We fabricated a Surface Enhanced Raman Scattering (SERS)-active surface based on photo-etched and Au-coated GaN. The highest enhancement factor (EF) in SERS and high reproducibility of spectra were obtained from surfaces covered with bunched nanopillars which were produced by relatively long defect-selective photo-etching. The surfaces exhibited SERS enhancements of the order of 2.8 × 106 for malachite green isothiocyanate (MGITC) and 2 × 106 for p-mercaptobenzoic acid (PMBA). These SERS enhancement factors were comparable to those of conventional SERS substrates, while the EF for MGITC was two orders of magnitude larger than the corresponding one reported for the SERS platform made on porous GaN. The standard deviation of the relative intensity of the 1180 cm−1 mode of MGITC was less than 5% for 100 randomly distributed locations across a single platform and less than 10% between different platforms. The SERS signal of MGITC at our GaN/Au surface (kept under ambient conditions) was extremely stable. We could not detect any peak shift or appreciable change of intensity even after three months. We used these surfaces to detect biological molecules such as amino acids and bovine serum albumin (BSA) at low concentration and with short detection time. We developed simple and effective cleaning procedures for our substrates. After cleaning, the same substrate could be used multiple times retaining the SERS activity. We are not aware of any other multiply regenerated SERS substrate which provides simultaneously such high stability with high enhancement, good uniformity, and high reproducibility.
22 January 2014 in Journal of Physics D: Applied Physics
We report on optically pumped lasing at 500 nm on InGaN laser structures grown by plasma assisted molecular beam epitaxy. The InGaN laser structures were grown under group III-rich conditions on bulk (0001) GaN substrates. The influence of the nitrogen flux and growth temperature on the indium content of InGaN layers was studied. We demonstrate that at elevated growth temperatures, where appreciable dissociation rate for In-N bonds is observed, the indium content of InGaN layers increases with increasing nitrogen flux. We show that growth of InGaN at higher temperatures improves optical quality of InGaN quantum wells, which is crucial for green emitters. The influence of piezoelectric fields on the lasing wavelength is also discussed. In particular, the controversial issue of partial versus complete screening of built-in electric field at lasing conditions is examined, supporting the former case.
We demonstrate true-blue 450 nm tunnel junction (TJ) laser diodes (LDs) grown by plasma-assisted molecular beam epitaxy (PAMBE). The absence of hydrogen during PAMBE growth allows us to achieve TJs with low resistance. We compare TJ LDs with LDs of standard construction with p-type metal contact. For both types of LD, the threshold current density is around 3 kA/cm2 and the slope efficiency is 0.5 W/A. We do not observe any significant changes in optical losses and differential gain in TJ LDs compared with standard LDs. The differential resistivity of the TJs for current densities higher than 2 kA/cm2 is below 10−4 Ωcm2.
We demonstrate a stack of two III-nitride laser diodes (LDs) interconnected by a tunnel junction grown by plasma-assisted molecular beam epitaxy. Hydrogen-free growth is used to obtain as-grown p-type conductivity essential for buried tunnel junctions (TJ). We show the impact of the design of tunnel junction. In particular, we show that, apart from the beneficial piezoelectric polarization inside the TJ, heavy doping reduces the differential resistivity even further. The device starts to lase at a wavelength of 459 nm with a slope efficiency (SE) of 0.7 W/A followed by lasing at 456 nm from the second active region doubling the total SE to 1.4 W/A. This demonstration opens new possibilities for the fabrication of stacks of ultraviolet and visible high power pulsed III-nitride LD.