The work described in this article is aimed at investigating the properties of a group of Ti-Zr-Nb alloys. In modern orthopedics and traumatology, the use of materials for bone implants with a minimum modulus of elasticity is becoming increasingly important. This is due to a number of advantages that allow for better integration of the implants with the bone tissue, including the reduction in the detrimental effect of the load-shielding effect, a better load distribution, and stress distribution, which allows for increasing the life of the implant. It is known that the lowest modulus of elasticity in titanium alloys at normal temperature is achieved by the phase composition consisting of metastable β-phase. It is possible to achieve the desired structure by a combination of alloy composition selection and heat treatment. Quenching of titanium alloys allows for the high-temperature β-phase to be fixed. This paper provides justification of the choice of compositions of the studied alloys by calculation methods. The structure of alloys after melting in a vacuum electric arc furnace in an argon environment was studied. The ingots obtained had a dendritic structure. Homogenizing annealing in a vacuum furnace at 1000 °C for 4 h was used to equalize the composition. The structure of the alloyed sheets after hot rolling and hot rolling and quenching was investigated. The microstructure of the plates in both variants had uniform grains of polyhedral shape. X-ray phase analysis of the plates showed that the content of metastable β-phase was 100% before and after quenching. Microhardness testing of the plates showed no significant effect of quenching. The result of the mechanical properties study showed an increase in the plasticity of the material after quenching, with the tensile plots of the samples after quenching reflecting the area where the reverse phase transition of β’<-> α’’ occurs. Mechanical studies by cyclic loading showed the presence of a superelasticity effect. The Young’s modulus study gave a result of 51 GPa for one of the compositions studied. The combination of properties of the materials under investigation has the potential for promising use as a basis for bone implants.

Hip joint implants are among the most prevalent types of medical implants utilized for the replacement of damaged joints. The utilization of modern implant materials, such as cobalt–chromium alloys, stainless steel, titanium, and other titanium alloys, is accompanied by challenges, including the toxicity of certain elements (e.g., aluminum, vanadium, nickel) and excessive Young’s modulus, which adversely impact biomechanical compatibility. A mismatch between the stiffness of the implant material and the bone tissue, known as stress shielding, can lead to adverse outcomes such as bone resorption and implant loosening. Recent studies have shifted the focus to β-titanium alloys due to their exceptional biocompatibility, corrosion resistance, and low Young’s modulus, which is close to the Young’s modulus of bone tissue (10–30 GPa). In this study, the microstructure, mechanical properties, and phase stability of the Ti-38Zr-11Nb alloy were investigated. Energy dispersion spectrometry was employed to confirm the homogeneous distribution of Ti, Zr, and Nb in the alloy. A subsequent microstructural analysis revealed the presence of elongated β-grains subsequent to rolling and quenching. Furthermore, grinding contributed to the process of recrystallization and the formation of subgrains. X-ray diffraction analysis confirmed the presence of a stable β-phase under any heat treatment conditions, which can be explained by the use of Nb as a β-stabilizer and Zr as a neutral element with a weak β-stabilizing effect in the presence of other β-stabilizers. Furthermore, the modulus of elasticity, as determined by tensile testing, exhibited a decline from 85 GPa to 81 GPa after annealing. Mechanical tests demonstrated a substantial enhancement in tensile strength (from 529 MPa to 628 MPa) concurrent with a 32% reduction in elongation to fracture of the samples. These alterations are attributed to microstructural transformations, including the formation of subgrains and the rearrangement of dislocations. This study’s findings suggest that the Ti-38Zr-11Nb alloy has potential as a material of choice due to its lower Young’s modulus compared to traditional materials and its stable β-phase, which enhances the implant’s durability and reduces the risk of brittle phases forming over time. This study demonstrates that the corrosion resistance of titanium grade 2 and Ti-38Zr-11Nb is comparable. The material in question exhibited no evidence of cytotoxic activity in the context of mammalian cells.

Composite materials "base–transition layer–surface metal layer (Ta/Ti)" were produced using a complex vacuum technology including magnetron sputtering. The structure (by scanning electron microscopy, Auger electron spectroscopy, X-ray diffractometry) and mechanical properties were studied. An almost linear increase in the thickness of both the surface and transition layers was observed with increasing deposition time and power; however, the growth of the surface layer slowed down with increasing power above some critical value. The transition zone with the growth of time stopped growing upon reaching about 300 nm and was formed approximately 2 times slower than the surface one (and about 3.5 times slower with power). It was noted that with equal sputtering–deposition parameters, the layer growth rates for tantalum and titanium were the same. In the sample with a Ta surface layer deposited on titanium, a strongly textured complex structure with alpha and beta Ta was observed, which is slightly related to the initial substrate structure and the underlying layer. However, even at small thicknesses of the surface layer, the co-deposition of tantalum and titanium contributes to the formation of a single tantalum phase, alpha.

The production of homogeneous Ti–10Nb–(1–3)Mo (at %) alloys in the form of semifinished products (plates) was studied through multiple remeltings and homogenization annealing. Metallographic studies of the resulting materials in cast, rolled, and annealed states were carried out. The effect of annealing and composition on the structure, phase composition, and mechanical properties of the Ti–10Nb–(1–3)Mo alloy was revealed. Homogeneity after smelting was achieved by annealing at a temperature of 950°C for 12 h. An increase in the Mo content in the Ti–10Nb–(1–3)Mo alloy led to an increase in the strength of the alloys, while the ductility decreased. The achievement of high strength characteristics in selected alloys was associated with the development of annealing parameters after plastic deformation, namely, controlling the size of recrystallized grains and separating the α and β phases. In addition to α-Ti and β-Ti, the samples contained small amounts of ω-Ti, which led to a sharp increase in the hardness of the samples.

The action of electrolytic plasma polishing (EPP) on the surface morphology, microstructure, and phase and chemical composition of plates made of titanium of the VT1-0 brand, a VT6 alloy, niobium of the Nb1 brand, and promising biomedical Ti–26Nb and Ti–23Nb–5Zr titanium alloys is studied. It is shown that EPP is a promising method for effective final treatment of the surface of biomedical titanium alloys, which noticeably positively affects the surface morphology and distribution of alloying elements over the surface of the samples under study without inducing a change in the microstructure and chemical and phase composition.

The research described in this article is a continuation of a series of studies on biocompatible materials, focused on finding the optimal alloy composition and heat treatment regimes. The use of materials with a low Young’s modulus ensures the long-term safety of the implant by reducing the stress shielding effect, which causes bone resorption. This work investigates the effect of alloying with niobium in the range of (8–10) at. % on the Ti-38Zr alloy, specifically its structure, mechanical properties, Young’s modulus, and superelasticity. In this study, plates of the Ti-38Zr-(8-10)Nb (at. %) alloy were investigated after quenching and subsequent annealing. In Ti-38Zr-(8-10)Nb alloys, quenching from 600 °C fixes the β-phase of Ti. In alloys with (8-9)Nb, this is a metastable β-phase, as evidenced by its superelastic behavior under cyclic tension. Annealing at 400 °C leads to a clear decomposition of the quenched high-temperature β-phase in Ti-38Zr-(8-9)Nb alloys into β- and α′-phases. Based on the mechanical test results, it can be inferred that the precipitation of the brittle ω-phase and the α′-phase occur concurrently, since annealing at 400 °C causes a pronounced embrittlement of the Ti-38Zr-(8–9)Nb alloys (with elongation dropping from ~15% to 0.7–2.5%, respectively) alongside a substantial increase in strength (from 500 MPa to 1010 MPa). For the Ti-38Zr-10Nb alloy, the ductility also declines but remains within acceptable limits (from ~14% to ~10%), while the strength rises from 520 MPa to 630 MPa. The Young’s modulus of the Ti-38Zr-(8-10)Nb alloy after quenching is ~80 GPa. After annealing, it increases to 95 GPa for alloys with (8-9)Nb, while for 10Nb it remains at approximately 80 GPa.