The hybridization between polymers and carbon materials is one of the most recent and crucial study areas which abstracted more concern from scientists in the past few years. Polymers could be classified into two classes according to the source materials synthetic and natural. Synthetic polymeric materials have been applied over a floppy zone of industrial fields including the field of biomedicine. Carbon nanomaterials including (fullerene, carbon nanotubes, and graphene) classified as one of the most significant sources of hybrid materials. Nanocarbons are improving significantly mechanical properties of polymers in nanocomposites in addition to physical and chemical properties of the new materials. In all varieties of proposed bio-nanocomposites, a considerable improvement in the microbiological performance of the materials has been explored. Various polymeric materials and carbon-course nanofillers were present, along with antibacterial, antifungal, and anticancer products. This review spots the light on the types of synthetic polymers-based carbon materials and presented state-of-art examples on their application in the area of biomedicine.
The usage of dyes has been tremendously augmented due to industrialization and human’s intrinsic fascination with colors. Owing to their excessive usage in industries like textiles, food, cosmetics, paints, printing etc., it is indisputably a contributing factor in aquatic pollution. Dyes effluents have emerged as a burgeoning challenge. Owing to issues such as toxicity, mutagenicity, and disturbed photosynthesis associated with dye contamination, it is crucial to look for an explication to deal with this challenge. Polypyrrole-based biocomposites have been reported as good adsorbents for textile wastewater treatment. In the last decade, numerous studies have stated the effective removal of dyes via Polypyrrole-based biocomposites. This review concentrates on the implication of different Polypyrrole-based biocomposites for decontamination of dyes and synthesis methods, characteristics, and mechanism of dyes degradation by these biocomposites from wastewater.
Hybrid materials are classified as one of the most highly important topics that have been of great interest to many researchers in recent decades. There are many species that can fall under this category, one of the most important of which contain biopolymeric materials as a matrix and are additionally reinforced by different types of carbon sources. Such materials are characterized by many diverse properties in a variety industrial and applied fields but especially in the field of biomedical applications. The biopolymeric materials that fall under this label are divided into natural biopolymers, which include chitosan, cellulose, and gelatin, and industrial or synthetic polymers, which include polycaprolactone, polyurethane, and conducting polymers of variable chemical structures. Furthermore, there are many types of carbon nanomaterials that are used as enhancers in the chemical synthesis of these materials as reinforcement agents, which include carbon nanotubes, graphene, and fullerene. This research investigates natural biopolymers, which can be composed of carbon materials, and the educational and medical applications that have been developed for them in recent years. These applications include tissue engineering, scaffold bones, and drug delivery systems.
24 November 2023 in International Journal of Biological Macromolecules
In this work, removal of chromium (VI) using alkali-treated composted peels of lemon (Citrus limonum), mango (Mangifera indica), water melon (Citrullus lanatus), and melon (Cucumis melo) has been studied in batch mode. Physico-chemical characteristics of each sorbent material were determined together with their subsequent characterization by scanning electron microscopic, FTIR, and TGA. The selected sorbent materials were chemically modified using nitric acid and sodium hydroxide solutions. Adsorption efficacy of the selected sorbent materials for Cr (VI) was investigated by optimizing different parameters. The most favorable conditions were as follows: adsorbent dosage=1.2g/50mL, pH=4.0, agitation speed=170rpm, 60 minutes=contact time, and temperature=313°K. Base-treated adsorbents were found to be better adsorbents as compared to the acid treated form which in turn are better than raw adsorbents (adsorbents without chemical modification). Overall, the chosen sorbents removed Cr (VI) in the range of 53.6296, whereas the maximum sorption is with base-treated water melon peels (BWMP), that is, 95.98. The kinetic studies discovered that the results fitted with pseudo-second-order model. Thermodynamic parameters also support that under optimal conditions, all the selected sorbents specifically base-treated sorbents are good enough for the elimination of Cr (VI) ions in an eco-friendly way.