Compared to steam reforming techniques, partial oxidation of methane (POM) is a promising technology to improve the efficiency of synthesizing syngas, which is a mixture of CO and H₂. In this study, partial oxidation of methane (POM) was used to create syngas, a combination of CO and H₂, using the SAPO-5-supported Ni catalysts. Using the wetness impregnation process, laboratory-synthesized Ni promoted with Sr, Ce, and Cu was used to modify the SAPO-5 support. The characterization results demonstrated that Ni is appropriate for the POM due to its crystalline structure, improved metal support contact, and increased thermal stability with Sr, Ce, and Cu promoters. During POM at 600 °C, the synthesized 5Ni+1Sr/SAPO-5 catalyst sustained stability for 240 min on stream. While keeping the reactants stoichiometric ratio of (CH₄:O₂ = 2:1), the addition of Sr promoter and active metal Ni to the SAPO-5 increased the CH₄ conversion from 41.13% to 49.11% and improved the H₂/CO ratio of 3.33. SAPO-5-supported 5Ni+1Sr catalysts have great potential for industrial catalysis owing to their unique combination of several oxides. This composition not only boosts the catalyst’s activity but also promotes favorable physiochemical properties, resulting in improved production of syngas. Syngas is a valuable intermediate in various industrial processes.

The greenhouse gas CH₄ is more potent than CO_2, although both these gases are solely responsible for global warming. The efficient catalytic conversion of CH₄ into hydrogen-rich syngas, which also demonstrates economic viability, can deplete the concentration of CH₄. This study examines the partial oxidation of methane (POM) prepared by the wetness impregnation process using 5% Ni supported over DSZ95 (93.3% ZrO₂ + 6.7% Sc₂O₃) and promoted with 1% Ga (gallium), 1% Sr (strontium), and 1% Ce (cerium). These catalysts are characterized by surface area porosity, X-ray diffraction, FT-Infrared spectroscopy, Raman infrared spectroscopy, temperature programmed reduction, CO₂ temperature-programmed techniques, desorption techniques, thermogravimetry, and transmission electron microscopy. The characterization results demonstrate that Ni is appropriate for the POM because of its crystalline structure, improved metal support contact, and increased thermal stability with Sr, Ce, and Ga promoters. The synthesized catalyst 5Ni+1Ga-DSZ95 maintained stability for 240 min on stream during the POM at 700 °C. Adding a 1% Ga promoter and active metal Ni to the DSZ95 improved the CH₄ conversion from 70.00% to 75.90% and raised the H₂ yield from 69.21% to 74.80%, while maintaining the reactants’ stoichiometric ratio of (CH₄:O₂ = 2:1). The 5Ni+1Ga-DSZ95 catalyst is superior to the other catalysts, given its rich catalyst surface, strong metal support interaction, high surface area and low amount of carbon deposit. The high H₂/CO ratio (>2.6) and H₂ yield close to 75% indicate that 5Ni+1Ga-DSZ95 is a potent industrial catalyst for hydrogen-rich syngas production through partial oxidation of methane.