Energy storage system (ESS) technology is still the logjam for the electric vehicle (EV) industry. Lithium-ion (Li-ion) batteries have attracted considerable attention in the EV industry owing to their high energy density, lifespan, nominal voltage, power density, and cost. In EVs, a smart battery management system (BMS) is one of the essential components; it not only measures the states of battery accurately, but also ensures safe operation and prolongs the battery life. The accurate estimation of the state of charge (SOC) of a Li-ion battery is a very challenging task because the Li-ion battery is a highly time variant, non-linear, and complex electrochemical system. This paper explains the workings of a Li-ion battery, provides the main features of a smart BMS, and comprehensively reviews its SOC estimation methods. These SOC estimation methods have been classified into four main categories depending on their nature. A critical explanation, including their merits, limitations, and their estimation errors from other studies, is provided. Some recommendations depending on the development of technology are suggested to improve the online estimation.
Renewable Energy Sources (RES) showed enormous growth in the last few years. In comparison with the other RES, solar power has become the most feasible source because of its unique properties such as clean, noiseless, eco-friendly nature, etc. During the extraction of electric power, the DC–DC converters were given the prominent interest because of their extensive use in various applications. Photovoltaic (PV) systems generally suffer from less energy conversion efficiency along with improper stability and intermittent properties. Hence, there is a necessity of the Maximum power point tracking (MPPT) algorithm to ensure the maximum power available that can be harnessed from the solar PV. In this paper, the most important features of the DC/DC converters along with the MPPT techniques are reviewed and analyzed. A detailed comprehensive analysis is made on different converter topologies of both non-isolated and isolated DC/DC converters. Then, the modulation strategies, comparative performance evaluation are addressed systematically. At the end, recent advances and future trends are described briefly and considered for the next-generation converter’s design and applications. This review work will provide a useful structure and reference point on the DC/DC converters for researchers and designers working in the field of solar PV applications.
Currently, enormous attention is being paid to the difficult design and synthesis of hierarchical nanosheet structures for high-performance supercapacitors. In the present study, we have explored electrochemically synthesized nanostructures of free standing NiCo2O4@NiCo2O4 composite electrode interconnected hierarchical nanoplates, and NiCo2O4 connected hierarchical nanowires were directly grown on a high conductivity Ni foam substrate as an electrode for supercapacitor applications through a cost effective and simple chemical bath deposition method. The electrochemical properties were investigated via cyclic voltammetry, galvanostatic charge–discharge and electrochemical impedance spectroscopy studies. This optimized NiCo2O4@NiCo2O4 nanoplate electrode delivered a remarkable specific capacitance of 2800 F g−1 at a current density of 35 A g−1, which is higher than that of the NiCo2O4 nanowire electrode (1200 F g−1 at 35 A g−1) in 3 M KOH aqueous solution, with good electrochemical and superior cycling life properties because of its higher conductivity, broad surface area and the mesopores on its walls. The NiCo2O4@NiCo2O4 nanoplate composite electrode is directly grown on the high conductivity Ni foam substrate with NiCo2O4 nanowires to support efficient electrocatalytic oxidation reactions. The mesoporous features of the NiCo2O4@NiCo2O4 nanoplate electrode enhance the properties through fast electron/ion transfer and enhance the utilization of the electrode material and large number of electroactive sites. All these results indicate that the NiCo2O4@NiCo2O4 nanoplate composite electrode would be a promising positive electrode material for flexible electrochemical capacitors.
Schematic of the synthesis of the honeycomb with a folded silk-like NF@NiMoO4@NiCo2O4 nanostructure, honeycomb-like NF@NiMoO4 structure and nanoplate-like NF@NiCo2O4 structure on nickel foam (NF).
In the context of constant growth in the utilization of the Li-ion batteries, there was a great surge in the quest for electrode materials and predominant usage that lead to the retiring of Li-ion batteries. This review focuses on the recent advances in the anode and cathode materials for the next-generation Li-ion batteries. To achieve higher power and energy demands of Li-ion batteries in future energy storage applications, the selection of the electrode materials plays a crucial role. The electrode materials, such as carbon-based, semiconductor/metal, metal oxides/nitrides/phosphides/sulfides, determine appreciable properties of Li-ion batteries such as greater specific surface area, a minimal distance of diffusion, and higher conductivity. Various classifications of the anode materials such as the intercalation/de- intercalation, alloy/de-alloy, and various conversion materials are illustrated lucidly. Further, the cathode materials, such as nickel-rich LiNixCoyMnzO2 (NCM), were discussed. NCM members such as NCM 333, NCM 523 that enabled to advance for NCM622 and NCM81are reported. The nanostructured materials bridged the gap in the realization of next-generation Li-ion batteries. Li-ion batteries’ electrode nanostructure synthesis, performance, and reaction mechanisms were considered with great concern. The serious effects of Li-ion batteries disposal need to be cut significantly to reduce the detrimental effect on the environment. Hence, the recycling of spent Li-ion batteries has gained much attention in recent years. Various recycling techniques and their effect on the electroactive materials are illustrated. The key areas covered in this review are anode and cathode materials and recent advances along with their recycling techniques. In light of crucial points covered in this review, it constitutes a suitable reference for engineers, researchers, and designers in energy storage applications.
Hyperthermia is a noninvasive method that uses heat for cancer therapy where high temperatures have a damaging effect on tumor cells. However, large amounts of heat need to be delivered, which could have negative effects on healthy tissues. Thus, to minimize the negative side effects on healthy cells, a large amount of heat must be delivered only to the tumor cells. Magnetic hyperthermia (MH) uses magnetic nanoparticles particles (MNPs) that are exposed to alternating magnetic field (AMF) to generate heat in local regions (tissues or cells). This cancer therapy method has several advantages, such as (a) it is noninvasive, thus requiring surgery, and (b) it is local, and thus does not damage health cells. However, there are several issues that need to achieved: (a) the MNPs should be biocompatible, biodegradable, with good colloidal stability (b) the MNPs should be successfully delivered to the tumor cells, (c) the MNPs should be used with small amounts and thus MNPs with large heat generation capabilities are required, (d) the AMF used to heat the MNPs should meet safety conditions with limited frequency and amplitude ranges, (e) the changes of temperature should be traced at the cellular level with accurate and noninvasive techniques, (f) factors affecting heat transport from the MNPs to the cells must be understood, and (g) the effect of temperature on the biological mechanisms of cells should be clearly understood. Thus, in this multidisciplinary field, research is needed to investigate these issues. In this report, we shed some light on the principles of heat generation by MNPs in AMF, the limitations and challenges of MH, and the applications of MH using multifunctional hybrid MNPs.