This investigation scrutinizes the economic features and potential of propylene and methanol production from natural gas in Iran because greenhouse gas emissions released by natural gas-based production processes are lower than coal-based ones. Considering the advantage of Iran’s access to natural gas, this study evaluates and compares the economic value of different plans to complete the value chain of propylene production from natural gas and methanol in the form of four units based on three price scenarios, namely, optimistic, realistic, and pessimistic, using the COMFAR III software. Iran has been ranked as the second most prosperous country globally based on its natural gas reserves. Methanol and propylene production processes via natural gas will lower the release of greenhouse gas. This, increasing the investment and accelerating the development of methanol and propylene production units driven by natural gas will lead the world to a low emission future compared to coal-based plants. The economic evaluation and sensitivity analysis results revealed that the conversion of methanol to propylene is more attractive for investment than the sale of crude methanol. The development of methanol to propylene units is more economical than constructing a new gas to propylene unit because of the lower investment costs.
Nanostructured Bismuth-based materials are promising electrodes for highly efficient electrochemical reduction processes such as hydrogen evolution reaction (HER). In this work, a novel sort of nanocomposite made up of partially reduced Bi2O3 into metallic Bi anchored on a 3D network of Ni-foam as a high-performance catalyst for electrochemical hydrogen reduction. The application of the hybrid material for HER is shown. The high catalytic activity of the fabricated electrocatalyst arises from the co-operative effect of Bi/Bi2O3 and Ni-foam which provides a highly effective surface area combined with the highly porous structure of Ni-foam for efficient charge and mass transport. The advantages of the electrode for the electrochemical reduction processes such as high current density, low overpotential, and high stability of the electrode are revealed. An overall comparison of our as-prepared electrocatalyst with recently reported works on related work is done.
Supercritical carbon dioxide injection in tight reservoirs is an efficient and prominent enhanced gas recovery method, as it can be more mobilized in low-permeable reservoirs due to its molecular size. This paper aimed to perform a set of laboratory experiments to evaluate the impacts of permeability and water saturation on enhanced gas recovery, carbon dioxide storage capacity, and carbon dioxide content during supercritical carbon dioxide injection. It is observed that supercritical carbon dioxide provides a higher gas recovery increase after the gas depletion drive mechanism is carried out in low permeable core samples. This corresponds to the feasible mobilization of the supercritical carbon dioxide phase through smaller pores. The maximum gas recovery increase for core samples with 0.1 mD is about 22.5%, while gas recovery increase has lower values with the increase in permeability. It is about 19.8%, 15.3%, 12.1%, and 10.9% for core samples with 0.22, 0.36, 0.54, and 0.78 mD permeability, respectively. Moreover, higher water saturations would be a crucial factor in the gas recovery enhancement, especially in the final pore volume injection, as it can increase the supercritical carbon dioxide dissolving in water, leading to more displacement efficiency. The minimum carbon dioxide storage for 0.1 mD core samples is about 50%, while it is about 38% for tight core samples with the permeability of 0.78 mD. By decreasing water saturation from 0.65 to 0.15, less volume of supercritical carbon dioxide is involved in water, and therefore, carbon dioxide storage capacity increases. This is indicative of a proper gas displacement front in lower water saturation and higher gas recovery factor. The findings of this study can help for a better understanding of the gas production mechanism and crucial parameters that affect gas recovery from tight reservoirs.
Hybrid inorganic perovskites (HIPs) have been developed in recent years as new high-efficiency semiconductors with a wide range of uses in various optoelectronic applications such as solar cells and light-emitting diodes (LEDs). In this work, we used a first-principles theoretical study to investigate the effects of phase transition on the electronic and optical properties of CsPbI3 pure inorganic perovskites. The results showed that at temperatures over 300 °C, the structure of CsPbI3 exhibits a cube phase (pm3m) with no tilt of PbI6 octahedra (distortion index = 0 and bond angle variance = 0). As the temperature decreases (approximately to room temperature), the PbI6 octahedra is tilted, and the distortion index and bond angle variance increase. Around room temperature, the CsPbI3 structure enters an orthorhombic phase with two tilts PbI6 octahedra. It was found that changing the halogens in all structures reduces the volume of PbI6 octahedra. The tilted PbI6 octahedra causes the distribution of interactions to vary drastically, which leads to a change in band gap energy. This is the main reason for the red and blue shifts in the absorption spectrum of CsPbI3. In general, it can be said that the origin of all changes in the structural, electronic, and optical properties of HIPs is the changes in the volume, orientation, and distortion index of PbI6 octahedra.
The power system planning problem considering system loss function, voltage profile function, the cost function of FACTS (flexible alternating current transmission system) devices, and stability function are investigated in this paper. With the growth of electronic technologies, FACTS devices have improved stability and more reliable planning in reactive power (RP) planning. In addition, in modern power systems, renewable resources have an inevitable effect on power system planning. Therefore, wind resources make a complicated problem of planning due to conflicting functions and non-linear constraints. This confliction is the stochastic nature of the cost, loss, and voltage functions that cannot be summarized in function. A multi-objective hybrid algorithm is proposed to solve this problem by considering the linear and non-linear constraints that combine particle swarm optimization (PSO) and the virus colony search (VCS). VCS is a new optimization method based on viruses’ search function to destroy host cells and cause the penetration of the best virus into a cell for reproduction. In the proposed model, the PSO is used to enhance local and global search. In addition, the non-dominated sort of the Pareto criterion is used to sort the data. The optimization results on different scenarios reveal that the combined method of the proposed hybrid algorithm can improve the parameters such as convergence time, index of voltage stability, and absolute magnitude of voltage deviation, and this method can reduce the total transmission line losses. In addition, the presence of wind resources has a positive effect on the mentioned issue.
Nowadays, water savings on industrial plants have become a significant concern for various plants and sections. It is vitally essential to propose applicable and efficient techniques to retreat produced water from onshore and offshore production units. This paper aimed to implement the PFF (Photo Fenton Flotation) method to optimize the water treatment procedure, as it is a two-stage separation technique. The measurements were recorded for the HF (hydraulic fracturing) and CEOR (chemically enhanced oil recovery) methods separately to compare the results appropriately. To assure the efficiency of this method, we first recorded the measurements for five sequential days. As a result, the total volume of 2372.5 MM m3/year of water can be saved in the HF process during the PFF treatment procedure, and only 20% of this required fresh water should be provided from other resources. On the other hand, the total volume of 7482.5 MM m3/year of water can be saved in CEOR processes during the PFF treatment procedure, and only 38% of this required fresh water should be provided from other resources. Therefore, the total water volume of 9855 MM m3 can be saved each year, indicating the efficiency of this method in supplying and saving the water volume during the production operations from oilfield units.