Nanosized bimetallic PtMo, PtFe and trimetallic PtMoSn catalysts deposited on highly dispersed carbon black Vulcan XC-72 were synthesized from the cluster complex compounds PtCl(P(C₆H₅)₃)(C₃H₂N₂(CH₃)₂)Mo(C₅H₄CH₃)(CO)₃, Pt(P(C₆H₅)₃)(C₃N₂H₂(CH₃)₂)Fe(CO)₃(COC₆H₅C₂C₆H₅), and PtCl(P(C₆H₅)₃)(C₃N₂H₂(CH₃)₂)C₅H₄CH₃Mo(CO)₃SnCl₂, respectively. Structural characteristics of these catalysts were studied using X-ray diffraction (XRD), microprobe energy dispersive spectroscopy (EDX), and transmission electron microscopy (TEM). The synthesized catalysts were tested in aqueous 0.5 M H₂SO₄ in a three-electrode electrochemical cells and in single fuel cells. Electrocatalytic activity of PtMo/C and PtFe/C in the oxygen reduction reaction (ORR) and the activity of PtMoSn/C in electrochemical oxidation of ethanol were evaluated. It was shown that specific characteristics of the synthesized catalysts are 1.5–2 times higher than those of a commercial Pt(20%)/C catalyst. The results of experiments indicate that PtFe/C, PtMo/C, and PtMoSn/C catalysts prepared from the corresponding complex precursors can be regarded as promising candidates for application in fuel cells due to their high specific activity.

Thin-film nanocrystalline hematite electrodes were fabricated by electrochemical deposition and loaded with electrodeposited zinc oxide in various amounts. Under visible light illumination, these electrodes demonstrate high activity in the photoelectrochemical degradation of methanol, ethylene glycol and, in particular, glycerol. Results of intensity-modulated photocurrent spectroscopy show that the photoelectrocatalysis efficiency is explained by the suppression of the electron–hole pair recombination and an increase in the rate of photo-induced charge transfer. Thus, zinc oxide can be considered an effective modifying additive for hematite photoanodes.

Photoelectrocatalytic oxidation of methanol, ethylene glycol, glycerol, and 5,6,7,8-tetrahydro-2-naphthol on thin-film nanocrystalline hematite electrodes fabricated by electrochemical deposition and promoted with spin-coated titanium has been studied. It is shown that the modification of hematite transforms it into material exhibiting high activity in the photoelectrochemical process of substrate oxidation upon illumination with light in the visible region of the spectrum. The highest activity is observed in the reaction of photoelectrocatalytic oxidation of glycerol. Results of intensity-modulated photocurrent spectroscopy (IMPS) suggest that the effect is due to an increased rate of charge transfer in the process of photoelectro-oxidation and efficient suppression of the recombination of generated electron-hole pairs. Therefore, thin-film photoanodes based on modified hematite are promising for practical application in the photooxidation of glycerol, a by-product of biofuel production, as well as in the photoelectrochemical degradation of other organic pollutants, including those formed during the production of pharmaceuticals.

The activity of Pt/Pd/C ETEK catalysts of the core-shell type with an ultralow content of platinum (0.5–15 μg cm⁻²) based on a commercial palladium catalyst is shown to exceed the activity of commercial Pt/C ETEK catalysts in the oxygen reduction reaction. The activity sharply increases with the decrease in the platinum content down to values corresponding to monolayer and submonolayer of platinum on palladium. This dependence wasn’t observed for the same amounts of platinum deposited on the carbon support Vulcan XC-72. This makes it possible to conclude that the most probable factor responsible for the high catalytic activity of Pt/Pd/C ETEK is the effect of palladium on the electronic properties of platinum rather than the effect of structural modification of the platinum deposit induced by the decrease in the platinum amount deposited on a foreign metal or a carbon support.