The potential pharmaceutical application of nanoparticles has led to the toxicity within the male reproductive system. In the present study, the effects of silver nanoparticles (Ag-NPs) on hematological parameters, free radical generation, antioxidant system, sperm parameters, and organ histo-morphometry in male rats were investigated. Ag-NPs were produced by the reduction of silver ions, while the formation of which was monitored by UV–visible spectrophotometry. Zeta potential, transmission, and scanning electron microscopies were applied for the characterization of AgNPs. A total of 30 rats were divided into 6 groups and were sub-dermally exposed to Ag-NPs at the dosage of 0 (control), 10, and 50 mg/kg bodyweight (bw) doses for either 7 or 28 days. Ag-NP administration altered hematological indices and caused dose-dependent decreases in sperm motility, velocity, kinematic parameters, concentrations of luteinizing hormone, follicle-stimulating hormone, and testosterone. In the epididymis and testis, the concentrations of malondialdehyde and peroxide increases while superoxide dismutase, catalase, reduced glutathione, and total thiol group decreases. These findings suggest that Ag-NP triggered hormonal imbalance and induce oxidative stress in testis and epididymis; which negatively affect sperm parameters of male rats.

Plain polyvinyl alcohol (PVA) nanofibres and novel polyvinyl alcohol benzene tetracarboxylate nanofibres incorporated with strontium, lanthanum and antimony ((PVA/Sr-TBC), (PVA/La-TBC) and (PVA/Sb-TBC)), respectively, where TBC is benzene 1,2,4,5-tetracarboxylate adsorbents, were fabricated by electrospinning. The as-prepared electrospun nanofibres were characterized by scanning electron microscope (SEM), Fourier transform infrared (FTIR) and thermogravimetric analysis (TGA). Only plain PVA nanofibres followed the Freundlich isotherm with a correlation coefficient of 0.9814, while novel nanofibres (PVA/Sb-TBC, PVA/Sr-TBC and PVA/La-TBC) followed the Langmuir isotherm with correlation coefficients of 0.9999, 0.9994 and 0.9947, respectively. The sorption process of all nanofibres followed a pseudo second-order kinetic model. Adsorption capacity of novel nanofibres was twofold and more compared to that of plain PVA nanofibres. The thermodynamic studies: apparent enthalpy (ΔH°) and entropy (ΔS°), showed that the adsorption of Pb(II) onto nanofibres was spontaneous and exothermic. The novel nanofibres exhibited higher potential removal of Pb(II) ions than plain PVA nanofibres. Ubiquitous cations adsorption test was also investigated and studied.

Macadamianutshell powder oxidized by hydrogen peroxide solutions (MHP) was functionalized by immobilizing 1,5′-diphenylcarbazide (DPC) on its surface. The effectiveness of grafting was confirmed by the Fourier transform infrared spectrum due to the presence of NH and C=C stretches at 3361, 1591, and 1486 cm⁻¹, respectively, on the grafted material which were absent in the nongrafted material. Thermogravimetric analysis revealed that the presence of DPC on the surface ofMacadamiashells lowered the thermal stability from 300°C to about 180°C owing to the volatile nature of DPC. Surface roughness as a result of grafting was appreciated on the scanning electron microscopy images. Parameters influencing the adsorptive removal of Cr(VI) were examined and found to be optimal at pH 2, 120 min, 150 mg/L, and 2.5 g/L. Grafting MHP with DPC leads to an increase in the Langmuir monolayer capacity from 37.74 to 72.12 mg/g. Grafting MHP with DPC produced adsorbent with improved removal efficiency for Cr(VI).

The occurrence of residual antifungal agents through indiscriminate prophylactic use and inappropriate disposal has been reported in wastewater treatment plants (WWTPs), surface water, and groundwater environments. Opportunistic pathogenic aquatic yeasts develop resistance to commonly used antifungal agents through continued exposure to residual antifungal agents in environmental waters. This poses a major public health concern. The present review attempts to provide a brief description of antifungal drugs, with a focus on the most widely used class of antifungal drugs, the azoles, as emerging contaminants in environmental water. Routes of exposure of azole antifungal drugs in wastewater treatment plants, surface water, and groundwater are discussed. The presence of pathogenic yeasts in environmental water, the associated azole resistance, and the risk of exposure to humans and microbiota are highlighted. Management actions needed to curtail the spread and minimise the risks are also indicated. Further research on the occurrence of antifungal agents in wastewater and environmental water is vital to better understand and mitigate the associated health-related risks.

This research work reports on pure and acid-treated fennel seed biomaterials for the removal of metal ions of copper Cu(II), lead Pb(II), and methylene blue (MB) dye from aqueous solution by batch adsorption. Pure fennel seeds were labelled as PFS; nitric and sulphuric acid-treated seeds were designated as NAFS and SAFS, respectively. The adsorbents were characterised by SEM, EDX, FTIR, XRD, and BET. The SEM images revealed that the surface of the adsorbents was porous. However, physicochemical characterization further revealed that BET surface area, pore size, and pore width increased for NAFS and SAFS compared to PFS. FTIR results revealed that the peaks for cellulose −COC and −OH decreased considerably for NAFS and SAFS; this indicated that cellulose was hydrolyzed during acid treatment. Adsorption data showed that all biomaterials had a higher affinity for MB dye more than Pb(II) and Cu(II) metal ions. The maximum adsorption capacities onto PFS were 6.834, 4.179, and 2.902 mg/g and onto NAFS are 15.28, 14.44, and 4.475 mg/g, while those onto SAFS are 19.81, 18.79 and 6.707 mg/g respective for MB dye, Pb(II), and Cu(II) ions. Postadsorption analysis revealed that adsorption of Pb(II) and Cu(II) was controlled mainly by the electrostatic attraction, while that of MB was synergistic of electrostatic attraction, π- π interaction, and hydrogen bond. It was found that the uptake processes of MB dye onto all adsorbents fitted Freundlich while both cations were described by Langmuir model. The thermodynamic parameters [ ] ^o and [ ] ^o indicated the endothermic nature and spontaneity of the processes, respectively.