We designed a tunable diode laser absorption spectroscopy (TDLAS) sensor for the online monitoring of CO₂ and H₂O concentrations. It comprised a small self-design multi-pass cell, home-made laser drive circuits, and a data acquisition circuit. The optical and electrical parts and the gas circuit were integrated into a portable carrying case (height = 134 mm, length = 388 mm, and width = 290 mm). A TDLAS drive module (size: 90 mm × 45 mm) was designed to realize the function of laser current and temperature control with a temperature control accuracy of ±1.4 mK and a current control accuracy of ±0.5 μA, and signal acquisition and demodulation. The weight and power consumption of the TDLAS system were only 5 kg and 10 W, respectively. Distributed feedback lasers (2004 nm and 1392 nm) were employed to target CO₂ and H₂O absorption lines, respectively. According to Allan analysis, the detection limits of CO₂ and H₂O were 0.13 ppm and 3.7 ppm at an average time of 18 s and 35 s, respectively. The system response time was approximately 10 s. Sensor performance was verified by measuring atmospheric CO₂ and H₂O concentrations for 240 h. Experimental results were compared with those obtained using a commercial instrument LI-7500, which uses non-dispersive infrared technology. Measurements of the developed gas analyzer were in good agreement with those of the commercial instrument, and its accuracy was comparable. Therefore, the TDLAS sensor has strong application prospects in atmospheric CO₂ and H₂O concentration detection and ecological soil flux monitoring.

The performance of an interband cascade laser based laser heterodyne radiometer (LHR) is demonstrated in ground-based solar occultation mode. High-resolution (0.0033 cm⁻¹) transmission spectra near 3.53 μm were obtained for simultaneous atmospheric observations of H₂O and CH₄. Combined with the preprocessed measurement data (acquired at Hefei, China, on June 21th 2016), an optimal estimation method based retrieval algorithm is developed for data retrieval and error analysis. By considering the corrected atmospheric parameters, vertical profiles of H₂O and CH₄ are retrieved. Finally, the measured total column abundance and X_CH4 were calculated to be 1.87 ± 0.02 ppm and 1.88 ± 0.02 ppm, respectively. The interband cascade laser-based laser heterodyne radiometer that is demonstrated in this manuscript has high potential for use in the development of compact, robust, and unattended LHR for spacecraft, airborne or ground-based atmospheric sensing.

A sensitive dual-gas sensor for the detection of CH₄ and C₂H₆ is demonstrated. Two tunable semiconductor lasers operating at 1.653 μm (for CH₄ monitoring) and 1.684 μm (for C₂H₆) were used as the light source for spectroscopic measurements of CH₄ and C₂H₆. Long-path absorption in a home-made compact dense-pattern multipass cell (L_eff = 29.37 m) was employed, combined with wavelength modulation and second harmonic detection. Simultaneous detection of CH₄ and C₂H₆ was achieved by separated wavelength modulations of the two lasers. Modulation frequencies and amplitudes were optimized for sensitivity detection of CH₄ and C₂H₆ simultaneously. The dual-gas sensor exhibits 1σ detection limits of 1.5 ppbv for CH₄ in 140 s averaging time and 100 ppbv for C₂H₆ in 200 s.

In this article, a compact dual-laser sensor based on an off-axis integrated-cavity output spectroscopy and time-division multiplexing method is reported. A complete dual-channel optical structure is developed and integrated on an optical cavity, which allows two distributed feedback (DFB) lasers operating at wavelengths of 1603 nm and 1651 nm to measure the concentration of CO₂ and CH₄, simultaneously. Performances of the dual-laser sensor are experimentally evaluated by using standard air (with a mixture of CO₂ and CH₄). The limit of detection (LoD) is 0.271 ppm and 1.743 ppb at a 20 s for CO₂ and CH₄, respectively, and the noise equivalent absorption sensitivities are 2.68 × 10⁻¹⁰ cm⁻¹ Hz^−1/2 and 3.88 × 10⁻¹⁰ cm⁻¹ Hz^−1/2, respectively. Together with a commercial instrument, the dual-laser sensor is used to measure CO₂ and CH₄ concentration over 120 h and verify the regular operation of the sensor for the detection of ambient air. Furthermore, a first-order exponential moving average algorithm is implemented as an effective digital filtering method to estimate the gas concentration.

A fully integrated photoacoustic nitrogen dioxide (NO₂) sensor is developed and demonstrated. In this sensor, an embedded photoacoustic cell was manufactured by using an up-to-date 3D printing technique. A blue laser diode was used as a light source for excitation of photoacoustic wave in the photoacoustic cell. The photoacoustic wave is detected by a sensitive microelectromechanical system (MEMS) microphone. Homemade circuits are integrated into the sensor for laser diode driving and signal processing. The sensor was calibrated by using a chemiluminescence NO–NO₂–NO_X gas analyzer. And the performance of this sensor was evaluated. The linear relationship between photoacoustic signals and NO₂ concentrations was verified in a range of below 202 ppb. The limit of detection was determined to 0.86 ppb with an integration time of 1 s. The corresponding normalized noise equivalent absorption was 2.0 × 10⁻⁸ cm⁻¹∙W∙Hz^−1/2. The stability and the optimal integration time were evaluated with an Allan deviation analysis, from which a detection limit of 0.25 ppb at the optimal integration time of 240 s was obtained. The sensor was used to measure outdoor air and the results agree with that obtained from the NO–NO₂–NO_X gas analyzer. The low-cost and portable photoacoustic NO₂ sensor has a potential application for atmospheric NO₂ monitoring.

The performance of a micro-electro-mechanical system (MEMS) modulator-based dual-channel mid-infrared laser heterodyne radiometer (MIR-LHR) was demonstrated in ground-based solar occultation mode for the first time. A MEMS mirror was employed as an alternative modulator to the traditional mechanical chopper, which makes the system more stable and compact. Two inter-band cascade lasers (ICL) centered at 3.53 µm and 3.93 µm, were employed as local oscillators (LO) to probe absorption lines of methane (CH4), water vapor (H₂O) and nitrous oxide (N₂O). The system stability greater than 1000 s was evaluated by Allan variance. The experimental MIR-LHR spectra (acquired at Hefei, China, on February 24th 2022) of two channels were compared and were in good agreement with simulation spectra from atmospheric transmission modeling. The mixing ratio of CH₄, H₂O and N₂O were determined to be ∼1.906 ppm, 3069 ppm and ∼338 ppb, respectively. The reported MEMS modulator-based dual-channel MIR-LHR in this manuscript has great potential to be a portable and high spectral resolution instrument for remote sensing of multi-component gases in the atmospheric column.