We designed a tunable diode laser absorption spectroscopy (TDLAS) sensor for the online monitoring of CO₂ and H₂O concentrations. It comprised a small self-design multi-pass cell, home-made laser drive circuits, and a data acquisition circuit. The optical and electrical parts and the gas circuit were integrated into a portable carrying case (height = 134 mm, length = 388 mm, and width = 290 mm). A TDLAS drive module (size: 90 mm × 45 mm) was designed to realize the function of laser current and temperature control with a temperature control accuracy of ±1.4 mK and a current control accuracy of ±0.5 μA, and signal acquisition and demodulation. The weight and power consumption of the TDLAS system were only 5 kg and 10 W, respectively. Distributed feedback lasers (2004 nm and 1392 nm) were employed to target CO₂ and H₂O absorption lines, respectively. According to Allan analysis, the detection limits of CO₂ and H₂O were 0.13 ppm and 3.7 ppm at an average time of 18 s and 35 s, respectively. The system response time was approximately 10 s. Sensor performance was verified by measuring atmospheric CO₂ and H₂O concentrations for 240 h. Experimental results were compared with those obtained using a commercial instrument LI-7500, which uses non-dispersive infrared technology. Measurements of the developed gas analyzer were in good agreement with those of the commercial instrument, and its accuracy was comparable. Therefore, the TDLAS sensor has strong application prospects in atmospheric CO₂ and H₂O concentration detection and ecological soil flux monitoring.

In this article, a compact dual-laser sensor based on an off-axis integrated-cavity output spectroscopy and time-division multiplexing method is reported. A complete dual-channel optical structure is developed and integrated on an optical cavity, which allows two distributed feedback (DFB) lasers operating at wavelengths of 1603 nm and 1651 nm to measure the concentration of CO₂ and CH₄, simultaneously. Performances of the dual-laser sensor are experimentally evaluated by using standard air (with a mixture of CO₂ and CH₄). The limit of detection (LoD) is 0.271 ppm and 1.743 ppb at a 20 s for CO₂ and CH₄, respectively, and the noise equivalent absorption sensitivities are 2.68 × 10⁻¹⁰ cm⁻¹ Hz^−1/2 and 3.88 × 10⁻¹⁰ cm⁻¹ Hz^−1/2, respectively. Together with a commercial instrument, the dual-laser sensor is used to measure CO₂ and CH₄ concentration over 120 h and verify the regular operation of the sensor for the detection of ambient air. Furthermore, a first-order exponential moving average algorithm is implemented as an effective digital filtering method to estimate the gas concentration.

Previous research revealed that isotopes ¹³C and ¹⁸O of exhaled CO₂ have the potential link with Helicobacter pylori; however, the ¹⁷O isotope has received very little attention. We developed a sensitive spectroscopic sensor for simultaneous δ¹³C, δ¹⁸O, and δ¹⁷O analysis of human breath CO₂ based on mid-infrared laser direct absorption spectroscopy with an interband cascade laser (ICL) at 4.33 μm. There was a gas cell with a small volume of less than 5 mL, and the pressure in the gas cell was precisely controlled with a standard deviation of 0.0035 Torr. Moreover, real-time breath sampling and batch operation were achieved in gas inlets. The theoretical drifts for δ¹³C, δ¹⁸O, and δ¹⁷O measurement caused by temperature were minimized to 0.017‰, 0.024‰, and 0.021‰, respectively, thanks to the precise temperature control with a standard deviation of 0.0013 °C. After absolute temperature correction, the error between the system responded δ-value and the reference is less than 0.3‰. According to Allan variance analysis, the system precisions for δ¹³C, δ¹⁸O, and δ¹⁷O were 0.12‰, 0.18‰, and 0.47‰, respectively, at 1 s integration time, which were close to the real-time measurement errors of six repeated exhalations.