Current petrochemical-based adhesives adversely affect the environment through substantial volatile organic compound (VOC) emissions during production, contributing to air pollution and climate change. In contrast, vegetable oils extracted from bio-resources provide a compelling alternative owing to their renewability, abundance, and compatibility with adhesive formulation chemistry. This review aimed to critically examine and synthesize the existing scholarly literature on environmentally friendly, sustainable, and high-performance polyurethane adhesives (PUAs) developed from vegetable oils. The use of PUAs derived from vegetable oils promises to provide a long-term replacement while simultaneously maintaining or improving adhesive properties. This quality renders these adhesives appropriate for widespread use in various sectors, including construction, automotive manufacturing, packaging, textile, and footwear industries. This review intended to perform a comprehensive assessment and integration of the existing research, thereby identifying the raw materials, strengths, weaknesses, and gaps in knowledge concerning vegetable oil-based PUAs. In doing so, it responded to these gaps and proposes potential avenues for future research. Therefore, this review accomplishes more than merely evaluating the existing research; it fosters the advancement of greener PUA technologies by identifying areas for improvement and innovation towards more sustainable industrial practices by showcasing vegetable oil-based PUAs as viable, high-performance alternatives to their petroleum-based counterparts.

This study aimed to analyze the effect of pre-heat treatment on bamboo strand properties and its impact on the properties of the resulting bamboo-oriented strand board (BOSB). Giant bamboo (Dendrocalamus asper (Schult.) Backer) with a density of 0.53 g cm⁻³ was converted into bamboo strands. These strands were pre-heat-treated at 140 and 160 °C for a duration of 1, 2, and 3 h. Changes in the chemical composition of the strand due to subsequent treatment were assessed. Fourier-transform infrared spectroscopy (FTIR) and X-Ray diffraction analysis (XRD) were used to determine the changes in the chemical composition of bamboo strands. The BOSB panels were produced with a target density of 0.7 g cm⁻³. The manufacturing of the BOSB was conducted in three layers with a ratio of 25:50:25, bonded with phenol-formaldehyde resin. The physical and mechanical properties of the laboratory-fabricated BOSB were tested in compliance with the criteria given in JIS A 5908 standards. Comparisons were made against OSB CSA 0437.0 Grade O-1 commercial standard. The pre-heat treatment led to chemical alterations within the material when set at 140 and 160 °C for 1 to 3 hours (h). FTIR spectral analysis demonstrated that longer exposure and higher temperatures resulted in fewer functional groups within the bamboo strands. The increased temperature and duration of pre-heat treatment enhanced the crystallinity index (CI). The dimensional stability and mechanical properties of the composites were improved significantly as hemicellulose and extractive content were reduced. This study demonstrated that the pre-heat treatment of bamboo strands at a temperature of 160 °C for a duration of 1 h was an adequate approach for heat modification and fabrication of BOSB panels with acceptable properties according to OSB CSA 0437.0 Grade O-1 commercial standard.

Hybrid Bamboo Oriented Strand Boards (OSB) were produced to improve bamboo OSB's physical and mechanical properties. Shelling ratio adjustment of the strand type combination could determine the optimal physical and mechanical properties of hybrid bamboo oriented strand boards (OSB). The purpose of this study was to evaluate the physical and mechanical properties of hybrid betung and andong bamboos OSB at various shelling ratios. Steam modified strands of betung and andong bamboo were used as an outer layer and core layer, respectively. Hybrid bamboo OSBs were prepared with 0.7 g cm-3 target density and 8% phenol-formaldehyde resin content. Three layers of OSB were made with outer: core shelling ratios of 30:70, 40:60, 50:50, and 60:40. The physical and mechanical properties of the OSB were tested referring to the JIS A 5908-2003 standard. The targeted board density was achieved and the physical properties of all hybrid bamboo OSB have met the requirement of CSA O437.0 (Grade O-1) standard criteria. The parallel modulus of elasticity (MOE) and modulus of rupture (MOR) increased with increasing outer layer ratio. However, the perpendicular MOE and MOR decreased with increasing outer layer ratio. The internal bonding (IB) of the OSB with a shelling ratio of 30:70 and 40:60 met with the requirement of the CSA O437.0 (Grade O-1) standard.