Recently reported with nontrivial topological properties and magnetic orders, is an intrinsic, magnetic topological insulator which holds promise for exploring exotic quantum phenomena such as the quantum anomalous Hall effect. However, the layer-dependent magnetism of , which is fundamental and crucial for further exploration of related quantum phenomena in this system, remains elusive. Here, by using polar reflective magnetic circular dichroism spectroscopy, we show that few-layered exhibits an evident odd-even layer-number effect, i.e., the oscillations of the coercivity of the hysteresis loop (at ) and the spin-flop transition (at ), concerning the Zeeman energy and magnetic anisotropy energy. Noticeably, an anomalous magnetic hysteresis loop is observed in the even-number septuple-layered , which might be attributed to the thickness-independent surface-related magnetization. A linear-chain model is applied to elucidate this odd-even layer-number effect of the spin-flop field and to determine the evolution of the magnetic states when subjected to an external magnetic field. A mean-field method further allows us to fully map the flake’s magnetic phase diagrams in the parameter space of the magnetic field, layer number, and, especially, temperature. By harnessing the unusual layer-dependent magnetic properties, our work paves the way for further study of quantum phenomena of .
The recently discovered layered kagome metals (, Rb, and Cs) with vanadium kagome networks provide a novel platform to explore correlated quantum states intertwined with topological band structures. Here we report the prominent effect of hole doping on both superconductivity and charge density wave (CDW) order, achieved by selective oxidation of exfoliated thin flakes. A superconducting dome is revealed as a function of the effective doping content. The superconducting transition temperature () and upper critical field in thin flakes are significantly enhanced compared with the bulk, which are accompanied by the suppression of CDW. Our detailed analyses establish the pivotal role of van Hove singularities in promoting correlated quantum orders in these kagome metals. Our experiments not only demonstrate the intriguing nature of superconducting and CDW orders, but also provide a novel route to tune the carrier concentration through both selective oxidation and electric gating. This establishes as a tunable 2D platform for the further exploration of topology and correlation among electrons in kagome lattices.
The combination of zero dimensional (0D) colloidal CdSe/ZnS quantum dots with Tin Disulfide (SnS2), a two-dimensional (2D) layered metal dichalcogenide, results in 0D-2D hybrids with enhanced light absorption properties. These 0D-2D hybrids, when exposed to light, exhibit intra-hybrid nonradiative energy transfer from photoexcited CdSe/ZnS quantum dots to SnS2. Using single nanocrystal spectroscopy, we find that the rate for energy transfer in 0D-2D hybrids increases with added number of SnS2 layers, a positive manifestation towards the potential functionality of such 2D-based hybrids in applications such as photovoltaics and photon sensing.