Mykola Melnychuk

Dr. Mykola Melnychuk

orcid

Research Focus & Metrics

Academic Career Length

9Years (2018-Present)

(Calculated once Scilit publication data is synced: current year − year of first publication + 1)

Representative Publications

View All Publications
16 December 2024 in Materials
Verified
Journal Article
Open access
PDF file
PBPatrycja Bazan
Patrycja Bazan
BFBeata Figiela
Beata Figiela
BKBarbara Kozub
Barbara Kozub
Michał ŁachMichał Łach
Michał Łach
KMKatarzyna Mróz
Katarzyna Mróz
Kinga KorniejenkoKinga Korniejenko
Kinga Korniejenko
Geopolymer materials are increasingly being considered as an alternative to environmentally damaging concrete based on Portland cement. The presented work analyzed waste from mines and waste incineration plants as potential precursors for producing geopolymer materials that could be used to make lightweight foamed geopolymers for insulation applications. The chemical and phase composition, radioactivity properties, and leachability of selected precursors were analyzed. Then, geopolymer materials were produced, and their strength properties were examined through compression and flexural tests. The results of the strength tests guided the material selection for foamed geopolymer materials. Next, geopolymer foams were foamed with hydrogen peroxide and aluminum powder. The produced foamed materials were subjected to strength and thermal conductivity tests. The results demonstrated the great potential of mine waste in the synthesis of geopolymers and the production of lightweight geopolymer foams with good insulating properties.

16 May 2024 in Materials
Verified
Journal Article
Open access
PDF file
MAREK NYKIELMAREK NYKIEL
MAREK NYKIEL
Kinga KorniejenkoKinga Korniejenko
Kinga Korniejenko
KSKinga Setlak
Kinga Setlak
MMMykola Melnychuk
Mykola Melnychuk
Nina PolivodaNina Polivoda
Nina Polivoda
Michał ŁachMichał Łach
Michał Łach
Geopolymer materials, considered to be an alternative to Portland cement-based concretes, can be produced from various types of waste aluminosilicate raw materials. This article presents the results of research related to the use of diatomite as an additive in geopolymers. The results of testing geopolymer composites with 1%, 3%, and 5% additions of diatomite with a grain size of 0–0.063 mm after and without thermal treatment were presented. This article presents the physical properties of the diatomite additive, the morphology of diatomite particles SEMs, thermal analysis, and compressive strength test results. In this research, diatomite was treated as a substitute for both fly ash and metakaolin (replaced in amounts of 1 and 3%) and as a substitute for sand introduced as a filler (in this case, 5% of diatomite was added). As a result of this research, it was found that the addition of diatomite instead of the main geopolymerization precursors in amounts of 1 and 3% had a negative impact on the strength properties of geopolymers, as the compressive strength was reduced by up to 28%. The introduction of crushed diatomite instead of sand in an amount of 5% contributed to an increase in strength of up to 24%.

14 May 2024 in Materials
Verified
Journal Article
Open access
PDF file
Michał ŁachMichał Łach
Michał Łach
BKBarbara Kozub
Barbara Kozub
SBSebastian Bednarz
Sebastian Bednarz
APAgnieszka Przybek
Agnieszka Przybek
MMMykola Melnychuk
Mykola Melnychuk
Adam MasłońAdam Masłoń
Adam Masłoń
Geopolymers are binder materials that are produced by a chemical reaction between silica or aluminum compounds with an alkaline activating solution. Foamed geopolymer materials are increasingly being cited as a viable alternative to popular organic insulation materials. Since the foaming process of geopolymers is difficult to control, and any achievements in improving the performance of such materials are extremely beneficial, this paper presents the effect of the addition of basalt powder on the properties of foamed geopolymers. This paper presents the results of physicochemical studies of fly ash and basalt, as well as mechanical properties, thermal properties, and structure analysis of the finished foams. The scope of the tests included density tests, compressive strength tests, tests of the thermal conductivity coefficient using a plating apparatus, as well as microstructure tests through observations using light and scanning microscopy. Ground basalt was introduced in amounts ranging from 0 to 20% by mass. It was observed that the addition of basalt powder contributes to a reduction in and spheroidization of pores, which directly affect the density and pore morphology of the materials tested. The highest density of 357.3 kg/m3 was characterized by samples with a 5 wt.% basalt powder addition. Their density was 14% higher than the reference sample without basalt powder addition. Samples with 20 wt.% basalt addition had the lowest density, and the density averaged 307.4 kg/m3. Additionally, for the sample containing 5 wt.% basalt powder, the compressive strength exceeded 1.4 MPa, and the thermal conductivity coefficient was 0.1108 W/m × K. The effect of basalt powder in geopolymer foams can vary depending on many factors, such as its chemical composition, grain size, content, and physical properties. The addition of basalt above 10% causes a decrease in the significant properties of the geopolymer.

10 December 2024 in Materials
Verified
Journal Article
Open access
PDF file
PBPatrycja Bazan
Patrycja Bazan
ARArif Rochman
Arif Rochman
KMKrzysztof Mroczka
Krzysztof Mroczka
KBKamil Badura
Kamil Badura
MMMykola Melnychuk
Mykola Melnychuk
AWAleksandra Węglowska
Aleksandra Węglowska
This study investigates the physical and mechanical properties of biodegradable composites based on PLA/PHBV blends modified with different content of nanocrystalline cellulose (NCC) of 5, 10, and 15 wt.%. Density measurements reveal that the density of the composite increases with increasing NCC content. Water absorption tests demonstrate a gradual increase in the composite water content with increasing incubation time, reaching stabilization after approximately 30 days. Mechanical testing was also carried out on both on conditioned samples after the process of hydrolytic degradation and accelerated thermal aging. The conditioned composites show an increase in the stiffness of the materials with increasing content of nanocrystalline cellulose. The ability to deform and the ability to absorb energy when the sample is dynamically loaded decrease. The repeated strength tests, after the process of incubation of samples in water and after the process of accelerated thermal aging, show the degradation of composite materials; however, it is noticed that the introduction of cellulose addition reduces the impact of the applied artificial environment in aging tests. The findings of this study indicate promising applications for these types of materials, characterized by high strength and biodegradability under appropriate conditions. Household items such as various containers or reusable packaging represent potential applications of these composites.

29 November 2023 in Materials
Verified
Journal Article
Open access
PDF file
Gabriel FurtosGabriel Furtos
Gabriel Furtos
Doina ProdanDoina Prodan
Doina Prodan
CODRUTA SAROSICODRUTA SAROSI
CODRUTA SAROSI
MMMarioara Moldovan
Marioara Moldovan
Michał ŁachMichał Łach
Michał Łach
Kinga KorniejenkoKinga Korniejenko
Kinga Korniejenko
In most studies about geopolymeric materials used in construction, the antibacterial properties of the building materials are treated as secondary features. Today, antimicrobial properties are a key feature in many building applications. The main objective of this article is to summarize the state-of-the-art in the area of design, development, and applications of nanoparticles as additives to geopolymer composites used in construction to improve their physical mechanical properties and induce a potential antibacterial effect, protecting them against alkali-resistant bacteria. On the basis of the literature and authors’ experience, the most important methods of obtaining especially the porous geopolymers, of nanomaterials used as additives, with potential antibacterial effect but also the potential mechanism of action against bacterial development were presented. The main findings show that using graphene oxide (GO) in geopolymer composites, but also other nanoparticles such as silver (Ag), zinc oxide (ZnO), silica (SiO2), titanium dioxide (TiO2), copper (Cu) as additives, is an effective way to induce a potential antibacterial effect and to improve the physical and mechanical properties in building materials.

27 November 2024 in Materials
Verified
Journal Article
Open access
BKBarbara Kozub
Barbara Kozub
JDJan Dudek
Jan Dudek
MMMykola Melnychuk
Mykola Melnychuk
Geopolymers are a modern class of construction materials that show significant potential for sustainable development, especially through the use of industrial wastes such as fly ash. This study investigated the effect of different oil additives on the properties of fly ash-based geopolymers, with particular emphasis on the use of both new and used oils. Test samples were prepared using class F fly ash and a 10-molar solution of sodium hydroxide and an aqueous solution of sodium silicate. Oil additives were added at 5%, 10% and 15% by weight. The physical and mechanical properties of the samples were assessed by measuring density, thermal conductivity, compressive and flexural strength, and by analyzing porosity and microstructure. The results showed that oil additives significantly affected the pore structure and mechanical properties of the geopolymers. Furthermore, the type and condition of the used oil determined the mechanical properties, including compressive and flexural strength. Research indicates the possibility of using oils as additives to geopolymers, which helps improve their physical properties and promotes sustainable development through recycling oil waste.