John Cleary

Dr. John Cleary

orcid

Research Focus & Metrics

Academic Career Length

24Years (2003-Present)

(Calculated once Scilit publication data is synced: current year − year of first publication + 1)

Representative Publications

View All Publications
17 September 2018 in Resources
Verified
Journal Article
Open access
PDF file
LKLaurence Kavanagh
Laurence Kavanagh
JKJerome Keohane
Jerome Keohane
GCGuiomar Garcia Cabellos
Guiomar Garcia Cabellos
ALAndrew Lloyd
Andrew Lloyd
JCJohn Cleary
John Cleary
Lithium is a key component in green energy storage technologies and is rapidly becoming a metal of crucial importance to the European Union. The different industrial uses of lithium are discussed in this review along with a compilation of the locations of the main geological sources of lithium. An emphasis is placed on lithium’s use in lithium ion batteries and their use in the electric vehicle industry. The electric vehicle market is driving new demand for lithium resources. The expected scale-up in this sector will put pressure on current lithium supplies. The European Union has a burgeoning demand for lithium and is the second largest consumer of lithium resources. Currently, only 1–2% of worldwide lithium is produced in the European Union (Portugal). There are several lithium mineralisations scattered across Europe, the majority of which are currently undergoing mining feasibility studies. The increasing cost of lithium is driving a new global mining boom and should see many of Europe’s mineralisation’s becoming economic. The information given in this paper is a source of contextual information that can be used to support the European Union’s drive towards a low carbon economy and to develop the field of research.

ALAnnija Lace
Annija Lace
DRDavid Ryan
David Ryan
MBMark Bowkett
Mark Bowkett
JCJohn Cleary
John Cleary
Chromium contamination of drinking water has become a global problem due to its extensive use in industry. The most commonly used methods for chromium detection in water are laboratory-based methods, such as atomic absorption spectroscopy and mass spectroscopy. Although these methods are highly selective and sensitive, they require expensive maintenance and highly trained staff. Therefore, there is a growing demand for cost effective and portable detection methods that would meet the demand for mass monitoring. Microfluidic detection systems based on optical detection have great potential for onsite monitoring applications. Furthermore, their small size enables rapid sample throughput and minimises both reagent consumption and waste generation. In contrast to standard laboratory methods, there is also no requirement for sample transport and storage. The aim of this study is to optimise a colorimetric method based on 1,5-diphenylcarbazide dye for incorporation into a microfluidic detection system. Rapid colour development was observed after the addition of the dye and samples were measured at 543 nm. Beer’s law was obeyed in the range between 0.03–3 mg·L−1. The detection limit and quantitation limit were found to be 0.023 and 0.076 mg·L−1, respectively.

24 March 2021 in Chemosensors
Verified
Journal Article
Open access
PDF file
ALAnnija Lace
Annija Lace
JCJohn Cleary
John Cleary
Heavy metal pollution of water has become a global issue and is especially problematic in some developing countries. Heavy metals are toxic to living organisms, even at very low concentrations. Therefore, effective and reliable heavy metal detection in environmental water is very important. Current laboratory-based methods used for analysis of heavy metals in water require sophisticated instrumentation and highly trained technicians, making them unsuitable for routine heavy metal monitoring in the environment. Consequently, there is a growing demand for autonomous detection systems that could perform in situ or point-of-use measurements. Microfluidic detection systems, which are defined by their small size, have many characteristics that make them suitable for environmental analysis. Some of these advantages include portability, high sample throughput, reduced reagent consumption and waste generation, and reduced production cost. This review focusses on developments in the application of microfluidic detection systems to heavy metal detection in water. Microfluidic detection strategies based on optical techniques, electrochemical techniques, and quartz crystal microbalance are discussed.

28 September 2004 in Langmuir
Verified
Journal Article
Closed access
JCJohn Cleary
John Cleary
LBLev Bromberg
Lev Bromberg
EMEdmond Magner
Edmond Magner

14 August 2014 in Analytical Methods
Verified
Journal Article
Open access
PDF file
DCDeirdre Cogan
Deirdre Cogan
JCJohn Cleary
John Cleary
CFCormac Fay
Cormac Fay
ARAoife Rickard
Aoife Rickard
KJKamil Jankowski
Kamil Jankowski
Dermot DiamondDermot Diamond
Dermot Diamond
This study demonstrates that by combining a modified version of the Berthelot method with microfluidic technologies and LED based optical detection systems, a low cost monitoring system for detection of ammonia in fresh water and wastewater can be developed. The assay developed is a variation on the Berthelot method, eliminating several steps previously associated with the method to create a nontoxic and simple colorimetric assay. The previous Berthelot method required the addition of three reagents, mixed sequentially with the sample, which complicates the microfluidic system design. With the modified method, comparable results were attained using a single reagent addition step at a 1 : 1 v/v reagent to sample ratio, which significantly simplifies the fluidic handling requirement for integration into an autonomous sensing platform. The intense colour generated in the presence of ammonia is detected at a wavelength of 660 nm. The method allows for ammonia determination up to 12 mg L−1 NH4 + with a limit of detection of 0.015 mg L−1 NH4 +. Validation was achieved by analysing split water samples by the modified method and by ion chromatography, resulting in an excellent correlation coefficient of 0.9954. The method was then implemented into a fully integrated sensing platform consisting of a sample inlet with filter, storage units for the Berthelot reagent and standards for self-calibration, pumping system which controls the transport and mixing of the sample, a microfluidic mixing and detection chip, and waste storage. The optical detection system consists of a LED light source with a photodiode detector, which enables sensitive detection of the coloured complex formed. The robustness and low cost of the microfluidic platform coupled with integrated wireless communications makes it an ideal platform for in situ environmental monitoring. This is the first demonstration of a fully functional microfluidic platform employing this modified version of the Berthelot method.

28 February 2007 in Talanta
Verified
Journal Article
Closed access
CMChristina M McGraw
Christina M McGraw
SSShannon E. Stitzel
Shannon E. Stitzel
JCJohn Cleary
John Cleary
CSConor Slater
Conor Slater
Dermot DiamondDermot Diamond
Dermot Diamond