The evolution of electric double-layer capacitors (EDLCs) has significantly benefited from advancements in graphene-based materials, particularly graphene oxide (GO) and reduced graphene oxide (rGO). This systematic review consolidates and analyzes existing research on the roles of GO and rGO in enhancing the performance of EDLCs, focusing on synthesis methods, electrode fabrication, electrolytes, and performance metrics such as capacitance, energy density, and cycling stability. Following the PICOS and PRISMA frameworks, a comprehensive literature search was conducted across Scopus, Web of Science, PubMed, and IEEE Xplore, covering the period from 2010 to 2023. A total of 128 articles were initially identified, with 27 studies meeting the inclusion criteria after rigorous screening and full-text analysis. Key findings reveal that the incorporation of GO and rGO in EDLCs leads to significant improvements in specific capacitance, energy density, and cycling stability. Notable advancements include novel synthesis techniques and composite materials such as nitrogen-doped graphene, graphene/polyaniline hybrids, and various metal oxide–graphene composites, which exhibit superior electrochemical performance. However, challenges such as material scalability, environmental sustainability, and consistency in synthesis methods remain. This review stresses the great potential of GO and rGO in the development of high-performance EDLCs and highlights the need for continued research to address existing challenges and further optimize material properties and fabrication techniques.
This study presents a numerical investigation of surface plasmon resonance (SPR) sensors based on multilayer configurations incorporating BK7, silver, silicon nitride (Si3N4), and black phosphorus (BP). Using the transfer matrix method, the optical performance of four architectures was evaluated under refractive index perturbations consistent with values reported in prior theoretical and experimental studies. The sensor response was characterized through metrics such as angular sensitivity, resonance shift, full width at half maximum, attenuation, and derived figures including detection accuracy and limit of detection. Parametric optimization was performed for the thickness of each functional layer to enhance sensing performance. Among all configurations, those incorporating both Si3N4 and BP demonstrated the highest angular sensitivity, reaching up to 394.46°/RIU. These enhancements were accompanied by increased attenuation and spectral broadening, revealing trade-offs in sensor design. The results, based entirely on numerical modeling, provide a comparative framework for guiding SPR sensor optimization under idealized optical conditions.
This work reports the fabrication and optimization of nylon/multi-walled carbon nanotube (MWCNT) nanocomposite-based triboelectric nanogenerators (TENGs) using a spin coating method. By carefully tuning the MWCNT concentration, the device achieved a substantial enhancement in electrical output, with open-circuit voltage and short-circuit current peaking at 29.7 V and 3.0 μA, respectively, at 0.05 wt% MWCNT loading on the surface of nylon. The corresponding power density reached approximately 13.9 mW/m2, representing a significant improvement over pure nylon-based TENGs. The enhanced performance is attributed to improved charge trapping and dielectric properties due to well-dispersed MWCNTs on the surface of nylon, while excessive loading caused agglomeration, reducing efficiency. This lightweight, flexible nanocomposite TENG offers a promising solution for efficient, sustainable energy harvesting in wearable electronics and self-powered sensor systems, highlighting its potential for practical energy applications.
Enhancing nanoparticles’ anti-cancer capabilities as drug carriers requires the careful adjustment of formulation parameters, including loading efficiency, drug/carrier ratio, and synthesis method. Small adjustments to these parameters can significantly influence the drug-loading efficiency of nanoparticles. Our study explored how chitosan and polyethylene glycol (PEG) coatings affect the structural properties, drug-loading efficiency, and anti-cancer efficacy of Fe3O4 nanoparticles (NPs). The loading efficiency of the NPs was determined using FTIR spectrometry and XRD. The quantity of chrysin incorporated into the coated NPs was examined using UV–Vis spectrometry. The effect of the NPs on cell viability and apoptosis was determined by employing the HCT 116 human colon carcinoma cell line. We showed that a two-fold increase in drug concentration did not impact the loading efficiency of Fe3O4 NPs coated with PEG. However, there was a 33 Å difference in the crystallite sizes obtained from chitosan-coated Fe3O4 NPs and drug concentrations of 1:0.5 and 1:2, resulting in decreased system stability. In conclusion, PEG coating exhibited a higher loading efficiency of Fe3O4 NPs compared to chitosan, resulting in enhanced anti-tumor effects. Furthermore, variations in the loaded amount of chrysin did not impact the crystallinity of PEG-coated NPs, emphasizing the stability and regularity of the system.
Introduction: Heavy metal contamination in water represents a major environmental and public health challenge because toxic ions frequently occur as complex multi-species mixtures rather than isolated pollutants. This study presents a numerical design and optimization of a surface plasmon resonance (SPR) sensor based on a LaF/Au/BaTiO3/WS2 heterostructure for monitoring refractive-index changes associated with mixed heavy metal ions in aqueous media. Methodology: The optical response of the multilayer sensor was evaluated using the transfer matrix method under TM-polarized illumination at 633 nm. Systematic optimization was performed for the prism substrate, Au thickness, dielectric oxide layer, and 2D nanomaterial interface. The final configuration consisted of a LaF prism, 50 nm Au film, 2.0 nm BaTiO3 spacer, and 0.80 nm WS2 monolayer. Sensor performance was assessed using resonance-angle shift, sensitivity, detection accuracy, quality factor, figure of merit, FWHM, attenuation, and estimated limit of detection. Results and Discussion: The optimized LaF/Au/BaTiO3/WS2 configuration produced stable simulated SPR responses across single, binary, quaternary, and five-ion heavy metal matrices. The WS2 monolayer provided the highest angular displacement among the evaluated 2D materials, while BaTiO3 improved field confinement and limited optical damping in the numerical model. The configuration maintained attenuation near 1.6%, FWHM values around 7.9°, detection accuracy between 0.030 and 0.032 deg−1, and model-based refractometric LoD values down to 3.49 × 10−5 RIU under the assumed angular-resolution criterion. Conclusions: The proposed LaF/Au/BaTiO3/WS2 SPR configuration provides a numerical framework for label-free monitoring of refractive-index changes associated with complex heavy-metal-ion mixtures in contaminated water. Experimental fabrication and testing are required to validate the simulated performance.
We investigated the effect of film thickness d on the acoustic response of titanium dioxide (TiO2) layers deposited on Ti, SiO2, Al2O3, and Si substrates. For each TiO2 thickness–substrate pair, we computed reflection coefficients and acoustic signatures under normal operating conditions of a conventional scanning acoustic microscope, then deduced the Rayleigh-wave velocity VR from spectral analysis of the oscillatory layer–substrate signatures. As d increased, VR either rose or fell, depending on the layer/substrate pair, and eventually approached a saturation value. For TiO2/SiO2 and TiO2/Ti, VR increased from those of the bare substrates (SiO2: 3415 m/s; Ti: 2965 m/s) toward 3830 m·s−1, the bulk TiO2 value. For TiO2/Al2O3 and TiO2/Si, VR decreased from the substrate values (Al2O3: 5700 m/s; Si: 4712 m/s) toward the same TiO2 saturation. These dispersion trends are consistent with stiffening (VR (TiO2) > VR (Substrate)) or loading (VR (TiO2) < VR (Substrate)) effects. The resulting VR–d dispersion charts provide theoretical reference trends relating thickness and Rayleigh-wave velocity for the idealized TiO2/substrate systems considered here.