In this work, a straightforward method for synthesizing fullerene derivatives with tentacle structures has been explored for monitoring environmental humidity, which involves introducing sulfonate onto the fullerenes. The structure and number of polar groups in three fullerene derivatives determined by a series of structural tests greatly affect their hydrophilicity and morphology, resulting in changes in humidity sensitive properties. In particular, the hysteresis and response time of the sensors display a great correlation with hydrophilicity. C₆₀-Ho, the best performing derivative of this work, has exhibited high response values (∼3500 times), good linearity (R² = 97.3 %), and rapid response/recovery times (0.3/4.4 s), making it suitable for various applications such as non-contact detection of respiration, finger distance, and soil humidity.

The pandemic of respiratory diseases enlightened people that monitoring respiration has promising prospects in averting many fatalities by tracking the development of diseases. However, the response speed of current optical fiber sensors is still insufficient to meet the requirements of high-frequency respiratory detection during respiratory failure. Here, a scheme for a fast and stable tachypnea monitor is proposed utilizing a water-soluble C₆₀-Lys ion compound as functional material for the tracking of humidity change in the progression of breath. The polarization of C₆₀-Lys can be tuned by the ambient relative humidity change, and an apparent refractive index alteration can be detected due to the small size effect. In our experiments, C₆₀-Lys is conformally and uniformly deposited on the surface of a tilted fiber Bragg grating (TFBG) to fabricate an ultra-fast-response, high-sensitivity, and long-term stable optical fiber humidity sensor. A relative humidity (RH) detecting sensitivity of 0.080 dB/% RH and the equilibrium response time and recovery time of 1.85 s and 1.58 s are observed, respectively. Also, a linear relation is detected between the resonance intensity of the TFBG and the environment RH. In a practical breath monitoring experiment, the instantaneous response time and recovery time are measured as 40 ms and 41 ms, respectively, during a 1.5 Hz fast breath process. Furthermore, an excellent time stability and high repeatability are exhibited in experiments conducted over a range of 7 days.

Functionalization of endohedral metallofullerenes (EMFs) plays an important role in exploring the reactivity of EMFs and stabilizing missing EMFs, thus conferring tunable properties and turning EMFs into applicable materials. In this review, we present exhaustive progress on the functionalization of EMFs since 2019. Classic functionalization reactions include Prato reactions, Bingel–Hirsch reactions, radical addition reactions, carbene addition reactions, and so on are summarized. And new complicated multi-component reactions and other creative reactions are presented as well. We also discuss the structural features of derivatives of EMFs and the corresponding reaction mechanisms to understand the reactivity and regioselectivity of EMFs. In the end, we make conclusions and put forward an outlook on the prospect of the functionalization of EMFs.