This study reports a new method for photocatalysts to degrade organic dyes on organic semiconductors. A novel strategy is reported to form TiO₂ nanorod (NR)/polydopamine (PDA) electrodes with a photoelectric polymerization strategy for PDA (pep-PDA) to produce cocatalytic electrodes. Amperometric i–t curves and UV-vis diffuse reflectance spectra were recorded and showed that compared with traditional self-polymerization (sp-PDA) and electropolymerization (ep-PDA), TiO₂ NR/pep-PDA exhibited an enhanced photocatalytic activity under visible light. As expected, TiO₂ NR/pep-PDA showed a significant improvement for the degradation of methylene blue (MB) under visible light, which can be attributed to the strong absorption of PDA in the visible light region and the more complete and uniform coverage of the TiO₂ NRs by the pep-PDA film. This study not only proposes a novel and highly efficient way to load PDA on TiO₂ NRs but also provides useful insights for the loading of other photocatalysts on organic semiconductors to degrade organic dyes.

The design of hierarchical structures from biomass has become one of the hottest subjects in the field of microwave absorption due to its low cost, vast availability and sustainability. A kapok-fiber-derived carbon microtube was prepared by facile carbonization, and the relation between the structure and properties of the carbonized kapok fiber (CKF) was systematically investigated. The hollow tubular structures afford the resulting CKF composites with excellent microwave-absorbing performance. The sample with a 30 wt.% loading of CKF in paraffin demonstrates the strongest microwave attenuation capacity, with a minimum reflection loss of −49.46 dB at 16.48 GHz and 2.3 mm, and an optimized effective absorption bandwidth of 7.12 GHz (10.64–17.76 GHz, 2.3 mm) that covers 34% of the X-band and 96% of the Ku-band. Further, more than 90% of the incident electromagnetic wave in the frequency from 4.48 GHz to 18.00 GHz can be attenuated via tuning the thickness of the CKF-based absorber. This study outlines a foundation for the development of lightweight and sustainable microwave absorbers with a high absorption capacity and broad effective absorption bandwidth.

Basalt rockwool wastes with large output, which are toxic and require expensive environmental treatment, are produced during the production of rock wool. Hence, it is urgent to find an effective method to reuse these materials. In this study, polyaniline (PANI)-coated basalt rockwool wastes (BRWs) were prepared as fillers to serve in coatings for the anticorrosion study. Results show that the PANI-coated BRW (PANI@BRW) had enhanced dispersion stability in several conventional solvents and improved the anticorrosion performance of the epoxy resin coating. A high protection efficiency of 97.7% could be obtained from the coating with 5% fillers after immersion for 30 days. This study not only provides a promising method of solving the issues caused by BRW, but also turns these wastes into valuable substances.

The global water crisis is becoming more and more serious, and solar steam generation has recently been investigated for clean water production and wastewater treatment. However, the efficiency of solar vapor transfer is still low. It is a great challenge to find photothermal materials which simultaneously have high energy transfer efficiency, facile production, and are low cost. To address this, we propose a method which is simple, low cost and suitable for large-scale preparation to fabricate the photothermal materials based on using recycled natural rubber sponge (NRS) coated with polydopamine (PDA). X-ray photoelectron spectroscopy analysis confirmed that when the PDA coated the surface of the NRS, the hydrophilicity of the sponge was significantly improved. Scanning electron microscopy characterization showed that the PDA-coated natural rubber sponge (PNRS) maintained the porous 3D skeleton of the pristine sponge. As a result, PNRS exhibits excellent photothermal properties, a very high evaporation rate of 1.35 kg m⁻² h⁻¹, and an energy transfer efficiency of 84.6% can be achieved under a light intensity of 1 sun (1 kW m⁻²). It is worth noting that the vapor generation of PNRS is still at a high level with 1.06 and 1.09 kg m⁻² h⁻¹ in the corrosive liquids of 1 M H₂SO₄ and 0.5 M NaOH, respectively. The photothermal materials based on using recycled NRS have good application prospects in seawater desalination and the purification of wastewater, which also provides a new method for the recycling of waste NRS.

In this paper, biodegradable epoxidized natural rubber containing cyclic carbonate groups (CNR) was prepared by the reaction between epoxidized natural rubber (ENR) and carbon dioxide. Dynamic disulfide bonds and a boronic ester structure were successfully constructed and then the cross-linking network was formed by the thermally initiated “click” reaction between thiol groups of the cross-linker and the residual epoxy groups of ENR. As a result of the exquisite double dynamic covalent structure, the material exhibits high self-healing efficiency. Moreover, by virtue of the cyclic carbonate structure of the CNR, the natural rubber was confirmed to be biodegradable according to the biodegradable measurement. To the best of our knowledge, natural rubber with biodegradable and self-healing characteristics was obtained for the first time.