environments. N-alloyed Mose2 coatings provide the additional benefit of overcoming the impact of PVD compositional variations on dry sliding, making them promising solid lubricants for mobility-sector applications. However, the impact of long-term storage has never been investigated for this rarely studied solid-lubricant system. This study investigates the tribological performance of direct current magnetron sputtered MoSeN coatings after 40 months of storage in an ambient atmosphere. Sliding tests were conducted under conditions consistent with pre-storage conditions. The results showed that coatings with 0 at. %, 22 at. %, 33 at. %, and 35 at. % N-alloying exhibited COF values nearly identical to the pre-storage results, with only a negligible increase in ~0.01. Similarly, all coatings displayed specific wear rates in the range of 10−7, aligning with earlier findings. The obtained results show that the sliding performance of MoSeN coatings does not deteriorate over time, highlighting their suitability for critical aerospace applications, where components and assembled parts may be stored for years before launching into space or in actual applications.
Core–shell structured magnetic nanoparticles combine hard and soft phases to improve energy efficiency. The mutual interaction of the two phases can lead to the exchange spring effect, leading to higher magnetic energy. In this regard, synthesis of Nd2Fe14B-based core–shell-structured powders have proven to be elusive, due to the relatively reactive nature of this phase. In this study, a process has been established for successfully coating the surface of Nd2Fe14B powders with a FeCo layer using the galvanic displacement method. Initially, a binary phase magnetic powder was synthesized containing Nd2Fe14B and Nd2Fe17 phase. Subsequently, the powders were coated using a Co precursor at 303 K. During coating, the metastable Nd2Fe17 phase was dissolved, and the Fe ions were released into the solution. Subsequently, the Fe ions deposited together with the Co ions on the surface of Nd2Fe14B powder to form a FeCo shell. The deposited layer thickness and composition was confirmed using TEM analysis.
Core-shell structured magnetic nanoparticles combine hard and a soft phases to improve energy efficiency. The mutual interaction of the two phases can lead to the exchange spring effect leading to higher magnetic energy. In this regard, synthesis of Nd2Fe14B based core-shell structured powders have proven to be elusive due to the relatively reactive nature of this phase. In this study, a process has been established for successfully coating the surface of Nd2Fe14B powders with FeCo layer using galvanic displacement method. Initially, a binary phase magnetic powder was synthesized containing Nd2Fe14B and Nd2Fe17 phase. Subsequently, the powders were coated using a Co precursor at 303 K. During coating the metastable Nd2Fe17 phase was dissolved and the Fe ions were released into the solution. Subsequently, the Fe ions deposited together with the Co ions on the surface of Nd2Fe14B powder to form a FeCo shell. The deposited layer thickness and composition was confirmed using TEM analysis.