The textile industrys discharges have long been regarded as severe water pollution. The photocatalytic degradation of dyes using semiconductors is one of the crucial methods. The present study efficiently used the mechanical method to synthesize Iron oxide Nanoparticles. XRD, FT-IR, UV-Vis DRS, and Raman analyses were performed to analyze the structural and optical. From the data provided by XRD and Raman data, we believed that the as-synthesized Iron oxide was pure hematite (α-Fe2O3) with a hexagonal structure. Additionally, the EDS results show that the synthesized material is pure. By adjusting specific parameters, including the dye concentration, the catalyst dosage, the pH, and the oxidizing agent such as H2O2 and K2S2O8, the degradation of eosin yellowish using Fe2O3 as a photocatalyst has been discussed. Additionally, the kinetics of eosin yellowish degradation has been studied. A study was also conducted using Fe2O3 nanoparticles attached to polyurethane polymer (PU) to investigate its photocatalytic activity on methylene blue, methyl orange, and indigo carmine. In 30minutes, nearly 90 of the dyes had degraded. The total organic carbon (TOC) analysis confirmed this result.
Anaerobic Co-Digestion of Human Feces with Rice Straw for Biogas Production: A Case Study in Sunyani: The choice of feedstock for biogas production should not only be limited to organic waste like agricultural products, food, and animal waste. Human feces could also be considered a source of biogas production. The ever-increasing cost of fossil fuels and environmental pollution threats are forcing the search for alternative energy sources. Several types of research have to unlock the mysteries behind the difficulties of producing biogas from human feces, especially the production of more HN3, which is a greenhouse gas because of its low C:N ratio. This research experimentally investigated how to reduce their amount using rice straw with a high C:N ratio. Several combinations were made between the human waste and the rice straw at different ratios during the experiment. The result shows that the optimal outcome for methane production fell on the 50 HF and 50 RS combination due to the actions of both aerobic and anaerobic processes.
20 April 2024 in Nanotechnology for Environmental Engineering
The study optimized the chromium removal capacity of Fe2O3 nanoparticles through the infusion of cobalt using a single-step synthesis method. This approach not only enhanced their magnetic properties but also employs less-chemical synthesis techniques, ultimately yielding highly magnetic CoFe2O4 nanoparticles and less impurities. The prepared materials underwent comprehensive testing, encompassing examinations of their optical properties, structure, chemical composition, and surface characteristics using various analyticals methods. In a span of 90 min under visible light exposure, CoFe2O4 nanoparticles exhibit the ability to remove more that 90% of chromium. This was corroborated through analysis using Inductively Coupled Plasma-Optical Emission Spectroscopy (ICP-OES). Moreover, the study illustrates that increased temperatures amplify the endothermic process of chromium adsorption. Positive ΔH°, negative ΔS°, and heightened Cr(IV) adsorption are linked to the temperature effects on solubility, mobility, and dissolved oxygen. Both Langmuir (R2 = 0.95, RL = 0.055) and Freundlich models (R2 = 0.98, n = 0.69) suggest favorable adsorption. The efficient Cr(IV) adsorption by CoFe2O4 nanocomposite is attributed to a rapid reaction rate and substantial capacity, following pseudo-second order kinetics (rate constant 0.01 g mg−1 min−1, R2 = 0.99). Graphical abstract