Microplastics have become one of the most serious environmental hazards today, raising fears that concentrations will continue to rise even further in the near future. Micro/nanoparticles are formed when plastic breaks down into tiny fragments due to mechanical or photochemical processes. Microplastics are everywhere, and they have a strong tendency to interact with the ecosystem, putting biogenic fauna and flora at risk. Polyester (PET) and polyamide (PA) are two of the most important synthetic fibres, accounting for about 60% of the total world fibre production. Synthetic fabrics are now widely used for clothing, carpets, and a variety of other products. During the manufacturing or cleaning process, synthetic textiles have the potential to release microplastics into the environment. The focus of this paper is to explore the main potential sources of microplastic pollution in the environment, providing an overview of washable polyester materials.

The existing research deals with the process of modifying polyester knitted fabrics and polyester/cotton knitted fabrics with chitosan and the stability of functionalized surface with chitosan in the washing process according to a standard and an innovative washing procedure. The current research concept aims to evaluate the degree of progressivity and progressiveness: the modification of polyester knitted fabrics with chitosan and an innovative washing process. The polyester and polyester/cotton fabrics modified with chitosan were characterized by a staining test, microscopic analysis, zeta potential measurement, and pilling tendency of the knitted fabrics before and after five and ten washing cycles with reference detergent ECE A. The results of the zeta potential measurement of knitted fabrics functionalized with chitosan confirmed cationization of the polyester and polyester/cotton fabric with chitosan. The presence of chitosan on the washed knitted fabrics in reduced quantities is demonstrated by the staining test, the colour strength (K/S), and the zeta potential values. The staining test and surface charge of the tested knitted fabrics confirmed the research hypothesis regarding the degree of progressivity of the modification of polyester and polyester/cotton knitted fabrics with chitosan and the sustainability of the innovative washing process. The streaming potential proved to be a favorable method for monitoring the stability of chitosan in the washing process in combination with a staining test with the selected dye Remazol Red RB.

Aging and washing factors have a direct influence on changing the properties of textile products, e.g., causing a release of textile fragments in the washing process. In this study, polyester fabrics were exposed to artificial aging under controlled conditions. Using a modified washing process, polyester fabrics were subjected to 10 washing cycles before and after the aging process. To monitor the influence of aging and the modified washing process on the polyester fabrics, the physical, structural and morphological properties of the fabrics and the composition of the collected wastewater were analyzed. The results indicate a slight degradation and increased defragmentation of the polyester fabric due to the processes used. Aging caused the phenomenon of “annealing”, photo-oxidative degradation, and the local thickening of the individual fibers. Aging and washing processes influence the change in tensile strength properties. An analysis of zeta potential and BET results confirmed that the aging process results in surface modifications that depend on the time of exposure. The physico-chemical characterization and microscopic analysis of the wastewater revealed various fragments and short, detached fibrils. The results confirmed that both aging and washing significantly affect the properties of polyester fabrics and the composition of the wastewater resulting from the washing process. The relevance of this research to environmental matters is emphasized through the parameters chosen, which reveal the influence of aging on polyester fabric characteristics and the contamination detected in wash wastewater. In conclusion, several avenues for future research have been identified, including lowering washing temperatures, choosing more appropriate detergents, and adjusting standard washing protocols.

In this research, the modification of different polyester structures (fabrics and knits) by the biopolymer chitosan was studied to evaluate the effects of the polyester structure and treatments on the particulate pollution of wastewater. The pristine polyester and the chitosan-polyester fabric and polyester knit composites were washed cyclically with standard ECE A detergent at 60 °C. The laser diffraction technique was used to characterize the particle size of the washing wastewaters from the 1–5, 6–10 and 1–10 wash cycles. In addition, the total solids (TS), total suspended solids (TSS), total dissolved solids (TDS), turbidity and chemical oxygen demand (COD) were also determined, according to standard procedures. The obtained results show the influence of the polyester fabrics and polyester knit structures and chitosan-polyester composites on the particle size distribution (PSD) in the washing wastewater. Differences in the values of the characteristic parameters, especially the span value and shape factor (k) of the individual curves, are visible, indicating the release of particles during the washing process. The experimental results show that the laser diffraction technique is suitable for characterizing the particle dimensions of the washing wastewater for different pristine polyester structures and chitosan-polyester composites. Modification with chitosan has been shown to provide potential protection against the release of microplastic particles into the environment.

Microplastics (MP), consisting of particles under 5 mm in size, and fibrous microplastics (FMPs), which originate from textiles and are shed during the washing process, are acknowledged as a new and expanding category of pollutants. This study aimed to conduct an analytical evaluation of the defragmentation process of polyester fabrics featuring a prominent tri-color pile surface. The evaluation involved washing the fabrics with detergent and water and employing various methods to assess the fabric, wastewater, and filter cake both prior to, and following, cryogenization. The specificity of a pile polyester fabric provided a baseline for evaluating the detergent and water system. Subjecting the polyester fabric to five cycles of washing in a detergent solution and water resulted in a measurable loss of mass. The pristine polyester fabric was analyzed microscopically and by FTIR, while the fabrics before and after washing were subjected to gravimetric analysis. The physico–chemical characteristics of the wastewater, such as the conductivity, turbidity, and chemical oxygen demand, were impacted by the composition of the washing bath. The application of pyrolysis, combined with gas chromatography and mass spectrometry (Py-GC/MS), on the filter cake demonstrated the value of using blank samples. The results indicated that both the detergent and the water significantly affected the release of FMPs during the washing process. Polyester fabric sample 1, which was washed in a detergent solution for five cycles, exhibited a mass loss of 1619 mg kg⁻¹. In contrast, sample 2, consisting of a polyester fabric washed solely in water, showed a mass loss of 1707 mg kg⁻¹ over the same number of cycles.

Human uncontrolled and careless habits and activities have disturbed the balance of the Earth's life cycle. Due to their effort to use natural resources as much as possible, humans have directly affected all the actors who live here, so that ecology has become an imperative today. Since the biggest polluters are factories in general, it can be stated that the textile industry is one of them. The increasing use of synthetic fibers in the production of textiles has led to some improvements in the form of mechanical, aesthetic and functional properties of the material. However, consumerism, the development of fast fashion, the rapid changes of fashion trends, irrational behavior and population growth have led to increased production of textiles based on synthetic fibers. Over the years, this has led to a slow accumulation of microfibers in the environment. Based on long-term test procedures under real conditions and with the aim of accelerating simulation, a standard polyester fabric is subjected to an artificial ageing process in this paper. By analyzing and characterizing the surface of the standard and the artificially aged fabric, and by instrumentally testing the tactile and mechanical properties, an attempt is made to gain insight into the behavior of the polyester fabric as a result of the applied modification. The results show that artificial ageing significantly affects the properties of polyester fabric, with a marked decrease in strength.