The Upper Permian marine shale of the inter-platform basin in the Nanpanjiang Basin are rich in organic matter, widely distributed, and relatively thick, indicating abundant resource potential for hydrocarbon exploration. To clarify the sedimentary condition and the variability of reservoir properties, the paleo-environment was reconstructed by using geochemical, mineralogical, rock-property, and pore-structure data. Building on a lithofacies classification, the development patterns of different shale lithofacies were revealed. Reservoir characteristics among lithofacies were compared using scanning electron microscopy (SEM), nuclear magnetic resonance (NMR), and low-temperature Nuclear Magnetic Resonance Cryoporometry (NMRC) experiments. A fractal analysis was performed based on NMR and NMRC data to quantify pore-scale heterogeneity, calculate fractal dimensions (D₁, D₂, and D_c), and evaluate the complexity of pore systems across lithofacies. Correlation analysis and redundancy analysis were applied to further explore the controlling factors of reservoir heterogeneity. The results showed that organic-rich shale in the Permian Linghao Formation occurred mainly in the 1st Member, with average total organic carbon (TOC) content of 2.57%, and the lower part of the 3rd Member (average TOC content 2.88%). In the 1st Member, high-carbon shale was deposited under humid conditions with intense weathering, abundant fine-grained clastic input from basin margins, strongly reducing (anoxic) bottom waters, vigorous phosphorus recycling, and moderate to low primary productivity. Using TOC and mineral composition, seven shale lithofacies were identified in the Linghao Formation, and their development patterns were established based on depositional paleo-environment characteristics and evolution. In the 1st Member, organic-rich shale was dominated by mixed lithofacies with moderate to high TOC. The paleo-environment exerted a primary control on reservoir properties, gas content, pore structure, and heterogeneity. The high-carbon lithofacies had the most favorable rock properties—higher porosity, greater pore volume, and higher gas content—and contained a larger proportion of well-developed organic pores. Fractal analysis revealed that seepage pores exhibited greater structural complexity than adsorption-related pores, with the high-carbon lithofacies showing the highest overall fractal dimensions and thus the strongest heterogeneity. Across the formation, higher clay content and TOC were the primary drivers of increased pore-scale heterogeneity, whereas greater feldspar and quartz contents tended to diminish it. Carbonates exerted a minor effect. Heterogeneity in adsorption pores exerted the strongest influence on differences among lithofacies. These results highlighted the utility of fractal analysis in quantitatively linking shale mineralogy and organic content to multiscale heterogeneity in inter-platform basin settings.

Geological Carbon Sequestration (GCS) plays a crucial role in addressing climate change, particularly in oil and gas development. Understanding the reaction of supercritical CO₂ under in situ conditions and its effects on minerals is essential for advancing GCS technology. This study investigates the reaction mechanisms of feldspar (potassium and sodium feldspar) and clay minerals (chlorite, illite, montmorillonite, kaolinite) in CO₂ environments. The impacts on mineral crystal structures, morphologies, and elemental compositions were analyzed using X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive spectroscopy (EDS), and ion concentration measurements (ICP-OES and ICP-MS). The results show that feldspar minerals exhibit lower reaction rates, with sodium feldspar dissolving faster than potassium feldspar, due to the higher solubility of sodium ions in acidic conditions. Chlorite showed significant crystal structure damage after 30 days, while montmorillonite underwent both dissolution and precipitation, influenced by interlayer cation dissociation. Kaolinite exhibited minimal reaction, primarily showing localized dissolution. Additionally, the formation of siderite (FeCO₃) was observed as Fe²⁺ substituted for Ca²⁺ in CaCO₃, highlighting the role of iron-bearing carbonates in CO₂ interactions. The study provides insights into the factors influencing mineral reactivity, including mineral structure, ion exchange capacity, and solubility, and suggests that chlorite, montmorillonite, and illite are more reactive under reservoir conditions, while kaolinite shows higher resistance to CO₂-induced reactions. These findings offer valuable data for optimizing GCS technologies and predicting long-term sequestration outcomes.

The deep marine shale of the Wufeng–Longmaxi (WF–LMX) Formation in the Sichuan Basin is characterized by laterally continuous thickness, high porosity, and significant gas content, making it a representative shale reservoir with considerable resource potential. This study investigates the heterogeneity of pore structures and their controlling factors using shale samples from three representative wells, based on low-temperature nitrogen adsorption and mercury intrusion data. The reservoir can be classified into three main lithofacies: mixed siliceous shale (MSS), clay-rich siliceous shale (CSS), and siliceous clay mixed shale (SMS). The results show that siliceous shales (MSS and CSS) exhibit higher total organic carbon and quartz contents, with more developed pore systems. Among them, the CSS exhibits the highest specific surface area and the largest mesopore and macropore volumes, indicating a greater development of larger pores and superior reservoir quality. All three shale facies exhibit clear single and multifractal characteristics. The average D₁ and D₂ values (fractal dimensions from nitrogen adsorption at P/P₀ < 0.45 and >0.45, respectively) are higher than D_Hg, (fractal dimension from mercury intrusion), indicating greater pore-surface roughness than internal pore structure complexity and stronger heterogeneity in larger pores. The D(q)–q spectrum shows a left-wide/right-narrow pattern, whereas the α–f(α) spectrum exhibits the opposite trend. The branch-width ratios S_kd and S_ka (indices of pore-size distribution complexity and heterogeneity) are both <0.1, suggesting that heterogeneity is more pronounced in low-probability regions. Fractal and multifractal analyses reveal significant pore structure heterogeneity across different lithofacies, with CSS showing relatively more homogeneous pore structures, whereas MSS exhibits stronger heterogeneity and poorer connectivity. The heterogeneity of shale reservoirs is primarily controlled by pore development, especially micropores and mesopores, and is strongly influenced by total organic carbon and quartz content.

Tight sandstone reservoir effectiveness is governed not by pore volume alone, but by the storage and flow contributions of different pore-throat scales, their structural complexity, and their three-dimensional connectivity. This study investigates tight sandstones of the Benxi Formation deposited in a marine–continental transitional mixed siliciclastic–carbonate setting in the Gaoqiao area, southern Ordos Basin. Petrophysical measurements, red-epoxy-impregnated thin-section petrography, mercury intrusion capillary pressure (MICP), segment-specific fractal analysis of functionally defined pore-throat regimes, X-ray micro-computed tomography (micro-CT), and pore-network modeling (PNM) were integrated. The MICP responses define three pore-throat structure types and two data-derived functional boundaries at 0.708 and 0.141 μm, which separate large-pore-throat-dominated, transitional pore-throat, and fine-throat-limited intervals. Using these nominal boundaries, Type I is strongly dominated by the large-pore-throat interval, which accounts for 88.7% of total mercury intrusion, whereas Type II exhibits a mixed large-to-transitional response, and Type III is characterized by negligible large-pore-throat intrusion and pronounced fine-throat restriction. Perturbing both functional boundaries by ±5% and ±10% does not alter these principal functional distinctions, although samples close to the second boundary exhibit the expected local transitional sensitivity. Among the three segment-specific fractal parameters, the fine-throat fractal dimension, D_B, shows the strongest association with median capillary pressure (r = 0.834, p < 0.001) and remains significantly related to displacement pressure, median pore-throat radius, and permeability, whereas D_T shows no significant linear correlation with the tested petrophysical and MICP parameters. The fractions of the largest connected pore cluster in representative Type I–III samples are 90.26%, 72.56%, and 64.65%, while their PNM permeabilities decrease successively from 64.32 mD to 0.850 and 0.121 mD. Together, these results indicate that, for the investigated samples, reservoir effectiveness reflects the combined influence of pore-throat size configuration, segment-specific structural complexity, and three-dimensional network connectivity.