We designed a tunable diode laser absorption spectroscopy (TDLAS) sensor for the online monitoring of CO₂ and H₂O concentrations. It comprised a small self-design multi-pass cell, home-made laser drive circuits, and a data acquisition circuit. The optical and electrical parts and the gas circuit were integrated into a portable carrying case (height = 134 mm, length = 388 mm, and width = 290 mm). A TDLAS drive module (size: 90 mm × 45 mm) was designed to realize the function of laser current and temperature control with a temperature control accuracy of ±1.4 mK and a current control accuracy of ±0.5 μA, and signal acquisition and demodulation. The weight and power consumption of the TDLAS system were only 5 kg and 10 W, respectively. Distributed feedback lasers (2004 nm and 1392 nm) were employed to target CO₂ and H₂O absorption lines, respectively. According to Allan analysis, the detection limits of CO₂ and H₂O were 0.13 ppm and 3.7 ppm at an average time of 18 s and 35 s, respectively. The system response time was approximately 10 s. Sensor performance was verified by measuring atmospheric CO₂ and H₂O concentrations for 240 h. Experimental results were compared with those obtained using a commercial instrument LI-7500, which uses non-dispersive infrared technology. Measurements of the developed gas analyzer were in good agreement with those of the commercial instrument, and its accuracy was comparable. Therefore, the TDLAS sensor has strong application prospects in atmospheric CO₂ and H₂O concentration detection and ecological soil flux monitoring.

We report an open-path and anti-pollution multi-pass cell based tunable diode laser absorption spectroscopy (TDLAS) sensor, which was designed for online measurement of atmospheric H₂O and CO₂ fluxes. It is mainly composed of two plano-convex mirrors coated on a convex surface, which makes it different from traditional multi-pass cells. This design does not allow a direct contact between the coating layer of the lens and air, thereby realizing the anti-pollution effect of the coating layer. Two DFB lasers operating at 1392 nm and 2004 nm were employed to target H₂O and CO₂ absorption lines, respectively. Allan analysis of variance indicated that detection limits of H₂O and CO₂ were 5.98 ppm and 0.68 ppm, respectively, at an average time of 0.1 s. The sensor performance was demonstrated by measuring CO₂ and H₂O flux emissions at Jiangdu Agricultural Monitoring Station in Jiangsu Province. The results were compared with those obtained using the commercial instrument LI-7500, which is based on non-dispersive infrared technology. The developed gas analysis instrument exhibited good consistency with commercial instruments, and its accuracy was comparable; thus, it has strong application prospects for flux measurements in any ecosystem.

The performance of an interband cascade laser based laser heterodyne radiometer (LHR) is demonstrated in ground-based solar occultation mode. High-resolution (0.0033 cm⁻¹) transmission spectra near 3.53 μm were obtained for simultaneous atmospheric observations of H₂O and CH₄. Combined with the preprocessed measurement data (acquired at Hefei, China, on June 21th 2016), an optimal estimation method based retrieval algorithm is developed for data retrieval and error analysis. By considering the corrected atmospheric parameters, vertical profiles of H₂O and CH₄ are retrieved. Finally, the measured total column abundance and X_CH4 were calculated to be 1.87 ± 0.02 ppm and 1.88 ± 0.02 ppm, respectively. The interband cascade laser-based laser heterodyne radiometer that is demonstrated in this manuscript has high potential for use in the development of compact, robust, and unattended LHR for spacecraft, airborne or ground-based atmospheric sensing.

We overview our recent progress in the developments and applications of light emitting diode-based incoherent broadband cavity enhanced absorption spectroscopy (LED-IBBCEAS) techniques for real-time optical sensing chemically reactive atmospheric species (HONO, NO₃, NO₂) in intensive campaigns and in atmospheric simulation chamber. New application of optical monitoring of NO₃ concentration-time profile for study of the NO₃-initiated oxidation process of isoprene in a smog chamber is reported.