We investigated the effect of reduced graphene oxide (rGO) doping on the birefringence of 5CB liquid crystal (LC). The characteristics of the synthesized rGO and LC-rGO composite with different rGO concentrations were analyzed by atomic force microscopy, X-ray photoelectron spectroscopy, white light polarized microscopy, voltage-dependent transmission measurement, and differential scanning calorimetry. We found that doping LC with an appropriate concentration of rGO enhances the birefringence of the LC. This is mainly due to the improved anisotropy of polarizability, which stems from the high shape anisotropy of rGO. However, the aggregation of rGO reduces the birefringence by decreasing the anisotropy of polarizability as well as the order parameter. Our study shows the promising potential of LC-rGO for developing various electro-optic devices that offer improved electro-optic effects.
This review explores the integration of graphene and liquid crystals to advance sensor technologies across multiple domains, with a focus on recent developments in thermal and infrared sensing, flexible actuators, chemical and biological detection, and environmental monitoring systems. The synergy between graphene’s exceptional electrical, optical, and thermal properties and the dynamic behavior of liquid crystals leads to sensors with significantly enhanced sensitivity, selectivity, and versatility. Notable contributions of this review include highlighting key advancements such as graphene-doped liquid crystal IR detectors, shape-memory polymers for flexible actuators, and composite hydrogels for environmental pollutant detection. Additionally, this review addresses ongoing challenges in scalability and integration, providing insights into current research efforts aimed at overcoming these obstacles. The potential for multi-modal sensing, self-powered devices, and AI integration is discussed, suggesting a transformative impact of these composite sensors on various sectors, including health, environmental monitoring, and technology. This review demonstrates how the fusion of graphene and liquid crystals is pushing the boundaries of sensor technology, offering more sensitive, adaptable, and innovative solutions to global challenges.
Quantum dots have diverse chemical properties with different ligands attached on the surface. The cysteamine has been used as a ligand for various quantum dots because it has high solubility in water, and it facilitates binding of quantum dot and gold surface. However, the hydrogen bonds in cysteamine cause aggregation of the cysteamine capped quantum dots. In this study, we suggested a simple synthesis method of aggregation-free PbS quantum dot and analyzed the electric and optical properties of the synthesized quantum dot. This study on aggregation-free cysteamine capped quantum dots has the potential to develop advanced quantum dot-based sensor technologies, including biomedical imaging and environmental sensors.
Manipulating the phase and amplitude of light led to many important breakthroughs in optics, and it is still considered one of the most critical technologies in emerging optical systems. However, conventional phase modulators generally suffer from the strong polarisation dependence that stems from the anisotropic optical property of the base material. Here, we report a phase modulator that is polarisation-independent and is based on the trilayer of birefringent materials which have their optical axes aligned at specific angles. The proposed structure effectively eliminates the polarisation dependence of the phase modulator without compromising its electro-optic properties. This technology provides a simple but significant method for developing a polarisation-independent phase modulator without fabrication complexity. Graphical abstract