The Upper Permian marine shale of the inter-platform basin in the Nanpanjiang Basin are rich in organic matter, widely distributed, and relatively thick, indicating abundant resource potential for hydrocarbon exploration. To clarify the sedimentary condition and the variability of reservoir properties, the paleo-environment was reconstructed by using geochemical, mineralogical, rock-property, and pore-structure data. Building on a lithofacies classification, the development patterns of different shale lithofacies were revealed. Reservoir characteristics among lithofacies were compared using scanning electron microscopy (SEM), nuclear magnetic resonance (NMR), and low-temperature Nuclear Magnetic Resonance Cryoporometry (NMRC) experiments. A fractal analysis was performed based on NMR and NMRC data to quantify pore-scale heterogeneity, calculate fractal dimensions (D₁, D₂, and D_c), and evaluate the complexity of pore systems across lithofacies. Correlation analysis and redundancy analysis were applied to further explore the controlling factors of reservoir heterogeneity. The results showed that organic-rich shale in the Permian Linghao Formation occurred mainly in the 1st Member, with average total organic carbon (TOC) content of 2.57%, and the lower part of the 3rd Member (average TOC content 2.88%). In the 1st Member, high-carbon shale was deposited under humid conditions with intense weathering, abundant fine-grained clastic input from basin margins, strongly reducing (anoxic) bottom waters, vigorous phosphorus recycling, and moderate to low primary productivity. Using TOC and mineral composition, seven shale lithofacies were identified in the Linghao Formation, and their development patterns were established based on depositional paleo-environment characteristics and evolution. In the 1st Member, organic-rich shale was dominated by mixed lithofacies with moderate to high TOC. The paleo-environment exerted a primary control on reservoir properties, gas content, pore structure, and heterogeneity. The high-carbon lithofacies had the most favorable rock properties—higher porosity, greater pore volume, and higher gas content—and contained a larger proportion of well-developed organic pores. Fractal analysis revealed that seepage pores exhibited greater structural complexity than adsorption-related pores, with the high-carbon lithofacies showing the highest overall fractal dimensions and thus the strongest heterogeneity. Across the formation, higher clay content and TOC were the primary drivers of increased pore-scale heterogeneity, whereas greater feldspar and quartz contents tended to diminish it. Carbonates exerted a minor effect. Heterogeneity in adsorption pores exerted the strongest influence on differences among lithofacies. These results highlighted the utility of fractal analysis in quantitatively linking shale mineralogy and organic content to multiscale heterogeneity in inter-platform basin settings.

Shale gas is one of the hot spots of energy development. Due to the strong heterogeneity and low physical properties of shale gas reservoirs, and the complex influencing factors of pore development, it is necessary to conduct a comprehensive analysis of the control factors of high-quality reservoirs. The sedimentary characteristics, mineral composition, pore structure and controlling factors of high quality reservoir development are studied on the basis of thin section, scanning electron microscopy (SEM) and QEMSCAN analysis, X-ray diffraction (XRD), total organic carbon (TOC), Nano-CT scanning and Low-pressure N₂ adsorption (N₂GA) analysis on shale samples from the Longmaxi Formation in South Sichuan Basin. The results show the following: (1) According to lithology, sedimentary structure, organic carbon content and mineral composition, six sedimentary microfacies can be divided. (2) Organic matter pores are developed in organic-rich siliceous shale and organic-rich silty shale at the bottom of the first member of the Longmaxi formation, with average porosity of more than 5% and permeability of more than 2 × 10⁻³ μm², which is conducive to the formation of high-quality shale gas reservoirs. (3) The contents of siliceous and TOC are positively correlated with porosity and specific surface area, while the contents of carbonate and clay minerals are negatively correlated with reservoir quality. (4) In the first member of the Longmaxi formation, the sedimentary water depth becomes shallower from bottom to top, and the sedimentary environment changes from a reduction to an oxidation environment. The contents of siliceous and organic matter decrease, while the contents of clay minerals and carbonate minerals show the opposite trend. The difference in sedimentary microfacies affects the distribution of mineral and organic matter and controls the heterogeneity of the shale reservoir.

The Benxi-Taiyuan Formation in the southern region of the Ordos Basin represents a typical mixed sedimentary system, which has witnessed recent breakthroughs in the exploration of tight sandstone gas within the Benxi Formation. However, the development patterns of reservoirs in this mixed sedimentary area remain unclear, influenced by the sedimentary model and the distribution scale of sedimentary sandstone bodies. This study investigates the paleogeomorphology, sedimentary model, sandstone body type, petrological characteristics, and pore structure of the Benxi Formation. Field profiles, drilling core observations, microscopic section analysis, scanning electron microscopy (SEM), high-pressure mercury injection (HPMI), and physical property analysis are employed. The findings indicate that the paleogeomorphology before the deposition of the Benxi Formation exhibits a west-to-east high-to-low trend, with a steeper gradient in the north and a gentler gradient in the south. This paleogeomorphology influences paleocurrent direction and the distribution of sandstone bodies. The sedimentary system, consisting of clastic tidal flats, mixed tidal flats, and mixed lagoons, develops from west to east on a plane, with the mixed lagoon being more prominent in the northeast of the study area. The sedimentary model determines the initial composition and structure of the reservoir, as well as subsequent diagenesis processes. Diagenetic reconstruction plays a crucial role in assessing the development degree of reservoir. Compaction and cementation result in the densification of the Benxi Formation sandstone. Dissolution and preservation of primary pores are critical for high-quality reservoir development. Among the various depositional models, the sand flat facies in the clastic tidal flat area of the Ben 2 Member and the tidal channel facies in the mixed tidal flat areas of the Ben 1 and Ben 2 members exhibit a high degree of pore development within the sandstone body, making them favorable locations for high-quality reservoir development. In summary, this study highlights the importance of paleogeomorphology, sedimentary models, and diagenetic reconstruction in understanding the controlling factors for efficient reservoir development in the mixed sedimentary system of the Benxi-Taiyuan Formation. Knowledge of these factors aids in the exploration of high-quality reservoirs within concealed and dispersed sandstone formations in the Ordos Basin.

Geological Carbon Sequestration (GCS) plays a crucial role in addressing climate change, particularly in oil and gas development. Understanding the reaction of supercritical CO₂ under in situ conditions and its effects on minerals is essential for advancing GCS technology. This study investigates the reaction mechanisms of feldspar (potassium and sodium feldspar) and clay minerals (chlorite, illite, montmorillonite, kaolinite) in CO₂ environments. The impacts on mineral crystal structures, morphologies, and elemental compositions were analyzed using X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive spectroscopy (EDS), and ion concentration measurements (ICP-OES and ICP-MS). The results show that feldspar minerals exhibit lower reaction rates, with sodium feldspar dissolving faster than potassium feldspar, due to the higher solubility of sodium ions in acidic conditions. Chlorite showed significant crystal structure damage after 30 days, while montmorillonite underwent both dissolution and precipitation, influenced by interlayer cation dissociation. Kaolinite exhibited minimal reaction, primarily showing localized dissolution. Additionally, the formation of siderite (FeCO₃) was observed as Fe²⁺ substituted for Ca²⁺ in CaCO₃, highlighting the role of iron-bearing carbonates in CO₂ interactions. The study provides insights into the factors influencing mineral reactivity, including mineral structure, ion exchange capacity, and solubility, and suggests that chlorite, montmorillonite, and illite are more reactive under reservoir conditions, while kaolinite shows higher resistance to CO₂-induced reactions. These findings offer valuable data for optimizing GCS technologies and predicting long-term sequestration outcomes.

The deep marine shale of the Wufeng–Longmaxi (WF–LMX) Formation in the Sichuan Basin is characterized by laterally continuous thickness, high porosity, and significant gas content, making it a representative shale reservoir with considerable resource potential. This study investigates the heterogeneity of pore structures and their controlling factors using shale samples from three representative wells, based on low-temperature nitrogen adsorption and mercury intrusion data. The reservoir can be classified into three main lithofacies: mixed siliceous shale (MSS), clay-rich siliceous shale (CSS), and siliceous clay mixed shale (SMS). The results show that siliceous shales (MSS and CSS) exhibit higher total organic carbon and quartz contents, with more developed pore systems. Among them, the CSS exhibits the highest specific surface area and the largest mesopore and macropore volumes, indicating a greater development of larger pores and superior reservoir quality. All three shale facies exhibit clear single and multifractal characteristics. The average D₁ and D₂ values (fractal dimensions from nitrogen adsorption at P/P₀ < 0.45 and >0.45, respectively) are higher than D_Hg, (fractal dimension from mercury intrusion), indicating greater pore-surface roughness than internal pore structure complexity and stronger heterogeneity in larger pores. The D(q)–q spectrum shows a left-wide/right-narrow pattern, whereas the α–f(α) spectrum exhibits the opposite trend. The branch-width ratios S_kd and S_ka (indices of pore-size distribution complexity and heterogeneity) are both <0.1, suggesting that heterogeneity is more pronounced in low-probability regions. Fractal and multifractal analyses reveal significant pore structure heterogeneity across different lithofacies, with CSS showing relatively more homogeneous pore structures, whereas MSS exhibits stronger heterogeneity and poorer connectivity. The heterogeneity of shale reservoirs is primarily controlled by pore development, especially micropores and mesopores, and is strongly influenced by total organic carbon and quartz content.

Tight sandstone reservoir effectiveness is governed not by pore volume alone, but by the storage and flow contributions of different pore-throat scales, their structural complexity, and their three-dimensional connectivity. This study investigates tight sandstones of the Benxi Formation deposited in a marine–continental transitional mixed siliciclastic–carbonate setting in the Gaoqiao area, southern Ordos Basin. Petrophysical measurements, red-epoxy-impregnated thin-section petrography, mercury intrusion capillary pressure (MICP), segment-specific fractal analysis of functionally defined pore-throat regimes, X-ray micro-computed tomography (micro-CT), and pore-network modeling (PNM) were integrated. The MICP responses define three pore-throat structure types and two data-derived functional boundaries at 0.708 and 0.141 μm, which separate large-pore-throat-dominated, transitional pore-throat, and fine-throat-limited intervals. Using these nominal boundaries, Type I is strongly dominated by the large-pore-throat interval, which accounts for 88.7% of total mercury intrusion, whereas Type II exhibits a mixed large-to-transitional response, and Type III is characterized by negligible large-pore-throat intrusion and pronounced fine-throat restriction. Perturbing both functional boundaries by ±5% and ±10% does not alter these principal functional distinctions, although samples close to the second boundary exhibit the expected local transitional sensitivity. Among the three segment-specific fractal parameters, the fine-throat fractal dimension, D_B, shows the strongest association with median capillary pressure (r = 0.834, p < 0.001) and remains significantly related to displacement pressure, median pore-throat radius, and permeability, whereas D_T shows no significant linear correlation with the tested petrophysical and MICP parameters. The fractions of the largest connected pore cluster in representative Type I–III samples are 90.26%, 72.56%, and 64.65%, while their PNM permeabilities decrease successively from 64.32 mD to 0.850 and 0.121 mD. Together, these results indicate that, for the investigated samples, reservoir effectiveness reflects the combined influence of pore-throat size configuration, segment-specific structural complexity, and three-dimensional network connectivity.