Nypa fruticans (NF) is a lignocellulosic material belonging to the family Palmae or Arecaceae. Effects of NF content and chemical modification using methyl methacrylate (MMA) on tensile, thermal, and morphological properties of biocomposites were investigated. The results showed that the addition of NF decreased the tensile strength, elongation at break, and crystallinity, but increased the Young’s modulus, of biocomposites. Moreover, the addition of NF increased the thermal stability. Meanwhile, the tensile strength and Young’s modulus of the biocomposites treated with MMA were higher than the untreated biocomposites. The treated biocomposites exhibited higher thermal degradation temperature and crystallinity compared to the untreated biocomposites. The morphology study of the tensile-fractured surfaces of biocomposites indicated that chemical modification with MMA enhanced the interfacial interaction between NF and the PLA/rLDPE matrix.
19 March 2018 in IOP Conference Series: Materials Science and Engineering
The main purpose of incorporating Nypa fruticans husks (NFH) into Polylactic acid (PLA)/Polymethylmethacrylate (PMMA) is to decrease the costs and enhanced the properties of the biocomposites. 3-Aminopropyl Triethoxysilane (3-APE) was used as coupling agent. The effect of NFH content and 3-APE on the mechanical properties and morphology of the biocomposites were investigated. Results show that the effect of NFH content increased Young's modulus but decreased the tensile strength and elongation at break of PLA/PMMA/NFH biocomposites. However, silanized biocomposites using 3-APE) was found to enhanced the tensile strength and Young's modulus but decreased the elongation at break of the silanized biocomposites. Scanning electron microscopy (SEM) study of the tensile fracture surface of the biocomposites indicated that the used of 3-APE as couling agent improved the interfacial interaction netween NFH and PLA/PMMA blends.
17 September 2014 in Polymer Engineering & Science
Hybrid fillers can be produced via various methods, such as physical mixing and chemical modification. However, there is a limited number of studies on the effect of hybridisation on the mechanical performance of hybrid filler-reinforced polymer composites, especially in the context of wear performance. This study investigated the wear resistance of carbon nanotubes (CNTs)/alumina hybrid-filled phenolic composite, where two hybrid methods were used to produce the CNTs/alumina hybrid filler. The CNTs/alumina (CVD hybrid) was synthesised using the chemical vapour deposition (CVD) method, whereas the CNTs-/alumina (physically hybrid) was prepared using the ball milling method. The CNTs/alumina hybrid filler was then used as a filler in the phenolic composites. The composites were prepared using a hot mounting press and then subjected to a dry sliding wear test using a pin-on-disc (POD) tester. The results show that the composite filled with the CVD hybrid filler (HYB composite) had better wear resistance than the composite filled with physically hybrid filler (PHY composite) and pure phenolic. At 5 wt%, the HYB composite showed a 74.68% reduction in wear, while the PHY composite showed a 56.44% reduction in wear compared to pure phenolic. The HYB composite exhibited the lowest average coefficient of friction (COF) compared to the PHY composite and pure phenolic. The average COF decreased with increasing sliding speeds and applied loads. The phenolic composites’ wear and average COF are in the order HYB composite < PHY composite < pure phenolic under all sliding speeds and applied loads.
The main purpose of incorporating Nypa Fruticans (NF) into Polylactic Acid (PLA)/Recycled Low Density Polyethylene (rLDPE) biocomposites is to decrease costs and change the properties. Polyethylene–co–acrylic acid (PEAA) was used as a compatibilizer. The effect of NF content and PEAA on the mechanical properties and morphology of the biocomposites were investigated. Results show that the effect of NF content increased Young’s modulus but decreased the tensile strength and elngation at break of PLA/rLDPE/NF biocomposites. It was found that incorporation of compatibilizer (PEAA) increased the tensile strength and Young’s modulus but decreased the elongation at break of compatibilized biocomposites. Scanning electron microscopy (SEM) study of the tensile fracture surface of the biocomposites indicated that the presence of PEAA improved the interfacial interaction between Nypa Fruticans and LDPE matrix.
21 June 2024 in Archives of Metallurgy and Materials
This study assessed the morphology and chemical composition of coir coconut husk carbon fiber, as well as the impact of fiber diameters on the physical and mechanical properties of polylactic acid composites. Researchers are studying polylactide acid, a biodegradable material. This eco-friendly material’s excellent features, generated from sustainable and renewable sources, have drawn many people. Malaysia’s high coconut fiber output made coir husk a popular commodity. Coconut fibers are lignin, cellulose, and hemicellulose. Alkaline treatment eliminates hemicellulose, oil, wax, and other contaminants from coir fibers and removes lignin. Fourier Transform Infrared Spectroscopy and Scanning Electron Microscopy were used to examine the treated coconut fibers’ chemical modification analysis and morphology. Coconut coir husk was carbonized to produce carbon fiber using a furnace operated at 300°C for 2 hours. Fiber and polylactic acid were mixed in different fiber sizes (0, 53 μm, 75 μm, and 212 μm) via extrusion and injection processing techniques. The results showed that the alkali treatment reduced the hydroxyl (-OH) group and separated the area from the carbonyl (C=O) group of coconut coir husk, which changed the filler’s hydrophilicity. The fiber size of 212 μm was discovered to have the highest tensile and flexural strength values. According to testing, the modified material structure had a better surface fill-matrix bond. Thus, generalized fiber sizing and characterization methods were developed. Regardless of the matrix, this method can characterize natural fiber strength and interfacial shear strength of varied diameters and solid contents.