The anodization of titanium has been an excellent option for protecting titanium and its alloys from corrosive environments such as acids and chloride systems, by generating a homogenous oxide layer. The objective of the current investigation was to evaluate the electrochemical corrosion behavior of alloys Ti-6Al-2Sn-4Zr-2Mo and Ti-6Al-4V anodized in 1M H₂SO₄ and H₃PO₄ solutions at a current density of 2.5 × 10^–3 A/cm². The anodization’s electrochemical characterization was achieved in NaCl and H₂SO₄ at 3.5% wt. electrolytes. Scanning electron microscopy (SEM) was employed to determine the anodized thickness and morphology. Cyclic potentiodynamic polarization (CPP) and electrochemical impedance spectroscopy (EIS), based on ASTM G61-86 and G106-15 Standards, were the electrochemical techniques mainly employed. The anodized samples presented a change in E_corr values and a higher passivation zone. The EIS plot showed a higher resistance for samples anodized in H₃PO₄ and Ti-6Al-2Sn-4Zr-2Mo.

Ti and Ti alloys are employed in demanding industries such as aerospace, automotive, biomedical, aeronautic, structural, naval, and chemical, thanks to their resistance to corrosion due to the formation of the TiO₂ film on the surface. Diverse research has established that different corrosive media could attack the oxide layer. One way to generate a stable, compact, and continuous oxide film is through anodizing treatment. The efficiency of anodization depends on diverse factors such as the microstructure, chemical composition of alloys, pH of electrolyte, time, and temperature of anodizing. This review aims to examine the corrosion resistance of the anodized layer on Ti and Ti alloys, with different parameters. The discussion is centered on the influence of the different parameters and alloy properties in the effectivity of anodizing when they are characterized by electrochemical techniques while studying the behavior of oxide.

Corrosion deterioration of materials is a major problem affecting economic, safety, and logistical issues, especially in the aeronautical sector. Detecting the correct corrosion type in metal alloys is very important to know how to mitigate the corrosion problem. Electrochemical noise (EN) is a corrosion technique used to characterize the behavior of different alloys and determine the type of corrosion in a system. The objective of this research is to characterize by EN technique different aeronautical alloys (Al, Ti, steels, and superalloys) using different analysis methods such as time domain (visual analysis, statistical), frequency domain (power spectral density (PSD)), and frequency–time domain (wavelet decomposition, Hilbert Huang analysis, and recurrence plots (RP)) related to the corrosion process. Optical microscopy (OM) is used to observe the surface of the tested samples. The alloys were exposed to 3.5 wt.% NaCl and H₂SO₄ solutions at room temperature. The results indicate that HHT and recurrence plots are the best options for determining the corrosion type compared with the other methods due to their ability to analyze dynamic and chaotic systems, such as corrosion. Corrosion processes such as passivation and localized corrosion can be differentiated when analyzed using HHT and RP methods when a passive system presents values of determinism between 0.5 and 0.8. Also, to differentiate the passive system from the localized system, it is necessary to see the recurrence plot due to the similarity of the determinism value. Noise impedance (Z_n) is one of the best options for determining the corrosion kinetics of one system, showing that Ti CP2 and Ti-6Al-4V presented 742,824 and 939,575 Ω·cm², while R_n presented 271,851 and 325,751 Ω·cm², being the highest when exposed to H₂SO₄.

In the present investigation, the physical, mechanical and durability properties of six concrete mixtures were evaluated, one of conventional concrete (CC) with 100% Portland cement (PC) and five mixtures of Ecofriendly Ternary Concrete (ETC) made with partial replacement of Portland Cement by combinations of sugar cane bagasse ash (SCBA) and silica fume (SF) at percentages of 10, 20, 30, 40 and 50%. The physical properties of slump, temperature, and unit weight were determined, as well as compressive strength, rebound number, and electrical resistivity as a durability parameter. All tests were carried out according to the ASTM and ONNCCE standards. The obtained results show that the physical properties of ETC concretes are very similar to those of conventional concrete, complying with the corresponding regulations. Compressive strength results of all ETC mixtures showed favorable performances, increasing with aging, presenting values similar to CC at 90 days and greater values at 180 days in the ETC-20 and ETC-30 mixtures. Electrical resistivity results indicated that the five ETC mixtures performed better than conventional concrete throughout the entire monitoring period, increasing in durability almost proportionally to the percentage of substitution of Portland cement by the SCBA–SF combination; the ETC mixture made with 40% replacement had the highest resistivity value, which represents the longest durability. The present electrical resistivity indicates that the durability of the five ETC concretes was greater than conventional concrete. The results show that it is feasible to use ETC, because it meets the standards of quality, mechanical resistance and durability, and offers a very significant and beneficial contribution to the environment due to the use of agro-industrial and industrial waste as partial substitutes up to 50% of CPC, which contributes to reduction in CO₂ emissions due to the production of Portland cement, responsible for 8% of total emissions worldwide.

This research evaluates the behavior corrosion of galvanized steel (GS) and AISI 1018 carbon steel (CS) embedded in conventional concrete (CC) made with 100% CPC 30R and two binary sustainable concretes (BSC1 and BSC2) made with sugar cane bagasse ash (SCBA) and silica fume (SF), respectively, after 300 days of exposure to 3.5 wt.% MgSO₄ solution as aggressive medium. Electrochemical techniques were applied to monitor corrosion potential (E_corr) according to ASTM C-876-15 and linear polarization resistance (LPR) according to ASTM G59 for determining corrosion current density (i_corr). E_corr and i_corr results indicate after more than 300 days of exposure to the sulfate environment (3.5 wt.% MgSO₄ solution), that the CS specimens embedded in BSC1 and BSC2 presented greater protection against corrosion in 3.5 wt.% MgSO₄ than the specimens embedded in CC. It was also shown that this protection against sulfates is significantly increased when using GS reinforcements. The results indicate a higher resistance to corrosion by exposure to 3.5 wt.% magnesium sulfate two times greater for BSC1 and BSC2 specimens reinforced with GS than the specimens embedding CS. In summary, the combination of binary sustainable concrete with galvanized steel improves durability and lifetime in service, in addition to reducing the environmental impact of the civil engineering structures.

Hard anodizing is used to improve the anodic films’ mechanical qualities and aluminum alloys’ corrosion resistance. Applications for anodic oxide coatings on aluminum alloys include the space environment. In this work, the aluminum alloys 2024-T3 (Al-Cu), 6061-T6 (Al-Mg-Si), and 7075-T6 (Al-Zn) were prepared by hard anodizing electrochemical treatment using citric and sulfur acid baths at different concentrations. The aim of the work is to observe the effect of citric acid on the microstructure of the substrate, the mechanical properties, the corrosion resistance, and the morphology of the hard anodic layers. Hard anodizing was performed on three different aluminum alloys using three citric–sulfuric acid mixtures for 60 min and using current densities of 3.0 and 4.5 A/dm². Vickers microhardness (HV) measurements and scanning electron microscopy (SEM) were utilized to determine the mechanical characteristics and microstructure of the hard anodizing material, and electrochemical techniques to understand the corrosion kinetics. The result indicates that the aluminum alloy 6061-T6 (Al-Mg-Si) has the maximum hard-coat thickness and hardness. The oxidation of Zn and Mg during the anodizing process found in the 7075-T6 (Al-Zn) alloy promotes oxide formation. Because of the high copper concentration, the oxide layer that forms on the 2024-T6 (Al-Cu) Al alloy has the lowest thickness, hardness, and corrosion resistance. Citric and sulfuric acid solutions can be used to provide hard anodizing in a variety of aluminum alloys that have corrosion resistance and mechanical qualities on par with or better than traditional sulfuric acid anodizing.